MSDS N7330

SAFETY DATA SHEET PRODUCT

NALCO® 7330

1.

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME

NALCO® 7330

OTHER MEANS OF IDENTIFICATION

Not applicable

RECOMMENDED USE AND RESTRICTIONS

BIOCIDE Refer to available product literature or ask your your local Sales Representative for restrictions on use and dose limits.

COMPANY IDENTIFICATION

PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Karang Asem Timur, Citeureup, Bogor, Indonesia TEL: 62-21-8753175 FAX: 62-21-8753167

EMERGENCY TELEPHONE NUMBER(S)

+65 6542 9595

2.

HAZARDS IDENTIFICATION

CLASSIFICATION Skin corrosion/irritation - Category 1 Serious eye damage/eye irritation - Category 1 Skin sensitization - Category 1 Acute toxicity, Inhalation - Category 4 Acute aquatic toxicity - Category 1 Chronic aquatic toxicity - Category 1 GHS LABEL ELEMENTS HAZARD SYMBOLS

SIGNAL WORD : Danger HAZARD STATEMENTS Causes severe skin burns and eye damage. Harmful if inhaled. May cause an allergic skin reaction. PRECAUTIONARY STATEMENTS Prevention: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Contaminated work clothing should not be allowed out of the workplace.

PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Desa Karang Asem Timur, Citeureup, Bogor, Indonesia TEL: 62-21-8753175 FAX: 62-21-8753167 1 / 11


NALCO® 7330

Wash hands thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. If skin irritation or rash occurs: Get medical advice/ attention. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/ physician. Wash contaminated clothing before reuse. Collect spillage. Storage: Store in accordance with local regulations. Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations. OTHER HAZARDS None known 3.

COMPOSITION/INFORMATION COMPOSITION/INFORMAT ION ON INGREDIENTS

SUBSTANCE / PREPARATION : Mixture CHEMICAL NATURE Water, Substituted isothiazoline CHEMICAL NAME 5-Chloro-2-Methyl-4-Isothiazolin-3-one 2-Methyl-4-Isothiazolin-3-one The balance of the substances in this product are not classified as hazardous or are present below hazard cut-off limits 4.

CAS NO

% (w/w)

26172-55-4 2682-20-4

1- 5 0.1 - 1

FIRST AID MEASURES

INHALATION Get immediate medical attention. Remove to fresh air, treat symptomatically. SKIN CONTACT PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with with plenty of water. Get immediate medical attention. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.



NALCO® 7330

EYE CONTACT PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with with water for at least 15 minutes while holding eyelids open. open. If only one eye is affected be sure to use care not to contaminate the other eye with the run-off. Get immediate medical attention. INGESTION DO NOT INDUCE INDUCE VOMITING. If conscious, washout mouth and give water water to drink. If reflexive vomiting occurs, rinse mouth and repeat administration of water. water. Get immediate medical attention. MOST IMPORTANT SYMPTOMS/ EFFECTS Causes severe skin burns and eye damage. May cause an allergic skin reaction. Harmful if inhaled. NOTE TO PHYSICIAN Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition. 5.

FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA Not expected to burn. Use extinguishing media appropriate for surrounding fire. UNSUITABLE EXTINGUISHING MEDIA Not applicable. FIRE AND EXPLOSION HAZARD Not flammable or combustible. May evolve oxides of carbon (COx) under under fire conditions. May evolve HCl under fire conditions. May evolve oxides of nitrogen (NOx) and sulfur (SOx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. 6.

ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS Restrict access to area as appropriate appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. only. Ventilate spill area if possible. possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and and environmental authorities. ENVIRONMENTAL PRECAUTIONS Do not contaminate surface water. METHODS FOR CLEANING UP SMALL SPILLS: Soak up spill spill with absorbent material. Place residues in a suitable, covered, properly properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. DEACTIVATION SOLUTION - Estimate volume of remaining spilled material on the floor and prepare 10 times as much deactivation solution as follows. Prepare fresh by mixing 5% sodium hypochlorite (household bleach) and 5% sodium bicarbonate or potassium bicarbonate away from the immediate area of the spill. The solution can be prepared by adding household bleach to the 3-quart fill mark on the 1 gallon plastic container container containing 1/3 of a lb. (150 grams) grams) of sodium bicarbonate. Put on the appropriate personal protection equipment and close the container securely and shake well for 1 minute. The materials and equipment for preparing solutions should be kept available for use in areas where spills may occur. PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Desa Karang Asem Timur, Citeureup, Bogor, Indonesia TEL: 62-21-8753175 FAX: 62-21-8753167 3 / 11


NALCO® 7330

Contact an approved waste hauler for disposal disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). 7.

HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING Do not get in eyes, eyes, on skin, skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containers closed closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Skin reaction can be delayed and therefore wetting wetting of the skin and/or clothes does not always give an indication of contamination. Treat all wetting of the skin and/or clothes which occurs during handling as contact with the product and administer first aid immediately. SUITABLE STORAGE CONDITIONS Protect product from freezing. Store in suitable labeled containers. Store the containers tightly tightly closed. Keep container in a well-ventilated place. SUITABLE CONSTRUCTION MATERIAL : HDPE (high density polyethylene), PTFE, Perfluoroelastomer, Polyvinylidene difluoride, PVC, Polypropylene, CPVC (rigid), Plexiglass UNSUITABLE CONSTRUCTION MATERIAL : Carbon steel, Stainless Steel 304, Stainless Steel 316L, Nitrile, Brass, Nylon, Neoprene, EPDM, Fluoroelastomer, Plasite 7122 8.

EXPOSURE CONTROLS/PERSONAL CONTROLS/PER SONAL PROTECTION

CONTROL PARAMETERS OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Country/Source Country/Source

Substance(s)

Basis

Manufacturer's Recommendation

5-Chloro-2-Methyl-4-Iso 5-Chloro-2-Methyl-4-Isothiazolin-3-o thiazolin-3-one ne

TWA

0.076

STEL

0.23

TWA

1.5

STEL

4.5

Manufacturer's Recommendation

2-Methyl-4-Isothiazolin-3-one

ppm

mg/m3

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and the eyes. MONITORING MEASURES A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed as referenced below: Substance(s) Method Analysis Absorbant 5-Chloro-2-Methyl-4-Isothiazolin-3-one No method identified 2-Methyl-4-Isothiazolin-3-one No method identified



NALCO® 7330

APPROPRIATE ENGINEERING CONTROLS General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor. PERSONAL PROTECTION RESPIRATORY PROTECTION An approved respirator must be worn if the occupational exposure limit is likely to be exceeded. An organic vapor cartridge with dust/mist prefilter or supplied supplied air may be used. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. EYE PROTECTION Wear a face shield with chemical splash goggles. HAND PROTECTION PVC or nitrile Butyl rubber Gloves should be replaced immediately immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. SKIN PROTECTION Wear protective overalls, chemical splash goggles and impervious gloves. A full slicker suit is recommended if gross exposure is possible. HYGIENE RECOMMENDATIONS Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. 9.

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE APPEARANCE ODOR ODOR THRESHOLD pH (100 %) MELTING POINT BOILING POINT FLASH POINT EVAPORATION RATE FLAMMABILITY (solid, gas) LOWER EXPLOSION LIMIT UPPER EXPLOSION LIMIT VAPOR PRESSURE

Liquid Light yellow Green Mild No data available. 3.0 - 5.0 ASTM E-70 -3 °C 100 °C ASTM D-86 Not flammable No data available. No data available. No data available. No data available. No data available.



NALCO® 7330

VAPOR DENSITY SPECIFIC GRAVITY DENSITY SOLUBILITY IN WATER OCTANOL/WATER COEFFICIENT (log Kow) AUTOIGNITION TEMPERATURE DECOMPOSITION TEMPERATURE VISCOSITY

No data available. 1.026 (25 °C) No data available. Complete No data available. No data available. No data available. No data available.

Note: These physical properties are typical values for this product and are subject to change. 10.

STABILITY AND REACTIVITY

STABILITY Stable under normal conditions. HAZARDOUS REACTIONS Hazardous polymerization will not occur. CONDITIONS TO AVOID Freezing temperatures. INCOMPATIBLE MATERIALS Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. HAZARDOUS DECOMPOSITION PRODUCTS Under fire conditions: Oxides of carbon, Oxides of nitrogen, Oxides of sulfur, HCl 11.

TOXICOLOGICAL INFORMATION

INFORMATION ON THE LIKELY ROUTES OF EXPOSURE PRIMARY ROUTES OF EXPOSURE Eye, Skin Refer to the sections below for details of health effects via each route. DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG TERM EXPOSURE ACUTE TOXICITY DATA Harmful if inhaled. SKIN CORROSION / IRRITATION Causes severe skin burns and eye eye damage. A 1.5% active solution is corrosive to skin, a 0.6% active solution is a severe skin irritant, a 0.3% active solution is a moderate skin irritant and a 0.06% active solution is a nonirritant. SERIOUS EYE DAMAGE / IRRITATION Causes serious eye damage. A 1.5% active solution is corrosive to the eyes, a 0.3% active solution is an eye irritant and 0.06% active solution is a non-irritant. PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Desa Karang Asem Timur, Citeureup, Bogor, Indonesia TEL: 62-21-8753175 FAX: 62-21-8753167 6 / 11


NALCO® 7330

RESPIRATORY / SKIN SENSITIZATION Repeated or prolonged contact may cause sensitization sensitization in some individuals. A Guinea pig (Buehler Technique) sensitization study with an induction dosage of 90 ppm of active ingredients followed by an insult of 429 ppm of active ingredients was positive. A human repeated insult patch study of 28 ppm active ingredients followed by an insult of 56 ppm of active ingredients resulted in no effect to the subjects tested. GERM CELL MUTAGENICITY Not expected to be a mutagen. CARCINOGENICITY None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). REPRODUCTIVE TOXICITY No reproductive toxic effects expected. SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE No adverse effects expected. SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE No adverse effects expected. ASPIRATION HAZARD No aspiration toxicity classification NUMERICAL MEASURES OF TOXICITY ACUTE TOXICITY DATA The following results are for the product. ACUTE ORAL TOXICITY : Species: Rat LD50: 3,810 mg/kg Test Descriptor: Product

ACUTE DERMAL TOXICITY : Species: Rabbit LD50: > 5,000 mg/kg Test Descriptor: Product

ACUTE INHALATION TOXICITY : Species: Rat LC50: 13.7 mg/l (4 hrs) Test Descriptor: Product

CHRONIC TOXICITY DATA A 90-day dietary study in dogs of 840 ppm of isothiazolinone resulted in no mortalities or pathological findings. A 90-day dermal study in rabbits of 0.4 mg/kg/day of isothiazolinone resulted in irritation but no pathological effects. A 30-month skin painting study with mice using 400 ppm isothiazolinone three times per week showed PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Desa Karang Asem Timur, Citeureup, Bogor, Indonesia TEL: 62-21-8753175 FAX: 62-21-8753167 7 / 11


NALCO® 7330

no increased tumor frequency over control. A teratology study with rabbits and rats was negative using dosages of 1.5 to 15 mg/kg isothiazolinone. Mutagenicity results have been equivocal. HUMAN HAZARD CHARACTERIZATION Based on our hazard characterization, the potential human hazard is: High 12.

ECOLOGICAL INFORMATION

ECOTOXICITY The following results are for the product, unless otherwise indicated. Acute Fish Results : Species Sheepshead Minnow Bluegill Sunfish Rainbow Trout Inland Silverside Bluegill Sunfish Rainbow Trout Sheepshead Minnow

Exposure 96 hrs 96 hrs 96 hrs 96 hrs 96 hrs 96 hrs 96 hrs

Test Type LC50 LC50 LC50 LC50 LC50 LC50 LC50

Value 32.000 mg/l 18.67 mg/l 12.67 mg/l 16.62 mg/l 0.28 mg/l 0.19 mg/l 0.3 mg/l

Test Descriptor Product Product Product Product Active Substance Active Substance Active Substance

ACUTE INVERTEBRATE RESULTS : Species Exposure Mysid Shrimp (Mysidopsis 96 hrs bahia)

Test Type LC50

Value 18.000 mg/l

Test Descriptor Product

Test Type LC50 LC50 LC50

Value > 100 mg/kg 85 mg/kg > 60 mg/kg

Test Descriptor Active Substance Active Substance Active Substance

AVIAN RESULTS : Species Pekin Duck Bobwhite Quail Bobwhite Quail

Exposure 8 Days 21 Days 8 Days

PERSISTENCY AND DEGRADATION The degradation of the major active substance begins with ring opening and elimination of chloride ion. Degradation leads to the formation of a variety of small organic acids, methylamine, carbon dioxide and elemental sulfur. The half life of each active substance is dependent upon the initial concentration. Total Organic Carbon (TOC) : 7,850 mg/l Chemical Oxygen Demand (COD) : 20,000 mg/l Biological Oxygen Demand (BOD) : Incubation Period Value 20 mg/l

Test Descriptor

MOBILITY The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. PT. ECOLAB INTERNATIONAL INDONESIA Jl. Pahlawan, Desa Desa Karang Asem Timur, Citeureup, Bogor, Indonesia TEL: 62-21-8753175 FAX: 62-21-8753167 8 / 11


NALCO® 7330

If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air <5%

Water 30 - 50%

Soil/Sediment 50 - 70%

The portion in water is expected to be soluble or dispersible. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate. ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: High OTHER INFORMATION No data available. 13.

DISPOSAL CONSIDERATIONS

DISPOSAL METHODS Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and federal regulations for specific requirements. DISPOSAL CONSIDERATIONS Empty drums should be taken for recycling, recycling, recovery, or disposal through a suitably qualified or licensed contractor. 14.

TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this this product are as follows. LAND TRANSPORT UN/ID No : Proper Shipping Name : Hazard Class(es) : Packing Group : AIR TRANSPORT (ICAO/IATA) UN/ID No : Proper Shipping Name : Hazard Class(es) : Packing Group : MARINE TRANSPORT (IMDG/IMO) UN/ID No : Proper Shipping Name : Hazard Class(es) :

UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (5-Chloro2-Methyl-4-Isothiazolin-3-one) 8 II

UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (5-Chloro2-Methyl-4-Isothiazolin-3-one) 8 II

UN 3265 CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (5Chloro-2-Methyl-4-Isothiazolin-3-one) 8



NALCO® 7330

Packing Group : EmS-Nr. : Marine Pollutant : 15.

II F-A, S-B 5-Chloro-2-Methyl-4-Isothiazolin-3-one

REGULATORY INFORMATION

APPLICABLE REGULATIONS, INDONESIA GHS Chemical Classification and Labeling (87/M-IND/PER/9/2009)

INTERNATIONAL REGULATIONS FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act : When use situations necessitate compliance with with FDA regulations, this product is acceptable acceptable under : 21 CFR 176.300 Slimicides 21 CFR 176.170 Components of paper and paperboard in contact with aqueous and fatty foods and 21 CFR 176.180 Components of paper and paperboard in contact with dry foods. 21 CFR 176.170 Components of paper and paperboard in contact with aqueous and fatty foods and 21 CFR 176.180 Components of paper and paperboard in contact with dry foods. The following limitations apply: Maximum dosage FOR 176.300: 0.125% (ACTIVES) FOR 176.170/180: 1675 PPM

FOR 176.170/180: 3350 PPM

Limitation of dry weight fiber as an antimicrobial agent for finished coating formulations and for additives used in the manufacture of paper and paperboard, including fillers, binders, pigment slurries and sizing solutions as an antimicrobial agent for polymer latex emulsions in paper coatings

INTERNATIONAL CHEMICAL CONTROL LAWS AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS). CANADA Substances regulated under the Pest Control Products Act are exempt from CEPA New Substance Notification requirements. CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC). EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS). KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL)



NALCO® 7330

NEW ZEALAND All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals. PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS). UNITED STATES This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory List. 16.

OTHER INFORMATION

This product material safety data sheet provides provides health and safety information. The product is to be used in applications consistent with our product literature. literature. Individuals handling this product should be informed informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. REFERENCES Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Mar yland Mar yland (TOMES CPS™ CD-ROM CD -ROM Version), Micromedex, Inc., Englewood, CO. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer. Integrated Risk Information Informati on System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO. Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service. Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS™ CD-ROM CD-ROM Version), Micromedex, Inc., Englewood, CO. The Teratogen Information System, University of Washington, Seattle, W A W A (TOMES CPS™ CD-ROM CD-ROM Version), Micromedex, Inc., Englewood, CO. REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. First issue :

02.12.2010

Date issued : Version Number : Prepared By:

14.11.2013 1.1 Nalco Asia Pacific, Regulatory Affairs (RA) Specialist


MSDS N7330

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