CAPE Chemistry Data Booklet

TABL E 6:SELECTED INFRARED ABSORPTION ABSORPTION SPECTROSCOPIC SPECTROSCOPIC DATA Characteristic Characteristic absorption ranges* (Wave number, cm-1) Bond ° “H

,free’ ,free’

3580 3580 to to 3670 36 3670 367 700

N-H

primary amines

3350 to to 3500 3500 3350 35 00

0-H

‘hydro ‘hydrogen-bonded’ gen-bonded’ in inalcoho al acohols, lcohols, lcohols, ls, phenols phen phenols phenols ols

323 32300 to to3550 3550 3230

C -H

alkanes, arene alkanes, alkenes, alkenes, arenes arenes areness

284 0 to to3095 2840 33095 095

0- H

'hydro ‘hydrogen-bond gen-bonded' ed’ in in acids ac acid idss

to 3300 2500 250 0to to3300 33 3300 00 2500 33 00

CmN

2200 to 2280 2280

C* C

2070 2070 to to 2250 225 2250 22500

C =0

aldehydes, ketones, acids, esters

1680 1680toto to1750 1750 17 1750 1750 50 1680

0 =0

1610 1610t o to1680 1680 1680

C -O

alcohols, ethers, esters esters

1000 1000toto to1300 1300 13 1300 1300 00 1000 700 700 to to 800 800

C~Cl

’ due to stretching stretching vibrations

TABLE 7: SELECTED 1H NMR DATA Type o f p r o to to n

Chemica l shif shifcc in regi on of

R—CH R—CH j

0.9

R—CHj-R

n

R

ft- C-H

10

_________ ___ n ______

—C —C —C H ,—

2.3

I o iJ

—O—CHj —O—CHj

—O —CHj— CHj—R —O—H

1.0' (variable) 7.5

■H O

-

—c —o

9.5

k

—c —o I

11.0

O—H

CXC

A11/U2/06

70

(variable)

s t n e m e l E e h t f o e l b a T c i d o i r e P e h T

1 e 8 . N 0 2

0 e 3 . H 0 4

m 2

0 1

A I I 9 V

0

r 0 8 . K 3 8

4 5

r 0 9 . B 3 7

3 5

9 e 6 . 7 S 8

2 5

3 s 2 . 7 A 4

1 5

e 1 6 . 7 G 2

0 5

7 a 2 . G 9 6

3 4

9 B 3 0 n . I 3 I Z 5 6

8 4

r 5 3 A 9 3

6 3

4 ! 5 , C 5 3

8 1

. F 0 9 1

7 1

5 3

0 0 . 0 6 1

6 1

7 0 . 4 3 s 2 3

0 A 7 N 1 . 4 1 V

5 1

7 9 . P 0 3

1 0 . c 2 1

4 1

A I V

A v r

e

6

A 5 I I I

1 8 . B 0 1

3 3 !

0 i 3 . S 3 2

2 3

l 8 9 . A 6 2

1 3

3 1

5 9 u . B I 2 C 3 6 5

1

2

A I

i 1 4 . L 9 8

3

4 8

. b 8 1 1 S 2

3 8

. n 7 8 1 S 1

2 8

3 4

B r 0 0 . I 4 2 2 V C 5

2 4

4 9 B 3 . V 2 V 0 5

1 4

7 i S . T 7 4

0 4

B 1 c 6 9 . I 2 I S 4 4 I

9 3

g 1 3 . 4 2 M

0 a 3 . C 0 4

0 2

9 a 9 . 9 1 N 2 2

0

. K 1 9 3

1 7

3 o ) 0 2 P (

0 7

. i 0 0 B 9 2

9 6

. u 0 5 L 7 1

)

(

, b 0 3 1 Y 7

. q 6 0 H 0 2

2 1 1

t r ) 1 7 u ( 2 U

t 1 9 P 5 1

0 1 1

m

7 7

2 . r S 2 ! 1

9 0 1

u R

1 1 0 1

6 7

. B s 2 0 0 9 1 O 1

o ) 8 3 T (

5 7

o 4 8 . 5 9 M

4 7

3 3 w 1

b 1 9 . N 2 3

3 7

. a 9 0 T 8 1

5 0 1

r 2 2 . Z 1 3

2 7

f 5 7 H 8 1

4 0 1

. a 9 3 L 8 1

9 8

) 7 2 2 (

a 3 7 B 3 1

a B

6 a ) 2 2 R (

. s 9 2 1 C 3

7 8

. d 4 6 P 0 1

8 7

9 . 2 0 1

1

2 . e S R 8 1

. Y S 8 8

7 5

r 2 6 . S 7 8

6 5

4 b 7 . R 5 3

5 5

8 3

7 3

9 o ) 5 2 N (

2 0 1

)

5 d 8 2 i (

1 0 1

. r 3 6 E 7 1 j 9 . ~ o 4 r H 6 i 1 ~ 5 . 6 y 2 6 6 D 1

9 9

. b 9 8 T 5 1

7 3

. d 3 7 1 G 5

6 9

8 6

4

0 8

9

8 m 6 T 1

2 r ) 6 2 L (

3 0 1

1

. b 2 7 P 0 2

b ) 7 7 u ( 2 U u ) 9 . . . u 0 7 g 7 1 7 3 u 2 7 4 9 1 0 7 2 1 J 1 1 A A t (

4 . 4 M 5

2 2

t 0 2 A 1

8

. d 4 2 1 C 1

4 4

n 9

1

) 2 2 2 (

. f l , f 4 n 4 1 i T 0 I 1 2

6 e 5 . F 5 5

B I 2 I 5 V

1 1

. e 6 7 1 T 2

5 4

7 2

6 2

2 1

5 3

3 9 o S . C 5

B V I

A 4 e 1 I . B 0 I 9

. 6 I 3 2

6 4

B i n v 8 0 H 0 . 1

6 8

i 9 6 . N 8 5

8 2

n R

. e 3 1 1 X 3

5 £

4 8

m

) 8 S 2 (

3 6

s ) 3 6 2 H (

2 6

4 h ) G 2 B (

1 6

) l f 6 6 2 S (

0 6

2 b ) 6 2 D (

9 5

f ) 1 6 2 R (

8 5

7 0 1

8 . 6 0 1

0

m F )

0 0 1

7 5 2 (

2 s ) 5 2 E (

f ) 1 5 2 C (

8 9

7 k ) 4 2 B ( )

7 4 m ( C 2 )

. u 2 E 5 1

5 9

0 m 1 S 5

4 9

) u 4 4 2 P (

5 4 m 1 P (

3 9

7 p ) 3 2 N (

. d 2 4 N 4 1

2 9

u 8 3 2

. r 3 0 P 4 1

1 9

1 a ) 3 2 F (

4

)

3 4 m 2 A (

0 .

0 . . e 1 2 0 0 b 4 9 C 1 l 3 2

c A

3 r ) 2 2 F (

e c i f f O e 6 n 1 o Z / 8 n 0 r e 6 t s e 0 0 W 2

/

n x n

> >

d

n \

o © O

1 <

CAPE Chemistry Data Booklet

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