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M SD S ACTIO ACTI O MSDS ID: 292 27
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SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION MANUFA CT CTURER URER NAME:
3M
DIVISION:
3M ESPE Dental Products
ADDRESS:
3M Center St. Paul, MN 55144-1000
EMERGENCY EMERGEN CY PHONE:
1-800-364-3577 or (651) 737-6501 (24 hours)
ISSUED:
02/24/10
SUPERSEDES:
10/02/06
Specific Use:
Temporary dental restorative
Intended Use:
Dent al product Limitat Limitat ions on Use: Use: For use only by dental prof essionals
ADDRESS:
3M Center
A DDRESS CITY: CITY:
St. P aul, aul,
A DDRESS STATE: STATE:
MN
AD DRESS ZIP:
55144-1000
BUSINESS PHONE:
1-800-364-3577 or (651) 737-6501 (24 hours)
MSDS Manufa Manufa cturer Number:
16-2782-7
TRAD E NAME:
3MTM 3MTM ESPETM CAV IT/ CAV IT-W/ CA VIT-G
PRO DUCT NA NA ME:
3M ESPE ESPE CA VIT/ CA CA VIT-W/ CAVIT-G
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS I ngredient Nam e
CA S#
I ngredient P erce nt
ZI NC O XI DE
131 4-13-2
3 0 - 50
C AL C I U M SU L FAT E
777 8-18-9
1 - 30
b y W e ig h t
BAR I U M SU L F AT E
772 7-43-7
0 - 20
b y W e ig h t
1 0 - 20
b y W e ig h t
ET H Y L ENE BI S( O XY ET H Y L ENE) DI AC ET AT E
1 1 1 -2 1 -7
T AL C
148 07-96-6
0 - 20
b y W e ig h t
b y W e ig h t
ZI NC SU L FAT E
773 3-02-0
5 - 10
b y W e ig h t
P O L Y ( VI NY L AC ET AT E)
900 3-20-7
1 - 5
b y W e ig h t
SECTION 3 - HAZARDS IDENTIFICATION Specific Physical Form:
Paste
Odor, Color, Grade:
Slight Slight charact eristic odor, pink, grey , or white in color
General Physical Form:
Solid
Immediate health, physical, and environmental hazards:
This document has bee n prepared in accordance with the U.S. OSHA Hazard Communication Standard, which which requires the inclusion of all kno known haza azards of th t he pr product oduct or in ingred gredients ients reg regardl ardless ess of t he potential potential risk. The The risks of t he hazards communicated in this document may v ary depending on the potential for e xposure.
EYE CONT CONTA A CT CT::
Contact with the eye s during during product use is not expe cted t o result in significant significant irritat irritat ion.
SKIN SKI N CONTA CONTA CT:
Mild Mild Skin Irritation: Signs/sympto ms m ay include include localized redness, swelling, and itching.
INHALATION:
Respiratory Tract Irritat ion: Signs/symptom Signs/symptom s may include cough, sneezing, nasal discharge, discharge, headache, hoarse ness, and nose and throat pain.
INGESTION:
Gastrointest inal Irritat ion: Signs/symptom Signs/symptom s may include abdominal pain, stomach upset, nausea, vom iting and diarrhea.
SECTION 4 - FIRST AID MEASURES www.a www.actiocms.com/v ctiocms.com/view_m iew_msds/MSD sds/MSDSDi SDisplayMYSQL/m splayMYSQL/msdsdispl sdsdisplay aycode_MYSQL.cfm code_MYSQL.cfm?msds_id=29227 ?msds_id=29227&cli &cli ent_id=111&CFID= 1975484&CFTOKEN= 1975484&CFTOKEN= 11cdaa57ea 11cdaa57ea… …
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EYE CONTA CT:
Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
SKIN CONTA CT:
Wash af fected area with soap and water. I f signs/symptoms develop, get medical attention.
INHALATION:
Remove person to f resh air. If signs/symptoms develop, get medical attention.
INGESTION:
Do not induce vom iting unless instructed to do so by me dical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical att ention.
First A id Comments:
The following first aid recom mendations are ba sed on an assumption that a ppropriate personal and industrial hygiene practices are followed.
SECTION 5 - FIRE FIGHTING MEASURES AUTOIGNITION TEMPERATURE:
No Data A vailable
FLASH POINT:
Not A pplicable
FLA MMA BLE LIMITS - LEL:
Not A pplicable
FLA MMA BLE LIMITS - UEL:
Not A pplicable
EXTINGUISHING MEDI A :
Use f ire extinguishers with class B ext inguishing agents (e.g. , dry chemical, ca rbon dioxide).
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Not a pplicable.
Note:
See STABI LITY A ND REA CTIVI TY (SECTION 10) for hazardous combustion and thermal decomposition information.
SECTION 6 - ACCIDENTAL RELEASE MEASURES Accidental Release Measures:
Evacuat e unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the are a with fresh air. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Observe pre cautions from other sect ions. Call 3M- HELPS line (1-800-364-3577) for m ore inform ation on handling and managing the spill. Collect as much of the spilled mate rial as possible. Clean up residue. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.
SECTION 7 - HANDLING and STORAGE HANDLING:
Avoid eye contact. Do not eat, drink or smoke when using this product. Wash ex posed areas thoroughly with soap and water.
STORAGE:
Not a pplicable.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION - EXPOSURE GUIDELINES Guideline Inf o:
15 mg/m3
Ingredient:
TALC
Guideline Type:
OSHA TWA concentration, as total dust
Guideline Inf o:
0.3 mg/m3
Ingredient:
TALC
Guideline Type:
OSHA TWA
Guideline Inf o:
20 millions of particles/cu. f t.
Ingredient:
ZINC OXIDE
Guideline Type:
A CGIH TWA , respirable f raction
Guideline Inf o:
2 mg/m3
Ingredient:
ZINC OXIDE
Guideline Type:
A CGIH STEL, respirable fraction
Guideline Inf o:
10 mg/m3
Ingredient:
ZINC OXIDE
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Guideline Type:
OSHA TWA , as fume
Guideline Inf o:
5 mg/m3
Ingredient:
ZINC OXIDE
Guideline Type:
OSHA TWA , respirable f raction
Guideline Inf o:
5 mg/m3
Ingredient:
ZINC OXIDE
Guideline Type:
OSHA TWA, as total dust
Ingredient:
TALC
Guideline Type:
CMRG TWA , as res pirable dust
Guideline Inf o:
0.5 mg/m3
Ingredient:
TALC
Guideline Type:
OSHA TWA concentration, respirable
Guideline Inf o:
0.1 mg/m3
Guideline Inf o:
5 mg/m3
Ingredient:
CALCIUM SULFA TE
Guideline Type:
OSHA TWA, as total dust
Guideline Inf o:
15 mg/m3
Ingredient:
TALC
Guideline Type:
A CGIH TWA , respirable f raction
Guideline Inf o:
2 mg/m3
Guideline Type:
OSHA TWA , respirable f raction
Ingredient:
BA RIUM SULFA TE
Guideline Type:
ACGIH TWA
Guideline Inf o:
10 mg/m3
Ingredient:
BA RIUM SULFA TE
Guideline Type:
OSHA TWA , respirable f raction
Guideline Inf o:
5 mg/m3
Ingredient:
BA RIUM SULFA TE
Guideline Type:
OSHA TWA, as total dust
Guideline Inf o:
15 mg/m3
Ingredient:
CALCIUM SULFA TE
Guideline Type:
ACGIH TWA, inhalable fraction
Guideline Inf o:
10 mg/m3
Ingredient:
CALCIUM SULFA TE
Prev ention of Swallowing:
Do not ea t, drink or smoke when using this product. W ash exposed areas t horoughly with soap and water. D o not ingest.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufac turer Recom mended Guideline OSHA : Occupational Safety and Health A dministration A IHA: A merican Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
ENGINEERING CONTROLS:
Use with appropriate local exhaust ventilation. Use in an enclosed process area is recomm ended. Not applicable.
EYE PROTECTION:
Avoid eye contact. The following eye protection(s) are recommended: Safe ty Glasses with side shields.
SKIN PRO TECTION:
Avoid prolonged or repeated skin contact.
RESPIRATORY PROTECTION:
Under normal use conditions, airborne exposures are not expect ed to be significant enough to require respiratory protect ion.
SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES Odor, Color, Grade:
Slight charact eristic odor, pink, grey , or white in color
General Physical Form:
Solid
Autoignition temperature:
No Data A vailable
Flash Point:
Not A pplicable
Flamm able Limits - LEL:
Not A pplicable
Flamm able Limits - UEL:
Not A pplicable
BOI LING POINT:
Not A pplicable
DENSITY:
No Data A vailable
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VA POR DENSITY:
Not A pplicable
VAPOR PRESSURE:
Not A pplicable
SPECIFIC GRAVITY:
2.6 - 3.0 [Ref Std: W A TER=1]
pH:
Not A pplicable
MELTING P OI NT:
No Data A vailable
EVAPORATION RATE:
Not A pplicable
VOLATILE ORGANIC COMPOUNDS:
Not A pplicable
PERCENT VOLA TILE:
Not A pplicable
VISCOSITY:
No Data A vailable
VOC LESS H2O & EXEMPT SOLVENTS:
Not A pplicable
SOLUBILITY IN WATER:
Nil
Specific Physical Form:
Paste
Kow - Oct/Wat er partition coef:
Not A pplicable
SECTION 10 - STABILITY and REACTIVITY STABILITY:
Stable.
CONDITIONS TO A VOID:
10.1 Conditions to a void None known 10.2 Materials to a void None known
HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.
HAZA RDOUS DECOMPOSITION Substance: Carbon monoxide (Condition: D uring Combustion) Substance: PRODUCTS: Carbon dioxide (Condition: D uring Combustion) Substance: Irritant Vapors o r Gases (Condition: During Combustion)
SECTION 11 - TOXICOLOGICAL INFORMATION Toxicological Inform ation:
Please contact the address listed on the first page of the MSDS for Toxicological Informat ion on this material and/or its components.
SECTION 12 - ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION:
Not determined.
CHEMICAL FATE INFORMATION:
Not determined.
SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL:
For quantities <100 lbs. (50kg): dispose of waste product in a sanitary landfill. F or larger quantities: incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. Since regulations vary , consult applicable regulations or authorities before disposal.
EPA Hazardous Waste Number EPA Hazardous Waste Number (RCRA ): Not regulated (RCRA):
SECTION 14 - TRANSPORT INFORMATION Transportation Information:
ID Number(s): 70-2011-0154-3, 70-2011-0155-0, 70-2011-0156-8, 702011-0157-6, 70-2011-0158-4, 70-2011-0159-2, 70-2011-0160-0, 702011- 0460-4, 70-2011-0461-2, 70-2011-0462-0, 70-2011-0463-8, 702011-0464-6, 70-2011-0465-3, 70-2011-0466-1, 70-2011-2096-4, 702011-2097-2, 70-2011-2098-0, 70-2011-3641-6, 70-2011-3642-4 Plea se contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.
SECTION 15 - REGULATORY INFORMATION US FEDERA L REGULATIONS:
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate
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Hazard - Yes De layed Hazard - No STA TE REGULATIONS:
Contact 3M for more information.
CHEMICA L I NVENTORIES:
A ll applicable chemical ingredients in this ma terial are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. This material contains one or more substances not listed on the TSCA Inve ntory. Commercial use of this material is regulated by the FDA. Contact 3M for more information.
INTERNATIONA L REGULATIONS:
Contact 3M for more information.
U.S OSHA :
This MSDS has been prepared to m eet t he U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 313:
ZINC OXID E (ZINC COMPO UNDS): (CAS: 1314-13-2; % by W t: 30 - 50;) ZINC SULFA TE (ZINC COMPO UNDS): (CAS: 7733-02-0; % by W t: 5 - 10;)
SECTION 16 - ADDITIONAL INFORMATION HMIS A ND NFPA NOTES:
NFPA Explanation: National Fire Protection A ssociation (NFPA ) hazard ratings are designed for use by eme rgency response personnel to address the hazards that are presented by short-term, acute exposure to a m aterial under conditions of f ire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of t he mate rial but also include the tox ic properties of combustion or decomposition products that are known to be generated in significant quantities. ;
NFPA - HEALTH:
1
NFPA - FIRE:
1
NFPA - REACTIVITY:
0
NFPA - SPECIAL HAZA RDS:
None
DISCLAIMER:
The information in this Material Saf ety Dat a Sheet (MSDS) is believed to be correct as of the date issued. 3M MA KES NO WA RRANTIES, EXPRESSED OR IMPLIED , INCLUDING, BUT NOT LIMITED TO, A NY IMPLIED WA RRANTY OF MERCHA NTA BILITY OR F ITNESS FOR A PA RTICULA R PURPOSE OR COURSE OF P ERFORMANCE OR USA GE OF TRA DE. User is responsible f or determ ining whether the 3M product is fit for a part icular purpose and suitable f or user's method of use or application. Given the variety of factors t hat can aff ect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that t he user evaluate t he 3M product to dete rmine whether it is fit f or a particular purpose and suitable for user's method of use or application. 3M provides informat ion in electronic f orm as a service to its customers. Due t o the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this inform ation, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the informat ion in the MSDS ava ilable directly f rom 3M. 3M MSDSs are available at www.3M.com
Revision Changes:
Section 1: Product name was modified. Sect ion 1: Product use informat ion was modified. Copyright was modified. Sect ion 3: Pot ential eff ects from ey e contact was modified. Section 3: Potential eff ects from inhalation information was modified. Section 3: Potential effects from ingestion inform ation was modif ied. Sect ion 7: Handling inform ation was modified. Se ction 8: Engineering controls informa tion was modified. Section 8: Skin protection phrase was modified. Sect ion 8: Prevention of swallowing inform ation was modified. Se ction 13: Wa ste disposal method informa tion was modified. Se ction 4: First aid for ingestion (swallowing) - deconta mination - was modified. Section 4: First aid for ingestion (swallowing) - medical assista nce - was modified. Page Heading: Product name was modif ied. Section 15: 311/312 Imme diate Hazard score was modified. Sect ion 15: Inventories informat ion was modified. Sect ion 9: Propert y description for optional properties was modified. Sect ion 3: Imm ediate ot her hazard(s) was added. Section 14: ID Number Heading Template 1 was added. Section 14: ID Number(s) Template 1 was added. Section 2: Ingredient table was added. Sec tion 15: EPCRA 313 information was added. Section 15: EPCRA 313 text was added. Sect ion 8: Exposure guidelines ingredient inform ation was added. Section 8: Exposure guidelines data source legend was added. Se ction 10.1 Conditions to av oid was added. Se ction 10.2 Materials to av oid was added. Section 6: Release me asures informat ion was added. Sect ion 6: Release measures information was added. Section 6: Release measures
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informat ion was added. Se ction 10: Materials to avoid physical property was added. Section 10: Conditions to av oid physical property was added. Section 6: Release mea sures information was deleted. Sect ion 10: Materials and conditions to av oid physical property was deleted. Sect ion 3: Immediate other hazard(s) comment was deleted.
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