NFPA 325 M

325

ANWNFPA 325

An American National Standard

August 5, 1994

NFPA 325 Guide to tire Hazard I

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Flammable Liauids. Gases. and Volatile

NFPA National Fire Protection Association, 1 Batterymarch Park, PO Box 9101, Quincy, MA 02269-9101

Copyright National Fire Protection Association Provided by IHS under license with NFPA No reproduction or networking permitted without license from IHS

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NOTICE All questions or other communications relating to this document should be sent only to NFPA headquarters, addressed to the attention of the Committee responsible for the document. For information on the procedures for requesting Technical Committees to issue Formal interpretations, proposing Tentative Interim Amendments, proposing amendments for Committee consideration, and appeals on matters relating to the content of the document, write to the Secretary, Standards Council, National Fire Protection Association, 1 Batterymarch Park, P.O. Box 9101, Quincy, MA 02269-9101. A statement, written or oral, that is not processed in accordance with Section 16 of the Regulations Governing Committee Projects shall not be considered the official position of NFPA or any of its Committees and shall not be considered to be, nor be relied upon as, a Formal interpretation.

Users of this document should consult applicable federal. state and local laws and regulations. NFPA does not, by the publication of this document, intend to urge action that is not in compliance with applicable laws, and this document may not be construed as doing so. Policy Adopted by NFPA Board of Directors on December 3,1982 The Board of Directors reaffirms that the National Fire Protection Association recognizes that the toxicity of the products of combustion is an important factor in the loss of life from fire. NFPA has dealt with that subject in its technical committee documents for many years. There is a concern that the growing use of synthetic materials may produce more or additional toxic products of combustion in a fire environment. The Board has, therefore, asked all NFPA technical committees to review the documents for which they are responsible to be sure that the documents respond to this current concem. To assist the committees in meeting this request, the Board has appointed an advisory committee to provide specific guidance to the technical committees on questions relating to assessing the hazards of the products of combustion. Licensing Provision

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This document is copyrighted by the National Fire Protection Association (NFPA). The terms and conditions set forth below do not extend to the index to this document. If public authorities and others reference this document in laws, ordinances, regulations, and administrative orders or similar instruments, it should be with the understanding that this document is informative in nature and does not contain mandatory requirements. Any deletions. additions, and changes desired by the adopting authority must be noted separately. Those using this method (“adoption by reference”) are requested to notify the NFPA (Attention: Secretary, Standards Council) in writing of such use. The term “adoption by reference” means the citing of the title and publishing information only. (For further explanation, see the Policy Concerning the Adoption, Printing, and Publication of NFPA Documents, which is available upon request from the NFPA.) Statement o n NFPA Procedures This material has been developed under the published procedures of the National Fire Protection Association. which are designed to assure the appointment of technically competent Committees having balanced representation. While these procedures assure the highest degree of care, neither the National Fire Protection Association. its members, nor those participating in its activities accept any liability resulting from compliance or noncompliance with the provisions given herein, for any restrictions imposed on materials or processes, or for the completeness of the text. NFPA has no power or authority to police orfenforcecompliance with the contents of this document, and any certification of products stating compliance with requirements of this document is made at the peril of the certifier.

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Copyright O 1994 NFPA, All Rights Reserved

NFPA 325 Guide to

Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids 1994 Edition This edition of NFPA 325, Guide to Fare Hazard Properties of Flammable Liquids, Gases, and Volatile Solids, was prepared by the Technical Committee on Classification and Properties of Hazardous Chemical Data and acted on by the National Fire Protection Association, Inc. at its Annual Meeting held May 16-18, 1994, in San Francisco, CA. It was issued by the Standards Council on July 14, 1994, with an effective date of August 5, 1994, and supersedes ali previous editions. The 1994 edition of this document has been approved by the American National Standards Institute. Changes other than editorial are indicated by a vertical rule in the margin of the pages on which they appear. These lines are included as an aid to the user in identifying changes from the previous edition.

Origin and Development of NFPA 325 The first edition of NFPA 325, 325111, was presented to the Association in 1930. Successively revised and enlarged editions were published in 1935, 1941, 1945, 1947, 1951, 1954, 1960, 1965, 1969, 1977, and 1984.

This document is not a code, standard, or recommended practice, as these terms are defined by NFPA. It is only a compilation of basic fire protection properties of various materials, prefaced by an explanation of the properties covered. T h e data contained have been collected from numerous authoritative sources, including the U S . Bureau of Mines, Factory Mutual Research Corporation, and Underwriters Laboratories Inc., as weil as from the manufacturers of the materials. The originating source of the data is on file at NFPA headquarters and may be obtained upon request. The table presented here summarizes available data on the fire hazard properties of about 1,500 substances, listed alphabetically by their chemical name. In addition, about 500 synonyms are listed alphabetically and cross-referenced to their proper entries. The valuCs for any given property are representative and deemed suitable for general use. Where differences exist in reference sources, the value selected for inclusion in this compilation is conservative. Slight differences are to be expected between data sources, due to differences in the purity of test samples, minor differences in test apparatus, and minor differences in technique and observation. In almost all cases, these minor variations have little practical significance. Where there is difference of opinion as to the actual value of a property of a given material or where the validity of the data presented is questioned, further tests should then be conducted on representative samples of the specific material in question by a qualified testing laboratory.


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This 1994 edition is an amended version of the 1991 edition. The hazard identification ratings of NFPA 704, Standard System for the IdentiJîcation of the Fire Hazards of Materials, have been updated to be consistent with changes made to chemicals listed in NFPA 49, Hazardous Chemicals Data. These are indicated by a vertical rule in the left-hand margin.

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PROPERTIES O F FLAMMABLE LIQUIDS, GASES, VOLATILE SOLIDS

Technical Committee on Classification and Properties of Hazardous Chemical Data F. Owen Kubias, Chair

Rocky River, OH Robert A. Michaels, Secretuly RAM TRAC Corp., NY Ron A. Kirsch, Occupational Health Services

Jacqueline E. Alpert, Underwriters Laborato-

ries Inc., IL

Inc., TN

John D. Arterberry, Northridge Hospital, CA William J. Bradford, Brookfield, CT Laurence G. Britton, Union Carbide Corp.,

Arthur A. Krawetz, Phoenix Chemical Labora-

wv

NY

John A. Davenport, Industrial Risk Insurers, CT John B. Farley, M&M Protection Consultants,

John Moskal, Arthur D. Little, Inc., MA Jennifer L. Nelson, AT&T Co., NJ

CA

Curtis G. Payne, U.S. Coast Guard (GMTH-l),

tory Inc., IL Roland J. Land, Jardine Insurance Brokers,

Rep. NFPA Industrial Fire Protection Section

Howard H. Fawcett, Wheaton, MD

DC

Rep. American Chemical Society Richard G. Gann, Nat’l. Inst. of Standards and Technology, MD Mark I. Grossman, Reliance Nat’l. Risk Specialists, NY William R Heitzig, The Dow Chemical Co., MI Rep. Chemical Manufacturers Association Richard Homer, U.S. Environmental Protection Agency, DC

Gary Robinson, Liberty Mutual Insurance

Co., IL Rep. The Alliance of American Insurers William J. Satteríìeld, Hartford Steam Boiler Inspection & Insurance Co., CT James Saylor, Aetna Life & Casualty, Rep. American Insurance Services Group, Inc. CT Norman V. Steere, Norman V. Steere Assoc., Inc., MN

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Alternates Chaman L. Aggarwal, Industrial Risk Insur-

Robert A. Kingsbury, Underwriters Laborato-

ers, CT (Alt. to J. A. Davenport)

ries Inc., IL (Alt. to J. E. Alpert)

Todd M. Christensen, M & M Protection Con-

sultants, CA (Alt. to J. B. Farley) Nonvoting Ira Wainless, U.S. Dept. of Labor/OSHA, DC

Jan van der Linde, Samsorn Chemical Publish-

ers, Netherlands Guy R Colonna, NFPA Staff Liaison This IUt repesats the mabership al the time the Committee WIIS balloted on the text of thzs edition. Since that time, changes in the membership ma9 have occurred. NOTE: Membership on a Committee shall not in and of itself constitute an endorsement of the Association or any document developed by the Committee on which the member serves. Committee Scope: This Committee shall have primary responsibility for documents o n the classification of the relative hazards of all chemical solids, liquids, and gases and to compile data on the hazard properties of these hazardous chemicals.

1994 Edition Copyright National Fire Protection Association Provided by IHS under license with NFPA No reproduction or networking permitted without license from IHS

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CONTENTS

Contents Chapter 1 General . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 - 1 Scope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,.... 1-2 Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-3 Definitions of Fire Hazard Properties . . . . . . . . . . . . . . . . . . . . . . . 1-4 Extinguishing Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-5 Suggested Hazard Identification . . . . . . . . . . . . . . . . . . . . . . . . . . 1-6 Additional Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-7 Indexing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Fire Hazard Properties of Flammable Liquids. Gases. and Volatile Solids Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

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PROPERTIES OF FLAMMABLE LIQUIDS, GASES, VOLATILE SOLIDS

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NFPA 325 Guide to Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids 1994 Edition Chapter 1 General 1-1 Scope. This guide applies to flammable liquids, flammable gases, and volatile flammable solids. 1-2 Purpose. The purpose of this guide is to provide the user with basic fire hazard information on the materials covered by the scope. 1-3 Definitions of Fire Hazard Properties.

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1-3.1 N o single fire hazard property, such as flash point or ignition temperature, should be used to describe or appraise the fire hazard or fire risk of a material, product, assembly, or system under actual fire conditions. The fire hazard properties given in this guide have been determined under controlled laboratory conditions and may properly be used to measure o r describe the response of materials, products, assemblies, or systems under these conditions. Properties measured under these conditions may be used as elements of a fire risk assessment only when such assessment takes into account all of the factors that are pertinent to the evaluation of the fire hazard of a given situation. 1-3.2 T h e pertinent literature seldom mentions the degree of purity of the material being tested; even boiling point or melting point data are frequently missing. These data, if available, would permit judging the purity of the material and, hence, the reliance to be placed on the values reported, particularly with respect to flash point and flammable range. Finally, it must be remembered that there is little industrial use of high purity materials. As a consequence of these considerations, no values of purity are given in this compilation. T h e melting points and boiling points should be regarded as approximations. 1-3.3 Flash Point. T h e flash point of a liquid is the minimum temperature at which the liquid gives off sufficient vapor to form an ignitible mixture with air near the surface of the liquid o r within the test vessel used. By “ignitible mixture” it is meant a mixture that is within the flammable range (between the upper and lower limits) and, thus, is capable of propagation of flame away from the source of ignition. Some evaporation takes place below the flash point, but not in quantities sufficient to form an ignitible mixture. Flash point applies mostly to flammable and combustible liquids, although certain solids, such as camphor and naphthalene, that slowly volatilize at ordinary room temperature, o r certain liquids, such as benzene, that freeze at relatively high temperatures, will exhibit a flash point in the solid state.

T h e flash points given in this manual are, for the most part, closed cup flash points. Where the only available data is based on open cup tests, this is designated by the initials

“oc” after the entry. I n the case of some of the older data in this manual, it could not be determined whether a closed cup or open cup procedure had been used. In these cases, it has been assumed that the data is based on closed cup tests. For further information on the flash point test procedures used, see NFPA 321, Standard on Basic ClassiJication of Flammble and Combustible Liquzds. 1-3.4 Ignition Temperature. T h e ignition temperature of a substance, whether solid, liquid, o r gas, is the minimum temperature required to cause self-sustained combustion, independently of the heating or heated element. Ignition temperatures observed under one set of conditions may differ markedly from those observed under another set of conditions. For this reason, ignition temperatures should be regarded as approximations. Some of the variables known to affect ignition temperature are the percentage of the gas or vapor in the mixture, the shape and size of the test vessel, the rate and duration of heating, the kind and temperature of the ignition source, and catalytic or other effects of materials that may be present. As there are many differences in ignition temperature test methods, such as the size and shape of the test vessel, the material of construction of the test vessel, method and rate of heating, residence time, and method of flame detection, it is not surprising that reported ignition temperatures may differ for the same material. The majority of the data reported in this manual have been obtained by one of two methods: ASTM D286 and ASTM D2155. Both have been withdrawn by the American Society for Testing and Materials. ASTM D2155 has been replaced by ASTM E659, Standard Test Method for Autoignition Temperatures of Liquid Chemicals. An earlier test method, ASTM D2883, Test Method for Reaction Threshold Temperature of Liquid and Solid Materials, provides for the study of autoignition phenomena at reduced and elevated pressures. Federal Test Method Standard 791B, Method 5050, is another current test method that provides for the measurement of autoignition properties in the same terms used by the ASTM procedures. Previous test methods relied only o n visual detection of flame. Consequently, the ignition temperatures obtained by these procedures were the minimum temperatures at which hot-flame ignition occurred. T h e current test methods employ thermoelectric flame detection, thus permitting the detection of nonluminous or barely luminous reactions that were difficult or impossible to detect by the older procedures. As a result, the following terms have come into use:

Hot-Flame Ignition. A rapid, self-sustaining, sometimes audible gas-phase reaction of the sample or its decomposition products with an oxidant. A readily visible yellow or blue flame usually accompanies the reaction. Cool-Flame Ignition. A relatively slow, self-sustaining, barely luminous gas-phase reaction of the sample o r its decomposition products with an oxidant. Cool flames are visible only in a darkened area. Pre-FlarnP Reaction. A slow, nonluminous gas-phase reaction of the sample or its decomposition products with an oxidant. Catalytic Reaction. A relatively fast, self-sustaining, energetic, sometimes luminous, sometimes audible reaction


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GENERAL

that occurs as a result of the catalytic action of any substance on the sample or its decomposition products, in admixture with an oxidant.

Non-Combustive Reaction. A reaction other than combustion or thermal degradation that is undergone by certain substances when they are exposed to heat. Thermal polymerization is an example of this type of reaction. Reaction Threshold. The lowest temperature at which any reaction of the sample or its decomposition products occurs, for any sampleioxidant ratio. Autoipition Temperature (AIT). The currently accepted term for the Hot-Flame Ignition Temperature. Cool-Flame Reaction Threshold (CFT). The lowest temperature at which cool-flame ignitions are observed for a particular system. Previously undefined. Prefiame-Reaction Threshold ( R U ) . T h e lowest temperature at which exothermic gas-phase reactions are observed for a particular system. Previously undefined. Previously, reported ignition temperatures, including those given in this manual, have corresponded roughly to the autoignition temperature (AIT), provided that proper allowances were made for empirical differences in the measurement technique. In the future, it is expected that CFT and R T ï will routinely be reported. Both are lower than AIT and are significant factors to be evaluated in the assessment of the overall ignition risk of a given system. Cool flames are self-sustaining, exothermic ignition reactions that, under proper circumstances, may act as the initiator of more energetic hot-flame reactions. Pre-flame reactions have the capacity, under adiabatic o r nearadiabatic conditions, to elevate the temperature of a fuel/ air mixture to the point where cool- or hot-flame ignition may occur.

As an illustration of the effects of test methods, the ignition temperature of hexane, as determined by three different methods, are 437°F (225”C),637°F (336“C), and 950°F (510°C). The effect of percentage composition is shown by the following ignition temperatures for pentane: 1018.4”F (548.4”C) at 1.5 percent, 935.6”F (502.4”C) at 3.75 percent, and 888.8”F (476.3”C) at 7.65 percent. The following ignition temperatures for carbon disulfide demonstrate the effect of the size of the test vessel: 248°F (120°C) in a 200 ml flask, 230°F (1 1 0 T ) in a 1 liter flask, and 205°F (96OC) in a 10 liter flask. The effect of the material of construction of the test vessel is shown by the following ignition temperatures for benzene: 1060°F (572°C) in a quartz vessel and 1252°F (678°C) in an iron vessel. The ignition temperature of a combustible solid is influenced by the rate of air flow, rate of heating, and size of the sample. Small sample tests have shown that, as the rate of air flow or the rate of heating is increased, the ignition t e m p e r a t u r e decreases to a minimum value, t h e n increases.

1-3.5 Flammable (Explosive) Limits. In the case of gases or vapors that form flammable mixtures with air, oxygen, or other oxidizers, such as chlorine and nitrous oxide, there is a minimum concentration of the material below

which propagation of flame does not occur. Similarly, there is a maximum concentration above which propagation of flame does not occur. These boundary mixtures, which, if ignited, will just propagate flame, are known as the “lower and upper flammable or explosive limits” and are usually expressed as percent by volume of the material in air (or other oxidant). I n popular terms, a mixture below the lower flammable limit (LFL) is too “lean” to burn, while a mixture above the upper flammable limit (UFL) is too “rich” to burn. The values for the flammable limits given in this manual are based on atmospheric temperatures and pressures, unless otherwise indicated. There will be considerable variation in flammable limits at temperatures and pressures above or below ambient. The general effect of an increase in temperature or pressure is to decrease the lower limit and to increase the upper limit, i.e., broaden the range between the two limits. A decrease in the temperature or pressure has the opposite effect. In most cases, the values given in this manual represent the concentration limits over which hot-flame ignitions have been observed. If coolflame ignitions are considered, wider flammable ranges are observed. Research has shown that flammability limits are not a fundamental combustion property, but depend on many variables, including the surface-to-volume ratio of the test vessel, the direction of air flow, and the velocity of air flow. In some experiments conducted at laminar flow velocities, the upper limit increased with increasing flow velocity, reached a maximum that was independent of the diameter of the test vessel, then decreased as flow became turbulent. The lower limit has been unaffected by air flow rate. ASTM E681 is the current test method for determining flammable limits. However, much of the data were obtained in small diameter tubes with ignition at the bottom so that flame propagation was upward. For most hydrocarbons, this method is appropriate. However, for highly oxygenated, aminated, or halogenated materials, larger diameter equipment is required to avoid quenching of the flame. Larger diameter test equipment o r more energetic ignition sources may better reflect real world burning conditions. The terms “flammable limits” and “explosive limits” are interchangeable. The range of concentration between the lower flammable limit and the upper flammable limit is known as the “flammable range,” also referred to and synonymous with “explosive range.” All concentrations of a gas or vapor in air that lie between the flammable limits are ignitible. 1-3.6 Specific Gravity (Relative Density). T h e specific gravity of a substance is the ratio of the weight of that substance to the weight of an equal volume of another substance. In this manual, the other substance is water. The values given in this manual for specific gravity are rounded to the nearest tenth. For materials whose specific gravity is from 0.95 to 1.O, the value is shown as 1.O - . For materials whose specific gravity is from 1.0 to 1.05, the value is given as 1.0 . In a few cases, such as fuel oils, where the percentage composition of the substance varies, specific gravity is given as less than ( < ) or greater than ( > ) 1.

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1-3.7 Vapor Density. T h e vapor density of a substance is the ratio of the weight of a volume of pure vapor o r gas (no air present) to an equal volume of dry air at the same temperature and pressure. It is calculated as the ratio of the molecular weight of the substance to the molecular weight of air, 29. A vapor density of less than 1 indicates that the substance is lighter than air and will tend to rise in a relatively calm atmosphere. A vapor density of greater than 1 indicates that the substance is heavier than air and may travei along grade level for a considerable distance to a source of ignition and flash back, assuming the gas o r vapor is flammable.

1-3.8 Boiling Point. T h e boiling point of each liquid is given at a pressure of 14.7 psia (760 mm Hg). Where an accurate boiling point is not available for a specific entry or where a specific entry is actually a mixture of components and does not have a constant boiling point, the boiling point given is the 10 percent distillation point as determined by ASTM D86, Standard Method of Test for Distillation of Petroleum Products. 1-3.9 Melting Point. Melting points are reported in this manual for most materials that melt at 70°F (21°C) or higher. However, the melting point is not available for some of these materials.

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1-3.10 Water Solubility. Water solubility d a t a a r e reported only for those materials for which reliable information is available, because of the lack of uniformity with which water solubility data are reported in the literature and because of the conflicting statements that sometimes accompany these data. Where such data is reported in this manual, “No” indicates that the material’s solubility is less than 10 grams per 100 milliliters (mi) of water; “Slight” indicates solubility is between 10 and 24 grams per 100 mi of water; “Yes” indicates solubility of 25 or more grams per 100 ml of water.

“No,” “Very Slight,” “Slight,” and “Yes” are sometimes used without definition in the literature to describe water solubility. In those cases where doubt exists as to a material’s solubility in water, tests should be conducted.

Information on the degree to which a material is soluble in water is useful in determining effective extinguishing methods and agents. For example, alcohol-resistant fire fighting foams are usually recommended for water-soluble flammable and combustible liquids. Also, fires involving water-soluble liquids can be extinguished by dilution with water, although this method is not commonly used because of the amount of water needed to dilute most flammable liquids to the point of noncombustibility and because of the danger of frothing if the liquid is heated to the boiling point of water, 2 12°F (1 OOOC).

1-4 Extinguishing Methods. 1-4.1 General. T h e extinguishing methods commonly used for fires involving flammable liquids are suitable for use on fires involving most of the materials listed in this manual. Carbon dioxide, dry chemical, foam, and vaporizing liquid extinguishing agents have all been found to be suitable for use on flammable liquid fires of moderate size, such as in dip tanks o r small spills of no appreciable depth.

T h e following comments apply to other extinguishing methods that have been found effective for the control or extinguishment of some flammable liquids fires. Water spray or fog can be particularly effective on fires involving flammable liquids and volatile solids whose flash points exceed 100°F (37.8”C). However, with liquids whose flash points exceed 212°F (100”C), frothing may occur. For information on the installation of water spray protection for flammable and combustible liquids, see NFPA 15, Standard f o r Water Spray Fixed Systems for Fire Protection. Automatic sprinklers are similar to water spray systems in extinguishing effectiveness. Their principal value is in absorbing the heat from the fire and keeping the surroundings cool until the flammable liquids fire either burns out or is extinguished by other means. Automatic sprinklers have a good record of fire control in garages, in paint and oil rooms, and in storage areas where liquids are kept in closed containers. I n some industries that use water-soluble liquids, such as the distilled spirits industry, sprinkler systems have been used to achieve protection and extinguishment with excellent results. Where automatic sprinklers are used to protect open tanks, overflow drains are necessary to prevent sprinkler discharge from overflowing the tank and spreading burning liquid to others parts of the property. For further information on automatic sprinklers, see NFPA 13, Standard f o r the Installation of Sprinkler Systems. Hose streams, both solid and straight streams, are frequently used to cool tanks, containers, and equipment from the heat of an exposing fire. They are also used for washing burning spills away from areas where the burning liquid could ignite other material. However, hose streams may also spread and extend the spill fire, if improperly used. Also, hose streams applied to open containers of burning liquid will only serve to spread the fire, either by splashing the burning liquid out of the container or by causing frothing of the liquid. Use of automatic-closing covers on open tanks or equipment containing flammable o r combustible liquid is also effective in fire control and extinguishment. T h e covers should be operated by a fusible link, with a manual override. Such covers are suitable for any size tank except where objects being dipped o r conveyor systems may prevent tight closing of the cover.

1-4.2 Selecting an Extinguishing Method. T h e selection of the extinguishing method used should be made with some degree of caution. Flowing fires, such as may be caused by a leaking overhead pipe, with burning liquid on the ground, are always difficult to extinguish. T h e amount of extinguishing agent and its rate and method of application must be carefully chosen in relation to the size and type of fire anticipated and may call for special engineering judgment. T h e use of approved extinguishing equipment is also a major consideration. The chemical and physical properties of the material involved will also affect the choice of extinguishing method and agent. Standard fire fighting foam cannot be used on fires involving water-soluble flammable liquids; the liquid destroys the foam blanket. Those properties that affect extinguishment were taken into consideration when selecting the methods given for each material in the column


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headed ?Extinguishing Methods.? The following information describes the properties of the material that dictate the numerically designated entries in this column. i . Water May Be Ineffective. This precaution applies to materials that have a flash point below 100°F (373°C). Obviously, the lower the flash point, the less effective the water will be. However, water can be used on low-flash point liquids when applied as a spray to absorb heat and to protect exposed material?of structures. Much of the effectiveness of using water spray, particularly from hose lines, will depend on the method of application. With proper selection of nozzles, even gasoline spill fires can be extinguished when several coordinated hose streams are used to sweep the flames from the surface of the burning liquid. Water has also been used to extinguish fires involving water-soluble flammable liquids by cooling and diluting the liquid. The distilled spirits industry has been especially successful in using water to control and extinguish fires of this type. Thus, the phrase ?water may be ineffective? indicates that, although water can be used to cool and protect exposed material, water may not be capable of extinguishing the fire unless used under favorable conditions by experienced fire fighters trained in fighting all types of flammable liquids fires.

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2. Water or Foam May Cause Frothing. This statement applies to liquids having flash points above 2 12°F ( 100°C) and is included only as a precaution. It does not indicate that water or fire fighting foam should not be used. The frothing may be violent and could endanger any fire fighters located too close to the burning liquid, particularly when solid streams of water are directed onto the hot, burning liquid. On the other hand, a carefully applied water spray has frequently been used to achieve extinguishment by deliberately causing frothing only on the surface of the liquid; the foaming action blankets the surface of the liquid and extinguishes the fire by excluding oxygen. This tactic is especially successful with high viscosity liquids. For example, certain asphalts have a low-flash point solvent added for fluidity, but because of the relatively high viscosity, frothing action is able to achieve fire control and extinguishment.

3. Water May Re Used to Blanket Fire. This statement is applicable to those liquids that have a specific gravity of 1.1 or greater and are not water-soluble. However, the water must be gently applied to the surface of the liquid, preferably with a fine spray or fog nozzle. 4. Water May Be Ineffective, Except as a Blanket. This statement is used as a warning for liquids whose flash points are below 100°F (373°C) and applies only to those liquids that have a specific gravity of 1.1 or greater and are not watersoluble. Here again, the water must be gently applied to the surface of the liquid. 5 . Alcohol Foam. Alcohol-resistant fire fighting foam is recommended for use on all water-soluble liquids or polar solvent-type liquids, except for those that are only ?very slightly? soluble. Certain judgment factors are introduced, however, since ordinary fire fighting foam may be used on some liquids that are only ?slightly? soluble, particularly if the foam is applied at higher-than-normal application rates. Conversely, some flammable liquids, such as

325-7

the higher molecular weight alcohols and amines, will destroy alcohol-resistant foams, even when applied at very high rates. Foams should not be used on water-reactive materiais. Some recently developed alcohol-resistant foams have been listed for use on both polar and nonpolar liquids. These ?multipurpose? foams are suitable for use on nearly ali flammable liquids except those that are water-reactive and are preferred for flammable liquid fires because they greatly minimize the problems of foam selection. Fire fighting foam suppliers should be consulted for recommendations regarding types of foam and application rates. 6. Stop Flow of Gas. For fires involving flammable gases, the best procedure is to stop the flow of the gas before attempting extinguishment of the fire. To extinguish the fire while allowing continued flow of the gas is extremely dangerous; an explosive cloud of gasiair mixture may be created that, if ignited, may cause far more damage than the original fire. Extinguishing the flame using carbon dioxide o r dry chemical may be desirable to allow immediate access to valves to shut off the flow of gas, but this must be done carefully. In many cases, it will be preferable to allow continued burning, while protecting exposures with water spray, until the flow of gas can be stopped.

1-5 Suggested Hazard Identification. 1-5.1 T h e increased use of chemicals, many of which introduced hazards other than flammability, led to the need for a simple hazard identification system that could be immediately recognized by emergency response personnel. This need led to the development of the NFPA 704 Hazard Identification System, otherwise known as the NFPA 704 diamond. This system is completely described in NFPA 704, Standard System f o r the Identification of the Fire Hazards of Materials. The system provides simple, readily recognized, and easily understood markings that give, at a glance, a general idea of the inherent hazards of the material and the order of severity of these hazards, as they relate to fire protection, exposure, and control. The system?s objectives are to provide an appropriate alert signal and on-the-spot information to safeguard the lives of both public and private emergency response personnel. The system also assists in planning for effective fire fighting operations and may be used by plant design engineers and plant protection and safety personnel. The system identifies the hazards of a material in terms of three categories: ?Health,? ?Flammability,? and ?Reactivity.? i t indicates the order of severity of these hazards by means of a numerical rating of O, indicating no special hazard, to 4, indicating extreme hazard. The three hazard categories were selected after studying about 35 inherent and environmental hazards of materials that could affect fire fighting operations. T h e five degrees of hazard were decided upon as necessary to give the required information. Finally, the system had to be relatively simple and readily understood. While the system is basically simple in application, the hazard evaluation required for the use of the system in a specific location must be made by experienced, technically competent persons. Their judgment must be based on factors that encompass a knowledge of the inherent hazards of different materials, including the extent of change in behavior to be anticipated under conditions of fire exposure and control.


Not for Resale

NFPA 325 94 D b47444b 0528273 b 3 î 325-8

PROPERTIES OF FLAMMABLE LIOUIDS. GASES. VOIATILE SOLIDS

-

1-5.2 Degrees of Hazard. T h e columns under “Suggested Hazard Identification” in this manual give the NFPA 704 severity ratings for each of the hazard categories for which information was available. Blank spaces indicate that sufficient information was not available for a severity rating to be assigned. It should be understood that the assignment of the ratings is based on judgment and that extenuating circumstances in plants and processes may dictate a change in any individual rating. --```,,`-`-`,,`,,`,`,,`---

T h e following commentary on the degrees of hazard are an interpretation of the information contained in NFPA 704, Standard System f o r the Identzfication of the Fire Hazards of Materials, and are specifically related to fire fighting. See NFPA 704 for more detailed information. Note: The hazard identification rating definitions below and the actual ratings in the text are based on definitions from the 1985 edition of NFPA 704. All materials contained in this guide have not yet been rated using the new definitions appearing in the 1990 edition of’ NFPA 704.

requiring the use of an approved air-purifying respirator. These materials are only slightly hazardous to health and only breathing protection is needed.

O

1-5.4 Flammability Hazard Rating. Susceptibility to ignition and burning is the basis for assigning the degree of hazard within this category. T h e method of attacking the fire is influenced by this susceptibility factor. For further information, refer to Section 1-4, Extinguishing Methods. T h e following information is based on the definitions of Flammability Hazard Rating contained in NFPA 704, Standard System f o r the Identzfication of the Fire Hazards of Materials. This degree includes flammable gases, pyrophoric liquids, and Class IA flammable liquids. T h e preferred method of fire attack is to stop the flow of material or to protect exposures while allowing the fire to burn itself out.

1-5.3 Health Hazard Rating. In general, the health hazard in fire fighting is that of a single exposure that may vary from a few seconds to as much as an hour. The physical exertion demanded in fire fighting operations or other emergencies may be expected to intensify the effects of any exposure. Only hazards arising out of the inherent properties of the material are considered. T h e following information on the five degrees of hazard are based on the information in NFPA 704 a n d relate to t h e protective equipment normally available to fire fighters.

4

3

2

1

This degree includes Class I B and IC flammable liquids and materials that can be easily ignited under almost all normal temperature conditions. Water may be ineffective in controlling or extinguishing fires in such materials. This degree includes materials that must be moderately heated before ignition will occur and includes Class II and IIIA combustible liquids and solids and semi-solids that readily give off ignitible vapors. Water spray may be used to extinguish fires in these materials because the materials can be cooled below their flash points.

Materials that, on very short exposure, could cause death o r major residual injury, including those that are too dangerous to be approached without specialized protective equipment. A few whiffs of the vapor or gas can cause death, or contact with the vapor or liquid may be fatal, if it penetrates the fire fighter’s normal protective gear. The normal full protective clothing and breathing apparatus available to the typical fire fighter will not provide adequate protection against inhalation o r skin contact with these materials. Materials that, on short exposure, could cause serious temporary or residual injury, including those requiring protection from all bodily contact. Fire fighters may enter the area only if they are protected from all contact with the material. Full protective clothing, including self-contained breathing apparatus, coat, pants, gloves, boots, and bands around legs, arms, and waist, should be provided. No skin surface should be exposed. Materials that, on intense o r continued (but not chronic) exposure, could cause temporary incapacitation or possible residual injury, including those requiring the use of respiratory protective equipment that has an independent air supply. These materials are hazardous to health, but areas may be entered freely if personnel are provided with fullface mask self-contained breathing apparatus that provides complete eye protection.

This degree includes materials that must be preheated before ignition will occur, such as Class IIIB combustible liquids and solids and semi-solids whose flash point exceeds 200°F (93.4”C), as well as most ordinary combustible materials. Water may cause frothing if it sinks below the surface of the burning liquid and turns to steam. However, a water fog that is gently applied to the surface of the liquid will cause frothing that will extinguish the fire. This degree includes any material that will not burn.

1-5.5 Reactivity Hazard Rating. T h e assignment of the degree of reactivity hazard is based on the potential of the material to release energy either by itself o r when in contact with water. In assigning this rating, fire exposure was considered, along with exposure to shock and pressure. T h e following information is based on the definitions of Reactivity Hazard Rating contained in NFPA 704, Standard System f o r the Identification of the Fire Hazards of Materials. 4

Materials that, on exposure, would cause irritation, but only minor residual injury, including those


Materials that, on exposure under fire conditions, offer no hazard beyond that of ordinary combustible material.

Not for Resale

This degree includes those materials that, in themselves, are readily capable of detonation, explosive decomposition, o r explosive reaction at normal temperatures and pressures. This includes materials that are sensitive to localized mechanical or thermal

NFPA 325 94 W b47444b 0528272 555 W 325-9

GENERAL

3

2

shock. If a material having this Reactivity Hazard Rating is involved in an advanced o r massive fire, the area should be immediately evacuated.

base the fire hazard of a mixture on that of the most hazardous component, consideration should be given to testing the mixture itself.

This degree includes materials that, in themselves, are capable of detonation, explosive decomposition, or explosive reaction, but require a strong initiating source o r heating under confinement. This includes materials that are sensitive to thermal and mechanical shock at elevated temperatures and pressures and materials that react explosively with water. Fires involving these materials should be fought from a protected location.

1-6.3 Mists and Froths. In finely divided form, such as a mist or spray, liquids can be ignited at temperatures considerably below their flash points. As in the case of vapors, the droplets of mist or spray must be present at a minimum concentration. Similarly, froths may be ignited at temperatures below the flash point.

This degree includes materials that are normally unstable a n d readily undergo violent chemical change, but are not capable of detonation. This includes materials that can undergo chemical change with rapid release of energy at normal temperatures and pressures and materials that can undergo violent chemical changes at elevated temperatures and pressures. This also includes materials that may react violently with water o r that may form potentially explosive mixtures with water. In advanced o r massive fires involving these materials, fire fighting should be done from a safe distance or from a protected location.

1-7.1 The materials in this manual are listed alphabetically by the name considered to be the most common. Other names and synonyms are indexed to this common name.

1

This degree includes materials that are normally stable, but that may become unstable at elevated temperatures and pressures and materials that will react with water with some release of energy, but not violently. Fires involving these materials should be approached with caution.

O

This degree includes materials that are normally stable, even under fire exposure conditions, and that d o not react with water. Normal fire fighting procedures may be used.

--```,,`-`-`,,`,,`,`,,`---

1-5.6 Additional Markings. T h e fourth space in the NFPA 704 rating is reserved for the use of two special symbols: OX, to denote materials that are oxidizing agents, and W, to denote materials that are water-reactive. 1-6 Additional Information.

1-7 Indexing.

1-7.2 The following prefixes are considered to be a part of the name of the material. As such, they are generally not hyphenated and are used to alphabetically index the material when they appear at the beginning of the name.

Bis Di Hexa

Is0 Mono Penta

Tetra Tri Tris

1-7.3 The prefix “mono” is often omitted. Thus, monochlorobenzene is frequently referred to as chlorobenzene. This manual uses the more common form. The alternate form is not given, unless it is also frequently used. 1-7.4 T h e following prefixes are not considered to be part of the name of the material. As such, they are hyphenated, but they are not used to alphabetically index the material.

o- (ortho) m- (meta) p- (para) n- (normal) sec- (secondary) tert- (tertiary)

d - (dextro) 1- (levulo) N- (nitro) a-(alpha) ß- (beta) Y- (gamma)

1-6.1 Mixtures with Oxygen. Unless otherwise indicated, all values in this manual are based on tests conducted in normal air. For mixtures involving enriched oxygen atmospheres, the values may differ and an increase in hazard is probable.

These prefixes may be written o u t in full, as in paradichlorobenzene. I n this manual, they are usually abbreviated. Thus, paradichlorobenzene appears in this manual as p-dichlorobenzene and is indexed under D. In accordance with custom, the prefix n-, for “normal,” is omitted, unless it appears in the middle of a name.

1-6.2 Mixtures of Materials. Mixtures of two o r more materials may have different fire hazard properties than any of the components. Although it is common practice to

1-7.5 The prefixes “cis” and “trans” may be placed either at the beginning or the end of a name. I n this manual, they are always listed at the end.


Not for Resale

NFPA 325 94 325-10

m 6474446 0528273 491 m


Fire Hazard Properties of Flammable liquids, Gases, and Volatile Solids Table

F W H IGNITION POINT TEMP. O F 1°C) OF [“Cl

I

I

BOILING POINT “F (‘C)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED HAïARD EXTINGUISHING METHODS IDENTIFICATION Flarnrna- ReacHealth biliiy tiviiy

See Methyl Abietate.

Acetal CH3cWCzHd2 (Acetoldehydediethylocetol)

-5 (-21)

446 (230)

1.6

Acetaldehyde CHBCHO (Acetic Aldehyde) (Ethanol)

-38 (-39)

347 (175)

4.0

10.4

60

0.8

4.1

0.8

2

3

O

3

4

2

3

1

O

5

3

2

O

Yes

5

3

2

1

Slight

5

2

1

O

2

2

1

O

215 (1021

Slight

1.5

70 (21)

Yes

1

5 1 5

Note: Polymerizes. See Hazardous Chemicals Doto.

Acetaldehydediethyiacetal

See Acetol.

Acetaldol

See Aldol.

Aceianilide CHjCONHCdHs

337 985 2 10 (169) (530) (OC) Note: Melting point 237 (i14).

1.21

4.65

582 (306)

Acetic Acid, GIaciaI CH3COOH

103 867 4.0 19.9@ (39) (463) 200 (93.4) Note: See Hazardous Chemicals Doto.

1.0+

2.1

245 (118)

Yes

Acetic Acid, Water Solutions (Ethanoic Acid)

Note: Ordinary acetic acid is the same os glacial acetic acid with water. The properties of ordinory ocetic acid depend upon the strength of the solution. In concentrated form its properties opprooch those of glacial acetic acid. In dilute solution it is nonhazardous.

Yes

Acetic Acid, isopropyl Ester

See Isopropyl Acetate.

Acetic Acid, Methyl Ester

See Methyl Acetate.

Acetic Acid, n-Propyl Ester

See Propyl Acetate.

Acetic Aldehyde

See Acetaldehyde.

Acetic Anhydride (cH~W20 (Ethonoic Anhydride)

120 600 2.7 10.3 (491 (316) Note: See Hazardous Chemicals Dato.

Acetic Ester

See Ethyl Acetate.

Acetic Ether

See Ethyl Acetate.

Acetoacetanillde CH3COCHzCONHCaH5

365 (185) ( 4 Note: Melting point 185 (85).

o-Acetoacet Anisidide CH3COCHzCONHC6H40CH3

325 (168)

1.1

3.5

284 (140)

1.1

2

@

melting point 1.1

7.0

No

@

(4

melting point

Note: Melting point 187.9 (87). Acetoocet-paro-Phenetide CH3COCHzCONHCaHdOCH2CH3

325 1.0+ (163) Note: Melting point 210-219 (99-104).

Decomposes

2

2

1

1

Acetoacet-ortho-Toluidide CH3COCH2CONHCbH4CH3

320 (160) Note: Melting point 214 (101).

Decomposes

2

2

1

1

m-Acetoacei Xylidide CHjCOCH2CONHCbHdCH31z

340 (171) (oc) Note: Melting point 197 (92).

5

2

1

O

1.2

Slight

2

Acetoacetic Acid, Ethyl Ester See Ethyl Acetoocetate. Acetoethylamide Acetone CH3COCH3 (Dimethyl Ketone) (2-Proponone) Acetone Cyanohydrin (CH~)ZC(OH)CN (2-Hydrow-2Methyl Propianitrile)

See N-Ethylocetomide. -4 (-20)

869 (465)

2.5

12.8

0.8

2.0

133 (56)

Yes

1 5

1

3

O

165 (74)

1270 (688)

2.2

12.0

0.9

2.9

248 (120) Decomposes

Yes

5

4

2

2

Note: See Hazardous Chemicals Dota.


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Abalyn

FLAMMABLE Vapor LIMITS Sp.Gr. Densily (Air Percent by vol. (Water Lower Upper =i) =i)

NFPA 325

6474446 0528274 328 325- 1 1


FLAMMABLE VaDor FLASH IGNITION LIMITS Sp.Gr. Density (Air POINT TEMP. Percent by vol. (Water “F (“C) Lower Upper =i) =i) “F (“C) Acetonitrile CHjCN (Methyl Cyanide)

42 975 3.0 16.0 (6) (524) (oc) Note: See Hazardous Chemicals Data.

0.8

BOILING POINT “F (“C) 179

1.4

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility tivity

Yes

1

2

3

O

1

1

O

O

5

(821

Acetonyl Acetone (CH2COCH~h (2.5-Hexanedionel

174 1791

920 1499)

1.0-

3.9

378 1192)

Yes

Acetophenone CAH&OCH, (Phenyl Meth;l Ketone)

170 1771

1058 I5701

1.0+

4.1

396

No

1

2

p-Acetotoluidide CHLONHCAH~CH?

334 (168)

2

1

Acetyl Acetone

See 2.4-Pentonedione.

Acetyl Chloride CH3COCI (Ethonoyl Chloride)

40 734 (4) (3901 Note: See Hazardous Chernicols Doto.

3

3

2w

Acetylene CHiCH (Ethine) (Ethyne)

Gos

5 ~

581

(2021

2.5

1.2

5.4

583 13061

No

1.1

2.7

124 (51)

Violent decomposition.

Do not use water

-118 (-83)

No

6

O

4

3

5

1

1

1

2

1

1

1

2

4

100

0.9

(305)

See Dichloroethylene-cis

Acetylene Dichloride-trans

See Dichlaroethylene-trans.

N-Aceîyl Ethanolamine CH3C:ONHCH2CH?OH [N-(Z-Hydraxyethyl) acetomidel

355 (179)

1.1

860 (460)

(04 1.1

N-Acetyl Morpholine 235 C H J C O N C H ~ C H ~ O C H ~ C H(1~13)

u

304-308 (1 5 1-1 53) @10mm Decomposes

Yes

Decomposes

Yes

2

5 2

See Acetic Anhydride.

--```,,`-`-`,,`,,`,`,,`---

Aceîyl Peroxide 25%solution in Dimethyl Phtholote (CH3C0)202

Note: See Hozordous Chemicals Dato.

Acetylphenol

See Phenyl Acetate

Acrolein CH2:CHCHO (Acrylic Aldehyde)

or foom

Note: Low pressure. Acetylene dissolved in acetone in closed cylinders can carry o 2 reactivity See Hozardous Chemicals Data.

Acehlene Dichloride-cis

Acetyl Oxide

~~

-15 (-26)

428 (220)

2.8

31

1.2

4.1

0.8

1.9

Explodes on heoting

125

Slight

Yes

1 5

4

3

3

304 (151)

Yes

5

1

2

1

2.5

287 (i 42)

Yes

5

3

2

2

1.8

171 (77)

Yes

1 5

4

3

2

509

No

1

O

2

1

(52)

Unstable Note: See Hazardous Chemicals Doto.

Acrolein Dimer (CH?:CHCHO)?

118 (48) (oc) Note: See Hazardous Chemicals Dato.

1.1

Acrylic Acid (Glacial) CHiCHCOOH

122 (50)

1.1

820 (438)

2.4

8.0

(4

Note: Polymerizes. See Hazardous Chemicals Data. Acrylic Aldehyde Acrylonitrile CH2:CHCN (VinylCyanide) (Propenenitrile)

See Acrolein. 32 101 (oc)

898 (481)

3.0

17

0.8

Note: Polymerizes. See Hozardous Chemicals Dota. Adipic Acid HOOC(CH2)4COOH

385 (196)

788 (420)

Adipic Ketone

See Cyclopentanone.

Adiponitrile NC(CH2)4CN

200 (93) (oc1 Note: See Hazordous Chemicols Dota.

1.37

5.04

(265)

(a 100

mm

1.0-

563 (295)

Slight

5

2


Not for Resale

NFPA 325 î4 --```,,`-`-`,,`,,`,`,,`---

325- 12

6474446 0528275 264


F W H IGNITION POINT TEMP. OF(%) "F("C)

FLAMMABLE Vapor LIMITS Sp. Gr. Densily (Air Percent by vol. (Water =i) =i) Lower Upper

BOILING ROINT "F("C)

Water Soluble

257-262 (125-128) @11 mm

Adipoyl Chloride ( - CHzCHzCOCIJz (Adipyl Chloride)

162 (72)

Adipyldinitrile CN(CH2)dCN (Adiponitrile) (Teiramethdene Diwonide)

199 (93) ( 4

Alcohol

See Ethyl Alcohol, Meihyl Alcohol, Denatured Alcohol, etc

Aldol CH3CH(OH)CHzCHO (3-Hydroxybutanol) (ß-Hydroxybuteraldehyde)

150 (66) (OC)

482 (250)

1.1

Allyl Acetate CH3COCH2CH CH2

72 (221

705 (374)

0.96

3.73

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth biiily tivily 5

2

2

4

2

O

563 (295)

No

3.0

174-176 (79-80) @12mm Decompases íg 176 (80)

Yes

5

3

2

2

0.9

3.45

219 (1041

No

5 1

1

3

O

70 713 2.5 18.0 (21) (3781 Note: See Hazardous Chemicals Doto.

0.9

2.0

206 (97)

Yes

1 5

4

3

1

2.2 22 -20 705 (-29) (374) Note: See Hazardous Chemicals Data.

0.8

2.0

128 (53)

Yes

1 5

4

3

1

1.4

4.2

160 (71)

No

5 4

3

3

1

367-370 (186-188)

No

5

1

2

O

(4

I I

Allyl Alcohol CH2:CHCHzOH Allylamine CH2:CHCHzNHi (2-Propenylamine) Allyl Bromide CHZ:CHCH2Br (3-Bromopropene)

30 (-1)

563 (2951

4.4

7.3

Allyl Caproate 150 CH~(CH~)~COOCH~CH:CHZ (66) (Allyl Hexonoaie) (2-Propenyl Hexonooie) Allyl Chloride CH2:CHCHzCI (3-Chloropropene)

-25 (-32)

0.9

737 (485)

Allyl Chlorocarbonate

See Allyl Chloroformaie.

Allyl Chloroformate CH2:CHCHzOCOCI (Allyl Chlarocorbonoie)

88 131)

2.9

11.1

0.9

2.6

113 (45)

No

5

3

3

1

1.1

4.2

223-237 (106-114)

No

5 4

3

3

1

3.4

203 (95)

Slight

5 1

3

3

2

No

3

2

2

1

1

3

3

2w

5

2

2

O

See Hazardous Chemicals Data. Allyl Diglycol Carbonate

See Diethylene Glycol Bis (Allylcarbonote)

Allylene

See Propyne.

Allyl Ether (CH2:CHCH2)20 (Diallyl Ether)

20 (-7) (oc)

0.8

Allylidene Diacetate CHz:CHCH(OCOCH3)2

180 (82) (oc1

1.1

Allyl Isothiocyanate

See Mustard Oil.

Allylpropenyl

See 1,4-Hexodiene.

Allyl Trichloride

See 1.2.3-Trichloropropane.

Allyl TrichIorosilane CH2:CHCH2SiClj

225 (107) @ 50 mm

95 (351 (oc1

Allyl Vinyl Eîher

See Vinyl Allyl Ether.

Alpha Methyl Fyridine

See Picoline-alpho.

1.2

6.05

243 ( i 17.5)

0.9

3.1

352 (178)

~

Aminobenzene

See Aniline

2-Aminobiphenyl

See 2-Eiphenylamine

1-Aminobutane

See Butylamine.

2-Amino-1 -Butanol CHJCH~CHNH~CH~OH

165 (74) (oc)

Amlnocyclohexane

See Cyclohexylamine.


Not for Resale

Yes

NFPA 325 94

I

rn 6474446 0528276

LTO

rn 325-13


FLAMMABLE Vapor FLASH ¡ONITION LIMITS Sp.Gr. Densiiy POINT TEMP. (Air Percent by vol. (Water 'F("C) "F("C) Lower Upper =i) =i) 1-Aminodecane

See Decylomine.

Amino Ethane

See Ethylomine.

2-Aminoethanol

See Ethanolamine.

1-Amino-4-Ethoxybenzene

See p-Phenetidine.

ß-AminoethylAlcohol

See Ethanolamine.

(2-Aminoethyl) Ethanolamine NHzCZH~NHCZH~OH

270 (132)

1.0+

695 (368)

BOILING POINT "F("C)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth biiiiy tiviiy

470 (243)

Yes

5 2

2

1

O

4-(2-Aminoethyl)Morpholine C~H~OC~HANC?HANH?

1.0

4.5

395.6 (202.8)

Yes

5

2

2

O

1-(2-Aminoethyl)200 Piperazine (93) (Oc) H~NC~H~NCH~CHZNHCHZCHZ

1.0-

4.4

432 (222)

Yes

5

2

2

O

0.9

3.0

329 1165)

Yes

5

2

2

O

423 (217) @ 100

Yes

5 2

2

1

O

Yes

5

2

2

O

Yes

5

2

2

O

438 (2261

Yes

5 2

2

1

O

-28

Yes

6

3

1'

O

See Heotvlamine. See 1-Amino-Z-Proponol.

2-Amino-4-Methvl-wntane

See 1.3-Dimethvlbutvlamine.

--```,,`-`-`,,`,,`,`,,`---

1-AminoheDtane adminolsopropylAlcohol

2-Amino-2-Methyl-1 Propanol íCH3)zC("z)CHzOH

-

153 167)

1-Aminooctane

See Octylamine.

2-Aminopentane

See sec-Amylamine.

p-Aminophenetole

See p-Phenetidine.

(m-Aminophenyl) Methyi Carbinol N~zCq"[CHlOH)CH31 (m-Amino-a-Methylbenzyl Alcohol)

315 (157)

1.1

(4

1-Amino-2-Propanol NHzCHzCHOHCH3 (a-AminoisopropylAlcohol) (Isopropanolomine)

171 (77)

N-(3-Aminopropyl) Cyclohexylamine C6HllNHCjH6NH2

175 (79) (oc)

mm

705 (374)

N-(3-Aminopropyl) 220 Morpholine (104) CZH=~OCZH~N(CHZ)~NHZ (04 Ammonia, Anhydrous "3

1.0-

2.6

0.9

5.4

320 (160)

1.0-

Gas

1204 15 28 0.7@ 0.6 (651) - 33°C Note: See Harordous Chemicols Data. 'This gas is "1" insteod of "4" because it is hard to burn.

Amoxybenzene

See Amyl Phenyl Ether.

Amyl Acetate CH3COOC5Hi 1 (1-Pentanol Acetate) Comm.

60 (16) 70 1211

sec-Amyl Acetate CH3COOCH(CH3)(CHdzCH3 (2-PentanolAcetate)

89 (32)

Amyl Alcohol CH~(CHZ)~CHZOH (1-Pentanol)

91 (33)

572 (300)

1.2

%-Amyl Alcohol CH3CH2CH2CH(OH)CH3 (Diethyl Carbinol)

94 (34)

650

1.2

(343)

680 (360)

1.1

7.5

10.0

0.9

4.5

300 (149)

Slight

1 5

1

3

O

0.9

4.5

249 (121)

Slight

1 5

1

3

O

0.8

3.0

280 (138)

Slight

5

1

3

O

0.8

3.0

245 (118)

Slight

1 5

1

3

O

@

212 (100) 9.0

I- 33)


Not for Resale

NFPA 325 94 325- 14

6474446 0528277 037


FIAMMELE Vamor FLASH IGNITION Sp. Gr. Den& LIMITS POINT TEMP. Percent by Vol. (Water (Air =1) =1) Lower Upper “F (“C) ”F (“C) Amylamine C5H1lNHZ (Pentylamine)

30 (-11

sec-Amylamine W(CHz)zCHICWW (2-Aminopentane) (Methylpropylcarbinylamine)

20 (-7)

2.2

22

0.8

0.7

3.0

3.0

BOILING POINT OF (“C)

Water Soluble

210 (991

Yes

198 (92)

Yes

498-504 (259-262)

No

365 11851

No

128-9 (53-54) í@ 746 mm

No

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD IDENTIFICATION METHODS Flamma- ReacHealth bilhy thriîy

2

3

O

5 1

2

3

O

2

3

1

O

1

2

O

4

1

3

O

1

5

p-tart-Amylaniline 215 (CZH~)(CHZ)ZCC~H~~HZ (1021

0.9

Amylbenzene C6HsCsHiI (Phenylpentane)

150 (66)

0.8-0.9

Amy¡ Bromide CH3CHzCHzCHzCHzBr (1-8romopentone)

90 (32)

1.2

Amyl Butyrate C~HI~OOCC~H~

135 (57)

0.9

5.46

365 (185)

No

5

1

2

O

Amyl Carbinol

See Hexyl Alcohol.

Amyl Chloride CH~(CHZ)~CHZCI (i -Chloropentane)

55 (13) (oc1

(04

tert-Amyl Chloride CH,CHZCCI(CH~)CH~ Amyl Chlorides (Mixed) C5HiiCI

500 (260)

1.6

8.6

0.9

3.7

223 (106)

No

1

1

3

O

653 (345)

1.5

7.4

1.4

3.7

187 (861

No

3

1

3

O

0.9

185-228 (85-109)

No

1

1

3

O

0.8

395 (202)

1

38 (3) ( 4

Amylcyclohexane c5HI Ic6HI I

462 (239)

Amylene

See 1-Pentene.

Ø-Amylene-clr

< -4

CzH5CH:CHCH3 (i-Pentene-cis) ß-Amylene-trans CzH5CH:CHCH3 (2-Pentene-trans) Amvlene Chloride

Amyl Ether C5HiiOC5Hii (Diomyl Ether) íPentvloxvoentanel

5.1

0.66

2.42

99 (37)

O

4

0.67

2.42

97 (36)

O

4

0.8-0.9

5.5

374 (190)

No

5

1

2

O

No

1

1

3

O

1

2

O

(<-20) <-4 ( < -20)

O

See 1.5-Dichloropentane. 135 157)

(4

338 11701

Amyl Formate HCOCC5Hii

79 (261

0.9

4.0

267 (131)

Amyl Lactate C~H~OCOOCHZCH(CH~)CZH~

175 1791

1.0-

5.5

237-239 (114-115) @ 36 mm

Vev slight

Amyl Laurate CiiHz3COOC5Hii

300 (149)

0.9

554-626 (290-330)

No

2

O

1

O

Amyl Maleate

270 (132)

1.0-

518-599 (270-31 5)

No

2

O

1

O

65 (18) (oc)

0.8

2

3

(CHCOOC5HiI)Z

Amyl Mercaptan (n) WiiSH (i -Pentanethiol)

Amyl Mercaptans (Mixed) CHdCHz14SH

Amyl Naphthalene CioHrC5Hii

Amyl Nitrate CH3íCHzhN03

3.59

65 0.8 (181 (oc) Note: See HorordousChemicals Doto.

260 (127) 176-257 (80-1 25)

No

1

2

3

O

2

O

1

O

2

2

oox

255 (124) locl

1.0-

550 (288)

No

118 (48)

1.o-

306-315 (153-1 57)

No

--```,,`-`-`,,`,,`,`,,`---

(oc)


Not for Resale

NFPA 325 94

b47444b 0528278 T73 325-15


FLASH POINT "F ("C) Amyl Nitrite CH3íCHhNOz

FLAMMABLE Vapor Sp. Gr. Density IGNITION LIMITS (Air TEMP. Percent by vol. (Water "F ("C) Lower Upper = 1) '1) 0.9

410 (210)


220

4.0

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZIIRD METHODS IDENTIFICATION Flamma- ReacHealîh blllty tivily

Slight

5

1

2

(104)

Amyl Oleate Ci7H33COOC4-i I

366 11861

0.9

392-464 (200-240) @ 20 rnm

No

2

O

1

O

Amyl Oxalate ICOOCsHi112 IDiamvl Oxalate1

245 (118)

1.0-

464-523 (240-273)

No

2

O

1

O

1.0-

455-482 (235-250)

Slight

5

2

1

O

2

p-terbAmyl Phenol

See Peniaphen.

p-sec-Amylphenol C5HiiCaH4OH

270 (1 32)

1.o-

482-516 (250-269)

No

2

1

1

O

2-(p-teri-Amylphenoxy) ethanol C ~ HiCaH40CHzCHzOH I

280 (138)

1.0+

567-590 (297-310)

No

2

1

1

O

Z-(p-teri-Amylphenoxy) ethyl Laurate C i IHz3COOICHz)zOC6H&Hi I

410 (210)

0.9

464-500 (240-260) @6mm

2

O

1

O

p-teri-amyl phenyl Acetate CH3COOC6H4C5HiI

240 (116)

1.0-

507-51 1 (264-266)

2

O

1

O

p-teri-Amylphenyl Butyl Ether CSHII C ~ H ~ O C ~ ~

275 11351

0.9

540-550 (282-288)

No

2

O

1

O

185

0.9

421-444 (216-229)

No

O

2

O

O

1

O

O

2

O

Amyl Phenyl Ether CHdCHd40C6H5 IAmoxvbenrenel , .

(85)

p-teri-Amylphenyl Methyl Ether

21O 1991

Amyl Phthalate

See Diamyl Phtholoie.

Amyl Propionate C2H5COO(CH2)4CH3 (Penty Propionole)

106 (41)

712 13781

(04

Amyl Salicylate H O C ~ H ~ C O O CI ~ H I

270 (132)

Amyl Stearate CHdCHdiaCOOC5Hi I

365 (185)

.

5.7

0.9

462-469 1239-243)

0.9

275-347 (135-175)

No

1.1

512 (2673

Na

2

O

1

O

0.9

680 (360)

No

2

O

1

O

[oc)

Amyl Sulfides, M i e d WIIS

185 (85)

09

338-356 (i 70-1 80)

No

2

2

O

Amyl Toluette CSHI~C~H~CH~

180 (82)

0.9

400-415 (204-213)

No

2

2

O

1.1

334 (168)

3

2

2\41

0.9

480-500 (249-260)

2

1

O

3

2

O

3

1

(oc1

Amyl Trichlorosilane C=,HS iC i3 l

145 (63)

Amyl Xylyl Ether &Hi I~C&(CHS)Z

205 (96)

(oc1

No

(oc1

158 1139 1.3 1.1 (70) 1615) Noie: See Hazardous Chemicals Data.

1.0+

3.2

364 (184)

Aniline Hydrochloride CaH5NH2HCI

380 (1931

1.22

4.46

473 12451

Slight

5

--```,,`-`-`,,`,,`,`,,`---

~

Aniline Cab"? (Aminobenzene) (Phenylamine)

(04

Nole: Melting poini 389 (198).


Not for Resale

NFPA 325 94 m b47444b O528279 90T m 325-16


FLAMMABLE Vawr F W H IGNITION LIMITS Sp. Gr. Densiiy (Air POINT TEMP. Percent by vol. (Water Lowar Upper =1) =1) O F ( % ) "F("C) 2-Anilinoeihanol C~H~NHCH~CHZOH (8-Anilinoeihanol Ethoxyaniline) lß-Hydron/elhylaniline)

305 1152) (oc)

ß-Anilinoethanol Eihoxyanillne

See 2-Anilinoethanol.

o-Anisaldehyde

See o-Methoxy Benzaldehyde,

o-Anisidine H~NC~HAOCH~ 12-Methonianilinel

244 (1 18) locl

Anisole C6H50CH3 (Methokybenzene) (Methyl Phenyl Ether)

125 (52) (oc)

Ano1

See Cyclohexonol.

Anthracene (C6H4CH)z

887 (475)

BOILING POINT ' O F ("C)

1.1

547 (286)

Very slight

2

2

1

O

1.1

435 1224)

No

5 2

2

1

O

No

1

2

O

O

1

O

1

1.0-

3.7

309 (154)

250 1004 0.6 (121) WO! Note: Melting point 423 (217).

1.24

6.15

644 (340)

Anthraquinone C6Hr(COhC6H4

365 (185) Note: Melting paint 354 (179).

1.44

7.16

716 (380)

Anificial Almond Oil

See Benzoldehvde

Asphalt (Cutback)

c 50 10)

Asphalt, liquid-Medium Curing

100 138)

No

No

2

O

3

O

No

2

O

2

O

Na

2

O

3

O

No

2

O

2

O

Grode SC-250

O

2

O

Grade SC-800

O

1

O

Grode SC-3000

O

1

O

O

1

O

(min)

Grades MC-30 and MC-70

150 166)

(min)

Grades MC-250; MC-800; and MC-3000

80 127)

(min)

Grades RC-250; RC-800; and RC-3000

(4

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility tivity

(4

Asphalt, üquld-Rapid Curing Asphalt, Liquld-Slow Curing

(4

150 + (661 ( 4 175+ (791 . .

(04

ZOO+

Grode SC-70

(93) ( 4

225+ 1107)

(04 Asphalt (Typical) (PetroleumPitch)

400+ (204+)

905 (485)

Aziridlne

See Ethvleneimine

Azobisirobutyronltrile N:CC(CH&N:NC(CH3)7C:N

147 (64 Note: Melting paint 221 (105)

Azole

See Rirrole

Banana Oil

See Isoamyl Acetate

Benzaldehyde CbHsCHO (Artificial Almond Oil) (Benzenecarbonal)

145 (63)

377 1192)

Benzedrine <212 C~H~CHZCH(CH~)NHZ ( < 100) (1-Phenyl Isopropyl Amine) Benzene c6H6 (Benzol)

See Benzaldehyde.

Benzene Carbonyl Chlorlde

See Benzoyl Chloride.


1.1

3.7

>700 (2371)

No

Decomposes

No

355

No

2

3

3

2

2

2

O

1

2

3

O

(179)

0.93

12 928 1.2 7.8 0.9 (-11) (498) Note: See Hazardous Chemicals Data.

Benzenecarbonal

1994 Edition

1.o-1.1

4.67

2.8

392 (200) 176

(80)

--```,,`-`-`,,`,,`,`,,`---

Not for Resale

No

1

O

NFPA 325 94

m 6474446

0528280 621

m 325- 17


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Or. Density POINT TEMP. Percent ir, vol. (Water (Air =i) =1) "FCC) "FCC) Lower Upper Benzine

See Petroleum Ether.

Benzocyclobutene

95 1 .351.

Benzoic Acid C6H5COOH Benzol Benzol Diluent

477 1 . 2471.

250

1058

(121)

WO!

0.96 1.27

BOILING POINT 'FCC)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD IDENTIFICATION METHODS Flammo- ReocHealth biiity tivity

306 I .1521. 4.21

482 (250)

Slight

2

1

2

3

O

1

2

1

Note: Melting point 252 (122). See Benzene

-25

(-32)

450 (232)

1.0

7.0<1

140-210 (60-99)

Na

1

Note: Flash point and ignition temperature will vaty depending o n the monufodurer.

Benzotrichloride C6H5CC13 (Toluene, a, a, a-Trichloro) [Phenyl Chloroform)

I

I

I

Benzotrifluoride CaH5Ch Benzoyl Chloride CsHsCOCI Benzene Corbonvl Chloride)

100-200 (38-93)

1040 (560)

1.3

3.7

Sublimes

No

429 (22 1 )

Na

2

3

1

O

4

3

3

1

3

2

2w

Note: Melting point 234-237 (1 12-1 1 4).

260 (127)

412 (211)

1.4

54

1.2

5.0

216 (102)

No

1.2

4.9

387 (197)

Decomposes

(1 2 ) Note: See Hazardous Chemicals Doto.

162 (72)

Decomposer in water

Note: See Hozardous Chemicals Dato. Benzyl Acetote CH~COOCH~C~HS

195 (901

860 (460)

1.1

41 7 (214)

Slight

5 2

1

1

O

Benzyl Alcohol C6H5CHzOH (Phenyl Carbinol)

200 (93)

817 (436)

1 .o+

403 (206)

Slight

5

2

1

O

Benzyl Benzoate CsHsCOOCH&Hs

298 (148)

896 (480)

1.1

614 (323)

No

2

1

1

O

Benzyl Butyl Phthalate CiH&OOC6H4COOCH2c6H5 (Butyl Benzyl Phthalate)

390 (199)

1.1

698 (370)

No

2

1

1

O

Benzyl Carbinol

See Phenethyl Alcohol.

Benzyl Chloride C~HSCH~CI (a-ChIorotoluene)

354 11791

No

3

3

2

1

Note: See Hazardous Chemicals Doto. Na

5 2

2

1

O

405-420 (207-216)

2

2

O

383 (195)

2

2

Benzyl Cyanide CaH5CH2CN (Phenyl Acetonitrile) (a-Talunitrile)

153 1671

1085 (5851

1.1

1.1

4.4

452 (233.5)

1.0+

235 (113)

(04 0.9

Benzyl Ether

See Dibenzyl Ether.

Benzyl Mercaptan CsHsCHzSH (a-Taluenethiol)

158 (70)

1.06

Benzyl Salicilate >212 O H C ~ H ~ C O O C H Z C ~ H ~( Z 100) [Salycilic Acid Benzyl Ester)

4.28

1.2

Bicyclohexyl iCH2(CH214CHI2 (Dicyclahexyl)

165 (74)

473 (245)

0.7 íG 212 (100)

5.1 C@ 302 (1 50)

0.9

Biphenyl CaHsCbHs (Diphenyl) (Phenylbenzene)

235 (113)

1004 (540)

0.6

5.8

1.2

8

@

2-Biphenylamine NH~C~H~C~HS (2-Aminobiphenyll

2

5.7

406 (208)

Na

5

1

1

O

462 (239)

Slight

5

1

2

O

489 (254)

No

2

2

1

O

570 (299)

No

2

2

1

O

232 311 [ill) (155) Note: Melting point 158 (70). 842 (4501, Note: Melting point 121 (49).

5.8


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

p-Benzoquinone Cd402 (Quinone1

b47444b 0528281 568

NFPA 325 94 325- 18


FLASH POINT "FCC) Bis (p-tert-Butylphenyl) phenyl Phosphate

FLAMMABLE Vapor IGNITION LIMITS Sp.Gr. Densiiy (Air TEMP. Percent by vol. (Water "F CC) Lower Upper =i) =1)

482

BOILING POINT "F ("C)

500-527 (260-275)

1.1

(2501

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Flamma- ReacHealth biliiy tMiy

1

O

2

1

O

2

2

O

2

1

O

5 2

1

1

O

2

1

1

O

5 2

2

1

O

5

3

1

O

1

1

O

O

1

O

No

2

237 (1 14)

Slight

5

353 (178)

Very slight

425 (218)

Very slight

@5mm

(C~H~C~H~~)ZPOOC&

> 250 (>121) (CH~CICH~OCHZCHZI~O

Bis [2-(2-Chloroethoxy) ethyl] Ether

1.2

2

(TetraglycolDichloride) Bis (2-Chloroethyl) Ether

(CH2CICH2)20 (Chlorex) Bis (2-Chloroethyl) Formal

CH2(0CHzCHzCl)z (Di-(2-Chloroethyl) Formal) (2,l-Dichloroethyl Formol)

131 (551

1.2

230 (1 10)

1.2

4.9

5 2

(oc)

Bis (p-Chloroisopropyi) Ether

See Dichloroisapropyl Ether

Bir-Diethylene Glycol Monoethyl Ether Phthalate

405 (207)

1.1

290

O.?

500 12601

C6H4(COOC2H4OC2H4Oc2Hd2 Bis (2.4-Dimethylbutyl) Maleate

394

(1 43)

No

(201) @ 50 mm

( 4

[(CH3)?CHCH2CH(CH& OCOCH:]? (Di(Methylamy1)Maleate) N,N'-Bis-( 1.4-DimethylPenMPPhenylenediamine

347 (175)

770 (410)

0.9

(oc)

C*Hd[NHCH(CH3)CH2CH2CWHd212 1.3-Bis (Ethylamino) Butane

See N,N-Diethyl-l,3-8utanediomine.

Bis (2-Ethylhexyl) Amine

270 [C~H~CH(CZH~)CHZ~Z~ ( 1 H321

0.8

537 (281)

Slighi

421 (2161

Slight

2

IOCI

(Diethylhexylamine) (Diodylamine)

280

Bis (2-Ethylhexy1)Ethanolamine

0.9

(138)

5

2

@ 50 mm

IC~H~CH(CZH~CH~IZNCiH4OH (Diethylhexylethanolamine) Bis (2-Ethylhexyl) Maleate

365 C ~ H ~ ~ O C O C H : C H C O O C B(185) H~~

408

0.9

No

5 2

No

5

(209)

(Di(?-Ethylhexyl)Maleote)

@lOmm

BIS(2-Ethylhexyl) Phosphoric Acid

1.0-

385 (194

IC~H~CH(CZHS)CHIZHPO~

2

(OC)

(Di(?-Ethylhexyl)Phosphoric Acid) Bis (2-Ethylhexyl) Succinate

(clOH 1902)Z

(Dill-Ethylhexyl) Succinate) N,N-Bir (1-Methylheptyl) Eihylenedlamine

31 5 (157)

0.9

495 (257)

>400

0.8

424 (218) @ 43 mm

( > 204)

HC(CHj)(CbHlj)NHCH2CHz"CH(CHd(CaH I 3) Bis (ß-Methylpropyl) Amine

See Diisobutylomine.

BIS (2,2,4-Trimethylpentanediolisobutyrate) Diglycolate

383 (1 95)

639 (337)

1.1

(oc)

CZaH2709 Blast-furnace Gas

See Gas.

Borneo Camphor

See 8orneol


Slight

5 2

O

1

O

No

2

O

1

O

2

O

1

O

@ 50 mm

--```,,`-`-`,,`,,`,`,,`---

Not for Resale

NFPA 325 94 M b 4 7 4 4 4 b 0528282 4 T 4 M 325-19


FLAMMABLE Vapor LIMITS Sp. Gr. Density FLASH IGNITION POINT TEMP. Percent by vol. (Water (Air Lower Upper =1) =1) O F ( % ) "F ("C) Borneol CioHi70H (Borneo Camphor)

150 (66)

1.0+

Boron Trifluoride Nheraie CH~CH~O(BF~)CHZCH~

147 (641 (oc)

1.1

Brandy

See Ethyl Alcohol and Water.

Brazil Wax

See Carnauba Wax

Bromobenzene C&i@r (Phenyl Bromide)

124 (511

1049 (5651

1-Bromo Butane

See Buh4 Bromide

4-Bromodiphenyl C&C&I&

291 (144)

Bromoethane

See Ethyl Bromide

Bromomcthane

See Methvl Bromide.

1-Bromopentane

See Amyl Bromide

3-Bromopropene

See Allyl Bromide.

1.5


2

O

No

2

259 (1261

Decomposes

3

313 (1561

No

3

2

2

O

592 (311)

No

2

2

1

O

413 (2121 Sublimes

5.4

Waler Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HURD METHODS IDENTIFICATION Flamma- ReacHeallh biiity livity

2 1W Decomposesin water.

o-Bromotoluenc BrCaH4CH3

174 (791

1.4

5.9

359 (1821

No

3

2

2

O

p-Bromololuene BrC6H4CH3

185 (851

1.4

5.9

363 (1841

No

3

2

2

O

6

2

4

2

Bronzing Liquid

May be below 80 (27).

1.3-Butadlene CH2:CHCH:CH2 (Ervthrene)

788 2.0 12.0 1.9 Gas (420) Note: Polymerizes. See Hazardous Chemicals Dato.

Butadiene Monoxide CHz:CHCHOCH2 (Vinylethylene Oxide)

No

< -58

0.9

24 (-4)

See Butyraldehyde

Butanal Oxime

See Butyraldoxime

Butane CH3CHzCHzCH3

-76 (-60)

550 (287)

1.9

8.5

1

2.4

151 (66)

2.0

31 (-1)

No

6

1

4

O

Yes

5

3

2

O

(<-50)

Butanal

No

1.3-Bulanediamine NHzCHzCHzCHNHzCH3 (1,3-Diominobutane)

125 1521 (oc)

0.9

3.0

289-302 (143-150)

1.2-Butanediol CH3CH2CHOHCH20H (1,Z-Dihydroxybutane] (Ethvlethvlene Glvcoll

104 (401

1.0

3.1

381 (194)

Slight

5

1

2

O

1.0+

3.1

442 (2281

Yes

2

1

1

O

363 (1841

Yes

5

1

1

O

1,3-Butanediol

See ß-ButyleneGlycol.

1A-Butanediol HOCHiCHzCH?CH?OH

250 (121) (oc) Note: Melting point 64-66 (18-19).

2,3-Butanediol CHqCHOHCHOHCHq

756 14021

1.0+

5

2,3-Butanedione CH3COCOCHj (Diacetyl)

80 (27)

1.0-

3o

190 (881

Yes

5

1

3

O

1-Bvianeihiol CH3CHzCHzCH?SH (Butyl Mercaptan)

35 (21

0.8

3.1

208

Slight

5 1

2

3

O

2-Bulanelhiol C4HpSH (sec-ButylMercopton)

í - 23)

-10

0.8

No

5 1

2

3

O

1-Butanol

See Butyl Alcohol.

2-Butanol

See sec-Butyl Alcohol.

2-Bulanone

See Methyl Ethyl Ketone.

2-Butenal

See Croionaldehvde

(981 3.1 1

185 i851

--```,,`-`-`,,`,,`,`,,`---


1994 Edition

Not for Resale

NFPA 325 9 4 325-20

m


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by Vol. (Water (Air "F("C) "FrC) Lower Upper =1) =1)

1-Butene CH3CHzCH:CHz (a-Butylene)

Gas

725 (3851

1.6

10.0

2-Butene-cis CH3CH:CHCHs

Gas

617 (325)

1.7

9.0

2-Butene-trans CH3CH:CHCH3 (ß-Butylene)

Gas

615 (3241

1.8

9.7

Butenediol H0CHzCH:CHCHzOH (2-Butene.l.4-Diol)

263 (128)

2-Butene-1 A-Diol

See Butenediol

2-Butene Nitrile

See Croiononitrile.

Butoxrbenzene

See Butvl Phenyl Ether.

1-Butoxybutane

See Dibutyl Ether.

2.8-Butoxyethoxyethyl Chloride CdH9CH2CH2OCH2CH2CI

(88)

21 (-6)

1.9

38.7 141

1.9

-34 (11

1.1

3.0

286-300 (141149) @ 20 mm

1.0

6.1

0.6

(oc)

190

Water Soluble No

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- Reactivity Health bility 6

1

4

O

6

1

4

O

No

6

1

4

O

Yes

2 5

1

1

O

2

2

O

2

1

O

2

O

1

O

2

2

1

O

2

2

1

O

1

1

3

O

392-437

(200-225)

1-(Butoxyelhoxy)-2P10 panoI CH~CH(OH)CHZOC~H~OC2H4GH5

250 (121)

Butoxyethyl Diglycol Carbonate

See Diethylene Glycol Bis (2-ButoxyethylCorbonote)

ß-Butoxyethyl Salicylate OCHaHaCOOCHKH7OCaHs

315 (157)

Butoxyl

See 3-Methoxybutyl Acetate.

N-Butyl Acetamide CHsCONHCdHp

240 (116)

509 (265)

0.9

445 12291

Yes

l.O+

367-378 (186-192)

No

0.9

455-464 (235-240)

1.0-

531-538 (277-281)

5

2

(04

N-Butylacetanilide 286 CH~(CHZ)~N(C~H~)COCH (141) ~

sec-Butyl Acetate CH3COOCH(CH3)C?H5


1.9

Note: Melting poini 45 (7).

Butyl Acetate CHjCOOCdH9 (Buiylethanoate)

m

b 4 7 4 4 4 b 0528283 330

72

(22)

797 (425)

a8

1.7

1.7

7.6

9.8

0.9

4.0

No

260 11271

Slight

5

0.9

4.0

234 (1121

Slight

1 5

1

3

O

1.0-

5.5

417 12141

Slight

5

1

2

O

428 (2201

No

2

2

1

O

2

2

2

(31) IOCI

Butyl Acetoacetate 185 C H ~ C O C H Z C O O ( C H ~ ) ~ C H(85) ~ (oc1

Butyl Acetyl Ricinoleate CI~H~Z(OCOCH~IICOOGHsI

230 (110)

725 (385)

0.9

Butyl Acrylaie CH2 CHCOOC4H9

a4 (29)

559 (292)

17

99

o9

44

260 11271 Polymerizes

Na

Butyl Alcohol CH~(CH~)ZCH~OH (1-Butanol) (Propylcarbinol) (Propyl Methanol)

98 (37)

650 (343)

1.4

11.2

0.8

2.6

243 (117)

No

1 5

1

3

O

sec-Butyl Alcohol CH3CHzCHOHCH3 (2-Butanol) (Methyl Ethyl Carbinol)

75 (24)

761 (4051

9.8

0.8

26

201 (94)

Slight

1 5

1

3

O

teri-Butyl Alcohol (CH3)2COHCH3 (2-Methyl-2-Propanol) (TrimethylCarbinol)

52 (11)

10 (-12)

~

Butylamine C.iHp"2 (1-Amino Butane)

@

4 212 (100)

892 (478)

2.4

8.0

0.8

2.6

181 (83)

Yes

1 5

1

3

O

594 (312)

1.7

9.8

0.8

2.5

172 (78)

Yes

1 5

3

3

O

--```,,`-`-`,,`,,`,`,,`---

I

1.7 212 (100)


Not for Resale

b47444b 05213284 277

NFPA 325 94

325-21


FLASH IGNITION POINT TEMP. “F (“C) “F (“Cl sec-Butylamine CH3CH&H(NH?)CH3

FLAMMABLE Vasor LIMITS Sp.Gr. Den& Percent by vol. (Water (Air l o w e r Upper =1) =i)

16 1-91

tert-Butylamine íCH3)3C“i

716 13801

17

89

C

@

212 11001

212 110OI

BOILING POINT “F (“C)

072

252

145 (63)

O7

25

113 (45)

Butylamine Oleate 150 Ci ~ H ~ ~ C O O N H ~ C ~ H T (661

0.9

tert-Butylaminoethyl Methacrylate (CH~)~CNHC~HAOOCC(CH31:CH?

0.9

Waier Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Flamma- ReacHealth billty tivity

3

3

Yes

5

2

4

O

Yes

5

3

2

O

2

1

O

3

1

O

(4

205 1961

200-221 (93-105)

5.5

(4

N-Butylaniline CaHsNHC4H9

0.9

Butyibenzene C6H5C4H9

160 1711

770 (410)

tart-Butylbenzene C6H5C(CH3)3

140 1601

842 (450)

(4

(04

0.8

0.7

@ 212 (100)

Butyl Benzyl Phthalaîe

465 1241)

Slight

5 2

5.8

0.9

4.6

356 1180)

No

2

2

O

5.7

0.9

4.6

336 1169)

No

2

2

O

482 1250)

No

1

1

O

O

1

8

212 (100) 1 .o

2-Butylbiphenyl C6H5.C6H4.C4Hp

No

2

See Benzyl Butyl Phthalate.

> 212 (>loo)

Butyl Bromide CH3(CH2)?CH?Br (1 -Bromo Butane)

65 1181

Butyl Butyrate CHJ(CH~)ZCOOC~H~

128 153)

806 (430) 509 1265)

- 554

7.26 [

2.6

@? 212 11001

6.6

- 290)

1.3

4.7

215 11021

No

4

2

3

O

0.9

5.0

305 1152)

Slight

5

2

2

O

0.8

3.0

237 1114)

Slight

1 5

2

3

O

545 12851

No

2

2

1

O

No

1

2

3

O

C 212 11001

¡oc)

Butylcarbamic Acid, Ethyl Esler

See N-Butylurethone.

tert-Butyl Carbinol (CH3)3CCH?OH (2.2-Dimethyl- 1 -Propanol) B u h l Carbitol

98 137) See Dieihvlene Glvcol Monobutvl Ether.

1 Butyl Chloride C4H9CI ( 1-Chlorobutane)

15 1-91

sec-Butyl Chloride CH3CHCIC2H5 (2-Chlorobutane)

(
tert-Butyl Chloride lCH3ì3CCI

< 32 (
(2-Chloro-2-Methyl-Proprine)

< 32

464 1240)

1.8

10.1

o+

0.9

3.2

170 177)

0.87

3.20

155 168)

2

3

0.87

3.20

124 (51)

2

3

2

1

O

2

2

O

2

1

O

1.1

453-484 (234-251)

No

1.0-

451-469 (233-243)

No

1.0-

278-280 (137-1 38)

No

2

2

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94 W 6474446 0528285 L O 3 325-22


FLASH POINT OF

I"C)

FLAMMABLE Vapor IGNITION LIMITS Sp. Gr. Density TEMP. Percent by vol. (Water (Air "FC'C) Lower U m e r =1) =1)

BOILING POINT

"F ("Cl

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHeaith bility tivity

Butylcyclohexane CaHvCaHi 1 (1 -CycLhexylbutane)

475 (2461

0.8

352-356 ( I 78-1 80)

O

O

sec-Butylcyclohexane C H ~ C H ~ C H ( C H ~ )1C ~ H I (2-Cyclohexylbutane)

53 1 (277)

0.8

351 (177)

O

O

ieri-Butylcyclohexane ( C H ~ ~ C Ci~ H I

648 (342)

0.8

333-336 (167-169)

O

O

0.8

409 (209)

0.8

314 (157)

N-Butylcyclohexylamlne CaHi i"(C4H9)

200 (93)

Slight

5

2

1

O

(4 Buîylcyclopentane W9GHv

480 (250)

O

O

Buîyldecalln C4WioHi7

500 (260)

2

1

1

O

tert-Butyldecalin CaHvCioHi7

640 (338)

2

1

1

O

285 (141)

504 (262)

Yes

5 2

2

1

O

1.0-

329-338 (165-170) 8 33 mm

Yes

2 5

2

1

O

O

2

1

1

O

2

2

3

2

(04 Note: Melting point I l 7 (47).

Butyl Diglycol Carbonate

See Diethylene Glycol Bis (Butyl Carbonate).

a-Butylene

See 1 -Butene.

ß-Butylene

See 2-Butene-trans.

y-Butylene

See 2-Methylpropene.

a-Butylene Glycol C~H5CHOHCH~OH I1 ,2-Butanediol) p-Butylene Glycol CH3CH(OH)CHzCHzOH (1.3-8utanediol) Butylene Glycol (pseudo)

CH3(CHOH)zCH3 (2,3-Butanediol) (Dihydroky Butane 2.3)

194 (90) 250

(121)

1.01

3.10

1 .o

743 (395)

185 (85)

1.01

377 (1 92) 399 (204)

3.10

Yes

5 2

356

--```,,`-`-`,,`,,`,`,,`---

leri-Butyldi~hanolamine C8HioNOz [2.2-(tert-Butylimino) Diethanal]

1.0-

O

( 1 80)

( 4

2,3-Butylene Oxide CHjHCOCHCHj

5 (-15)

822 (439)

1.5

18.3

1,2-Butylene Oxide HzCOCHCHzCH3

-7 (-22)

822 (439)

1.7

19

0.83

2.49

149 (651

Slight

0.8

2.2

145 1631

Yes

5 1

2

3

2

09

40

377

Yes

5

1

2

O

Yes

1 5

2

3

O

O

2

1

4

Noie: See Hazardous Chemicals Data. Butyl Ethanedioate N-Butyl Ethanolamine CH3(CH2)3NHCHzCHzOH

See Butyl Oxalate.

170 (77)

(i92)

(oc) Butyl Ether

See Dibutyl Ether.

Butylethylaceîaldehyde

See I-Ethylhexonal.

Butyl Ethylene

See 1 -Hexene.

Butyl Elhyl Ether

See Ethyl Butyl Ether.

Butyl Formate HCOOCaH9 IButvl Methanoate) (Formic Acid, Butyi Ester)

64 (181

612 (322)

1.7

8.2

0.9

3.5

4.45

Butyl Glycolate CHzOHCOOC4Hv

142 (61)

1.01

teri-Buiyl Hydroperoxide (CHJJ~COOH

< 80 or above

0.9

i< 27)

2,2-(Buhlimino) Dielhanol

See tert-Butvldiethanolamine.

-356 (-180) Slight

Note: May explode See Hazardous Chemicals Dota.


225 (107)

Not for Resale

5

40x

NFPA 325 94

= b 4 7 4 4 4 b O526266

04T 325-23

PKOPERI'IES O F FLAMMABLE LIQUIDS, GASES, VOLATILE SOLIDS

FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol. (Water (Ali 'F("C) Lower Upper =i) =i) 'F("C)

BOILING POINT 'FCC)

Water Soluble

--```,,`-`-`,,`,,`,`,,`---

2

2

1

2

O

2

2

O

5

1

2

O

No

2

1

1

O

277 11361

No

1

1

3

3

486

No

2

1

1

O

n-Butyl Isocyanate CHB(CHZ)~NCO (Butyl Isocyonote)

66 (19)

0.9

3.00

235 (113)

Butyl Isovalerale C4HpOOCCHzCH(CH3)2

127 (53)

0.87

5.45

302 (150)

Butyl Lactate CH3CH(OH)COOC4H9

160 (71) (oc)

1.0-

5.0

320 1160)

Slight

Butyl Mercaptan

See 1-Butonethiol.

tert-Buiyl Mercaptan

See 2-Meihyl-2-Proponethiol. 0.9

4.9

325 063)

No

0.9

4.0

378 1192)

Yes

Butyl Meihacrylaie CH~:C(CHO)COO(CHz)3CH3

720 (382)

126 1521 (04

Butyl Meihanoate

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING "XRD METHODS IDENTIFICATION Ramma- ReacHealth bility iivity

Rends

5

3

O 5

See Butyl Formole.

N-Butyl Monoeihanolamine C~H~NHCZH~OH

170 177)

id

Butyl Naphthalene C~H~CIOH~

680 13601

Butyl Nitrate CHiICHzI~ON02

97 1361

1.0+

4.1

2-Butyloctanol 230 C ~ H I ~ C H ( C ~ H ~ ) C H ~ O H (110)

0.8

356 1180) (04

0.9

440.6442 4 (227-228) @ 15 rnrn

No

2

O

1

O

1.o

472 12441

No

2

O

1

O

Explodeson heating.

No

1

2

3

4

Explodeson heoting.

No

1

3

40x

Explodes on heoting.

No

O

3

40x

Butyl Oleate C i 7H33COOC4H9

1252)

ieri-Butyl Peracetate diluted with 25% of benzene CH3CO(Oz)ClCH3)3

< 80 [ < 27) Note: Ropid decornposiiion ot 200 (93) See Hozordous Chernicols Dota.

tert-Butyl Perbenzoate C6H~COOOC(CH~)3

I > 881

>190

1.0+

loci See Hozordous Chemicals Doto. teri-Butyl Pcroxypivolate diluted wiih 25% of minerol spirits (CHJ)~COOCOC(CH~)~

z 155 (>68) (oc)

Noie: Ropid decomposition ni 90 (32). See Hazardous Chernicols Doto.

p-(p-ieri-Butyl Phenoxy) Ethanol (CH3)3CC6H40CH2CH20H

248 (120) (oc)

1.0+

293-313 (1 45-156)

No

2

O

1

O

ß-(p-teri-Butylphenoxy) Ethyl Acetate (CH~)~CCAH~OCH~CHzOCOCH3

324 (162) IOC)

1.0+

579-585 (304-307)

No

2

O

1

O

410 (210)

No

1

2

O

385-388 (i 96-1 98)

No

1

1

O

3

1

0.9

4-tert-Butyl-2Phenylphenol CaH&b0HC(CH3)3

320 (160)

1.0+

Butyl Phosphate

295 1146) (oc)

0.98

P 0 4 L b ì 3

(Tributy Phosphote)

Butyl Phthalyl Butyl 390 Glycolaie 1199) C ~ ~ ~ ( C O O ~ Z ( C ~ ~ P ) -(oc1 CH7COOC4H9 Butyl Propionate CZH~COOC~H~

90 (321

5.2

9.12

1.1

799 (426)

0.9

4.5

2

559 (293) 653 (345)

No

2

1

1

O

295 (1 46)

No

1

2

3

O


Not for Resale

NFPA 325 9 4 D b 4 7 4 4 4 b O528287 T ô b 325-24


FLAMMABLE Vapor F W H IGNITION LIMITS Sp. Gr. Density TEMP. Percent by vol. p a t e r (Air POINT ‘F (“Cl “F (“C) Lower Upper =i) = i ) Butyl Ricinoleate Ci&W”C4H9

Butyl Stearate CI~H~SCOOC~H~

320 (1601

terl-Butylstyrene

177 (81) TCC

tert-Butyl Tetralln CdH9CioHi i

680 (360)

671 (355) 1

2.7

Water Soluble

0.9

790 (421)

No

2

1

1

O

0.9

653 (345)

No

2

1

1

O

0.9

650 (343)

No

2

1

1

O

0.9

426 (219)

No

2

2

2

2

2

1

O

3

2

2

O

2

O

Butyl TrichIorosilane CH3(CHz)3SiC13

130 (54) (oc)

1.2

6.5

300 (149)

No

N-Butylurethane CH~(CHZ)~NHCOOCZHS (ButylcarbamicAcid, Ethyl Ester) (Ethyl Butylcarbomote)

197 (92)

0.9

5.0

396-397 (202-203)

No

0.69

1.86

81 (27)

0.8

2.5

169 (76)

Butyl Vinyl Ether 2-Butyne CH3CiCCH3 (Croionylene) Butyraldehyde CH3(CHz)zCHO (Butanal) IBukric Aldehvdel --```,,`-`-`,,`,,`,`,,`---

I

230 (110)

BOILING POINT O F (“C)

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReocHealth bility tivity

SeeVinyl Butyl Ether.

< -4 (<-20)

-8 (-22)

1.4

425 (218)

1.9

12.5

4

No

1

3

3

O

280 (138) @ 50mm

Slight

5

2

2

O

Note: See Hazardous Chemicals Data

Butyraldol CüHi602

165 (74) ( 4

0.9

Butyroldoxirne CdHsNOH (ûutanal Oxime)

136 (58)

0.9

3.0

306 (152)

Slight

5

2

2

O

Butyric Acid CH3(CHz)zCOOH

161 830 2.0 10.0 (72) (443) Note: See Harordous Chemicals Data.

1.0-

3.0

327 (164)

Yes

5

3

2

O

Buhric Acid. Ethvl Ester

See Eihvl Bukrate.

Butyric Aldehyde

See Butyraldehyde.

Butyric Anhydride

180 (54)

1.0-

5.4

388 1196)

Decomposes

5

1

2

1W

399 (204)

Yes

5

O

1

O

5

3

3

O

ICH~(CHZ)ZC~IZ~

535 (279)

Buhric Ester

See Ethvl Butvrate.

Butyrolactone CHzCHzCHzCOO

209 (98) IOCI

Butyrone

See 4-Heptanone.

Butyronitrlle CH~CH~CHZCN

76 (24)

Camphor CiDHl60 (Gum Camphor)

150 (66)

Camphor Oil (light) (Liquid Comphor)

117 (47)

I

0.9

5.8

1.1

935 (501)

1.65

871 (466)

0.6

0.8

2.4

243 (117)

Slight

1.0-

5.24

399 (204)

No

O

2

O

0.9

347-392 (i 75-200)

No

2

2

O

0.9

400 (204)

No

2

1

O

335 (168)

Very slight

2

2

foc)

Caproaldehyde

See Hexanol.

Caproic Acid (CH~)(CHZ)~COOH (HexanoicAcid)

215 (102)

Coprylaldehyde CH~(CHZ)~CHO (Caprylic Aldehyde) (Octonal) Capiylic Aldehyde

(4

716 (380)

125 (52)

3.5

0.8

4.4

2

O

See Copryloldehyde.


Not for Resale ~~

~

NFPA 325 94 D 6474446 0528288 912 D 325-25

PROPERTIES OF FLAMMABLE LlQUIDS, GASES, VOLATILE SOLIDS

FLAMMABLE Vopor FIA!% IGNITION LIMITS Sp. Or. Density (Air POINT TEMP. Percent by Vol. (Water “F (“C) “F (“C) Lower Upper =i) =i) 180

Caprylyl Chloride CH3(CH2)6COCI

I

I

Corbitol

See Diethylene Glycol Monoethyl Ether. See Phenol.

Carbon BisuHide

See Carbon Disulfide.

Carbon Disulfide c52 (Carbon Bisulfide)

1.0-

5.6

384 (196)

1.3

2.6

115 (46) -314 (-192)

(82)

Carbolic Acid

-22 194 1.3 50.0 1-30) (90) Note: See Hazardous Chernicols Doto.

Corbon Monoxide

Gor

Carbon Oxysulfide

Gos

1128 (609)


12.5

74

1.o

12

29

2.1

cos

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAiARD METHODS IDENTIFICATION Flammo- ReocHealth biiity tivity

Decomposes

5

3

2

1

No

4

3

3

O

Slight orvery slight, 2,3rnl per 1O0 rnl

6

3

4

O

6

3

4

1

No

2

O

1

O

No

2

O

1

O

- 58

( - 50)

(Carbonyl Sulfide) Carbonyl SuHide

See Corbon Oxysulfide.

Carnouba Wax (BrazilWax)

540 (282) Note: Melting point 185 185).

1.0-

Castor Oll (RicinusOil)

445 (229)

1.0-

Costor Oll (Hydrogenated) (c18H3503)3C3h

401 1205)

No

2

O

1

O

Cellulose Nitrate Wet with Alcohol (Nitrocellulose)

55 (13)

No

1 5

2

3

3

Cetane

See Hexadecone.

840 (449)

China Wood Oil

See Tung Oil

Chlorex

See Bis (2-chloroethvl) Ether

Chlorine Monoxide CI90

Gas

Chloroacetic Acid CH2CICOOH

259 (126)

Chlorooceto Phenone C6H5COCH?CI IPhenacvl Chloride)

23.5

595 (313)

100

Explodes

Yes

3 4 3 Explodes on heating.

@ 39 (4) 1.58

3.26

372 (189)

Yes

3

1

O

244 (1 18)

1.32

5.32

477 (2471

No

2

1

O

2-Chloro-4,6-di-teriAmvlahcnol (C5Hi;);CaH?ClOH

250 1121) . .

1.0+

32O -354 (160-179) @ 22 mrn

2

2

1

O

Chlom-4-teri-Amylphenol C5Hi iC6H3CIOH

225 (107)

1.1

487-509 (253-265)

2

2

1

O

2-Chloro-4-tert-AmylDhenvi Meihvl Ether C5hi I C ~ H ~ C I O ~ H J

230 11101 . .

1.1

518-529 (270-276)

2

1

1

O

p-Chlorobenzoldehyde CIC~HACHO


1.2

Chlorobenzene C6H5CI (Chlorobenzol) (Monochlorobenzene) (PhenylChloride)

82 (28)

>932 (>500)

1099 1593)

1.3

9.6

7.3

417 (214)

Slight

5

2

2

O

No

4

2

3

O

2

O

2

1

1.1

3.9

270 (132)

Noie: See Hazardous Chernicols Doto.

Chlorobenzol

See Chlorobenzene.

Chlorobenzotrifluoride CICaH4CF3

117 (47)

1.35

6.24

282 (139)

o-Chlorobenzotrifluoride CICaH&F3 (o-Chloro-a,a,atrifluorotoluene)

138 159)

1.4

6.2

306 (152)

Chlorobutadiene

See 2-Chloro-1.3-Butadiene.

2

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94 D b47444b 0528289 859 325-26


FLAMMABLE Vapor FIASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol. (Water (Air O F (“e) ‘F(“C) Lower Upper =i) =i) 2-Chloro-1.3-Butadiene CH2:CCI:CH:CHz (Chlorobutadiene) (Chloroprene) 1-Chlorobulane 2-Chlorobutene-2 CH3CCI:CHCH3

I

-4


Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Aommo- ReacHealth bility tivity

4.0

20.0

1.0

3.0

138 (59)

Slight

1 5

2

3

O

2.3

9.3

0.9

3.1

143-159 (62-71)

Very slight

1

2

3

O

15.9

1.2

2.8

264-266 (1 29-130)

Yes

5

4

2

( - 20)

See Butyl Chloride.

-3

í- 19)

--```,,`-`-`,,`,,`,`,,`---

Chlorodiethylalumlnum

See Diethyloluminum Chloride.

Chlorodinitrobenzene

See Dinitrochlorobenzene

Chloroethane

See Ethyl Chloride

2-Chloroethanol CH2CICHzOH (2-Chloroethyl Alcohol) IEthvlene Chlorohvdrinì

140 (60)

Chloroethyl Acetate CZH~CIOOCCH~

129 154)

1.2

4.2

293 (145)

No

3

2

2

O

2-Chloroethyl Acetate CH3COOCHzCHzCI

151 (661

1.2

4.2

291 (144)

No

3

2

2

O

1.oc

4.9

364 (184)

No

1

2

O

613 (3231

Slight

2 5

1

O

270

No

1

3

O

No

2

1

O

1

3

2

3

2

3

797 (4251

4.9

2-Chloroethyl Alcohol

See 2-Chloroethanol.

Chloro-4-Eîhylbenzene C?H&HdCI

147 (64)

Chloroethylene

See Vinyl Chloride.

2-Chlometh~lVinrl Ether

See Vinyl 2-Chloroethvl Ether.

2-ChioroethyL2-Xenyl Ether C&,C6H40CH?CH?CI

í 1 60)

320

1.1

1-Chlorohexone CH3(CHz)4CHzCI (Hexyl Chloride]

95 (35)

Chloroisoaroovl Alcohol

See 1 -Chloro-2-Prooanol.

Chloromethane

See Methyl Chloride.

1-Chloro-2-Methyl Propane

See Isobutyl Chloride.

1-Chioronophthalene CioH7CI

250

21036

(121)

(>558)

2-Chloro-5Nitrobenzotrifluoride C&CF3(2-CI. 5-NOz) (2-Chloro-a,a,a-Trifluoro-5Nitrotoluene) 1-Chlore-1-Nitroethone CzH4NOzCI

0.9

4.2

’

0

(1321

1.2

5.6

505

1

(263)

2

275 (1 35)

1.6

133 (561

1.3

3.8

344 1173)

Slight

5

1.2

4.3

285 (141)

Slight

5

1.2

4.3

273 11341

Slight

446 (230)

(oc)

1-Chloro-1-Nitropropane CHNOzCICzH5

144 (62) (oc)

2-Chloro-2-Nltropropone CH~CNOZCICH~

135 (57)

1-Chloropenìane

See Amyl Chloride.

ß-Chlorophenetole C~H~OCHZCHZC lß-PhenoxveihvlChloridel

(107)

o-Chlorophenol CICbH40H

Explodeson heating.

Explodes upon rapid heating

IOCI

225

1.1

147 (64)

1.3

306-31 1 (152-155)

Slight

5 2

347

Slight

5

p-Chlorophenol CsH4OHCI 2-Chloro-4-Phenylphenol C&C6H3CIOH

345 (1 74)

Chloroprene

See i-Chloro-l,3-Butodiene.

<1

613 (323)

Note: Melting point 172-1 76 (78-80).


3

2

O

3

1

O

2

1

O

(1 75)

Not for Resale

Slight

2 5

b 4 7 4 4 4 b 0528290 570

NFPA 325 94

325-27


FUMMABLE Vamor FIASH IGNITION LIMITS Sp. Or. Den& POINT TEMP. Percent by vol. (Water (Air "F ("C) "F ("C) Lower Upper =i) =i)

BOILING POINT 'F ("C)

Water Soluble


1-Chloropropane

See Propyl Chloride.

2-Chloropropane . .

See Isopropyl . . Chloride

2-Chloro-1-Propanol CHKHCICHiOH (ß-Chloropropy Alconol) [PropyleneChlorohyarinl

125 (521

1.1

3.3

271-273 1133-1341

Yes

5

2

2

O

125

1.1

3.3

261 (127)

Yes

5

2

2

O

352-374 (178-1 90)

Yes

5 2

1

O

Yes

5

2

1

2

4

2

1-Chloro-2-Propanol CHzCICHOHCH3 (Chloroisopropyl Alcohol] (sec-PropyleneChlorohydrin)

1521 (oc1

1-Chlore-1-Propene

See 1-Chloropropylene.

3-Chloropropene

See Allyl Chloride

a-Chloropropionlc Acid CH3CHCICOOH

225 (1071

3-Chloropropionhrile CICH2CH2CN

168 1761

1.1

3.0

348.8 (176) Decomposes

2-ChloropropionylChloride

88 1311

1.3

0.12

230 (1101

ß-ChloropropylAlcohol 1-Chloropropylene CH&H:CHCI 11-Chlore-1 -Propene)

2-Chlor0 Propylene CH2CCI:CHi (ß-Chloropropylene) (2-Chloropropene)

1.3

932 (500)

Reads

See 2-Chloro-l -Propanol <21 ( < -61

4.5

16

0.9

< -4 1< -201

4.5

16

0.93

2.63

73 (23)

2

4

O

1.08

4.37

320 (1601

2

2

O

--```,,`-`-`,,`,,`,`,,`---

2-Chloropropylene Oxide

See Epichlorohydrin

7-Chloropropylene Oxids

See Epichlorohydrin.

Chlorotoluene CbH4CICH3 ITolvl Chloridel

126 1521

a-Chlorotoluene

See Benzyl Chloride.

Chlorotrifluoroethylene

See Trifluorochloroethylene.

2-Chloro-a,a,~-Trlfluoro-5Nitrotoluene

See 2-Chloro-5-Nitrobenzotrifluoride.

o-Chloro-a,a,aTrifluorotoluene

See o-Chlorobenzotrifluoride

Cimene

See Dipentene

Cinnamene

See Skrene

95-97 (35-36)

1

(oc1

Citral 195 (CHS)~C:CH(CH~)~C(CH~):(91) CHCHO (3.7-Dimethyl-2,bOdodienol] (Geraniol)

0.9

197-199 (92-93)

No

5

O

2

O

Citronellel (CH3)2C:CH(CH2)2CH(CH3]CHiCHO (3.7-Dimelhyl-6-0ctenol) (Rhodinall

165 (74)

0.9

117 1471

No

5

O

2

O

Citronellol

205 (96)

0.85

227 (108.4)

No

5

O

1

O

O

2

O

(CH3)2C:CH(CH2)2CH(CH3)-

lCHzl2OH (3,7-Dimethyl-6-0cten-1-01] Cleaning Solvent, Stoddard Solvent

> 1O0 (>38)

444 (229)

No

0.8


Not for Resale

NFPA 325 94 325-28

PROPERïïES OF FLAMMABLE LIQUIDS, GASES, VOLATILE SOLIDS

FIASH POINT 'F("C) Cleaning Solvents, 140 (60) Class

= 6474446 0528291 407

IGNITION TEMP. 'F("C)

FIAMMBLE Vamor LIMITS Sp. Gr. Densify Percent by Vol. (Water (Air Lower Upper =i) =i)

138.2 159)

453.2 (2341

0.8

or higher

or higher

302 (1 50)

ßOiUNG POINT 'F("C)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING WARD METHODS IDENTIFICATION Flamma- ReacHealth biliîy tiviîy

No

O

2

O

<1

No

2

3

O

>1

No

O

1

O

1

2

O

Initio1

0.8

O

357:8 (181) or

higher Coal Gas

See Gas.

Coal Oil

See Fuel Oil No. 1.

< 80

C o a l Tar Light Oil

( < 271

Coal Tar Pitch

405 12071

Cobalt Naphîha (Cobolt Naphthenate)

121 (49)

529 (276)

Cobalt Naphîhenate

See Cobalt Naphtha.

Cocoanut Oil Refined Crude

420 (216) 548

2

0.9

No

0.9

No

2

O

1

O

0.9

No

2

O

1

O

1 5

1

4

O

O

1

O

I;;( (216)

Note: Melting point 72 (22)

Collodion C1zH1606(N03)4C13H1707(N03)3 Solution of Nitrated Cellulose in Ether-Alcohol

412 (2111

(<-la)

Cologne Spirits

See Ethyl Alcohol.

Columbian Spirits

See Methyl Alcohol

Colza Oil

See Rape Seed Oil.

--```,,`-`-`,,`,,`,`,,`---

Cod Liver Oil

Corn Oil Cooking

No

0.9

2 2

<1

Cotionseed Oil Refined Cooking

'5486 ;)

650 (343)

0.9 <1

No

2

No

2

O

1

O

No

3

2

2

O

3

3

2

O

3

2

O

4

3

2

(321) Creosote Oil

165 (741

637 (336)

o-Cresol CHJC~H~OH (Cresylic Acid) (o-Hydroxytoluene) (o-Methyl Phenol)

178 (81)

1110 (599)

m- or p-Cresol

CHaC6H40H

382-752 1194-400)

>1

14

Q 300 (1 491

Note Melting point 88 (31) See Hazardous Chemicals Data

187 (86)

1038 (5581

1 .o

1.1

Ci

395 (201)

No

216 (102)

Slight

302 (1 50) Note: Melting point of meto: 53.6 (12); of para: 94.6 (35). See Hoirardous Chemicals Data.

Cresylic Acid Crotonaldehyde CH3CH:CHCHO (2-Butenol) (Crotonic Aldehyde) (Propylene Aldehyde)

See o-Cresol

55

(13)

450 (2321

2.1

155

O9

24

Note See Hozordous Chemicals Doto


Not for Resale

1 5

NFPA 325 94

= 647V44b

0528292 343 325-29

PKOPEKTIES OF FLAMMABLE LIQUIDS, GASES, VOLATILE SOLIDS

FLAMMABLE Vapor FIASH IGNITION LIMITS Sp. Or. Density (Air POINT TEMP. Percent by Vol. (Water "F ("Cl "F YC) Lower Upper =i) =i) .. Crotonic Acid CH3CH:CHCOOH

190 (88)

(04

745 (396)

Crotononilrile CH3CH:CHCN 12-Butenenitrileì

Water Soluble

2

O

No

1

O

To

3

2

3.0

372 (189)

Yes

0.8

2.3

230240.8 I l 10-1 161

0.85

2.49

250 (121)

1.0-

@

5

3

176

Note: Melting point 162 (72). Crotonic Aldehyde

BOILING POINT OF("C) . .

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flomma- ReacHealth blliw tivlh

(80)

See Crotonaldehyde.

<212 (
Crotonyl Alcohol CH&H:CHCH?OH (2-Buten-1-01) (Crotyl Alcohol)

81 (27)

660 (349)

4.2

35.3

16%

--```,,`-`-`,,`,,`,`,,`---

1-Crotyl Bromide CH3CH:CHCHzBr (1 -Bromo-2-Butene)

4.6

12.0

4.66

2

3

2

1-Crotyl Chloride CHjCH:CHCHzCI

4.2

19.0

3.13

2

3

2

0.9

6.5

No

2

3

1

Slight

1

2

40x

4

1

3

2

2

1

1

2

2

1

O

6

4

4

2

1

4

O

2

O

3

O

(1 -Chlors-2-Butene) Cumene C~H~CH(CH~)Z (Curnol) (2-PhenylPropane) (Isopropyl Benzene) Cumene Hydroperoxide C~H~C(CH~)ZOOH

96 (36)

795 (424)

0.9

4.1

Explodes on heating.

175 (791 Note: See Hazardous Chemicals Doto

Cumol

See Cumene

Cyanamide NHzCN

286 (141)

1.07

1.45


1.1

4.3

Polymerizes

09

52

Note: Melting point 1 1 1 (44). I-Cyanoethyl Acrylate CHZCHCOOCH~CH~CN

306 (152)

255

(124)

No

(oc1 ~

N-(I-Cyanoethyl) Cyclohexylamine C6Hi iNHC2H4CN

255

~~

(oc)

Cyclamen Aldehyde (CH3)zCHCbHdCH(CH3)CH2CHO (Methyl Para-Isopropyl Phenyl Propyl Aldehyde)

1.8

-6 (-211

5

1.0-

190

(88)

Cyclobutane C4H8 (Tetromethylene)

Gas

1.5.9-Cyclododecatriene CizHia

1,CCyclohexane Dimethanol c8H 1 6 0 2 (CHDM)

-

(1241 Gos 6.6 32 Note: See Hazardous Chemicals Dolo.

Cyclohexone C6H12 (Hexohydrobenzene) (Hexomethylene)

No

1.8

1.9

0.9

160

(71)

-4 (-20)

332 (167)

Cyclohexanethiol CaHiiSH (Cyclohexylmercopton) Cyclohexanol CaHiiOH (Ano4

473 (245)

1.3

600 (316)

110 (43) 154

572

(68) (3001 Note: Melting point 75 (24).

8

0.8

29

1.0-

0.95

4.00

1.0-

3.5

55 (13)

No

448 (231)

No

179 (82)

No

1

525 (274)

Yes

5 2

1

O

315-319 (157-159)

No

5

2

O

Slight

5

2

O

322 (1 61 )

6

1

1

(Hexailin) (Hydralin)


Not for Resale

NFPA 325 94 325-30

m 6474446 O528293

28T

m


__

Vaaor LIMITS Sp. Gr. Denkt, Perceni bvol. (Water (Air Lower Upper =i) =i) FLAMMABLE . - -....-.-

--```,,`-`-`,,`,,`,`,,`---

FLASH IGNITION POINT TEMP. "F ("C) 'F ("e) Cyclohexanone C&oO (Pimelic Ketone)

111 (44)

788 (420)

1.1

c

0.9

3.4

0.8

2.8

313 (156)

Water Soluble Slight

5

1

2

O

No

1

1

3

O

1

1

3

O

1

2

O

3

3

O

2

1

O

2

3

O

O

1

O

2

O

1

O

3

O

212 II

Cyclohexene CHzCH2CH2CH2CH:CH I

9.4


SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flammo- ReacHealth bilit, tiviiy

<20 ( < - 7)

noi

471 (244)

181

183)

I

3-Cyclohexene-lCarboxaldehyde

See 1,2,3.6-Tetrahydrobenroldehyde.

CyclohexenoneA CaHsO

93 134)

Cyclohexyl Acetale i CHrCOiCaHi (Hexalin Acetate)

136 158)

635 13351

Cyclohexylamine C6Hi i"2 [Amino Cyclohexane) (Hexahydroaniline)

88 (31)

560 (293)

Note: See Hozordous Chemicols Daia.

Cyclohexylbenzene C6H5C6Hii 1Phenvlwclohexanel

210 (99) [oc)

0.9

90 (32)

0.99

270 1132)

1.0-

Cyclohexyl Formale CH?[CHz)rHCOOCH

124 (51)

1.01

Cyclohexylmeihane

See Methylcyclohexane.

o-Cyclohexylphenol CaHiiCóH40H

273 1134) Note: Melting point 116 1471.

1.0+

1,á-Cycloocîadiene CnHio

95 (35)

0.9

3.66

304 (151)

No

1

0.7

2.4

121 (49)

No

1

1

3

O

0.8

2.35

111 (44)

1

1

3

1

124 (51)

0.95

2.97

286 (141)

O

2

O

79 (26)

0.9

2.3

267 (131)

Slight

1 5

2

3

O

1.5

-29 ( - 34)

NO

6

1

4

O

4.6

349 (176)

No

2

2

O

3

2

1

2

2

O

_ _

~

3.3

313 (156)

1.0-

4.9

350 (1771

No

0.9

3.4

274 11341

Yes

459 12371

No

1 5

~~

Cyclohexyl Chloride CHz(CHz)4CHCI

U

4.08

288 11421

(Chlorocyclohexane) Cyclohexylcyclohexanol CnHi iCaHI nOH

Cyclopentane C,H,n - Cyclopeniene CH:CHCHzCH?CHz Cyclopenianol CH2(CH2)3CHOH

<20 1< -71

682 (361)

-20

743 (395)

(-29)

1.5

304-313 (151-1 56) 4.42

2

324 (162)

298 (148) @ 10mm

U Cyclopenianone OCCHzCHzCH2CHz

No

Slight

5

2

2

(Adipic Ketone) Cyclopropone (cH2)3 (Trimethylene)

Gor

928 (498)

2.4

10.4

p-Cymene CH~C~H&H(CH~)Z Tech. (4-Isopropyl-1-Methyl Beniene)

117 (47) 127 (53)

817 (436) 833 (445)

0.7

5.6

DDS

See Dimethyldichlororilone.

Decaborane BIOH14

0.9

@ 212 (100)

5.6

176

0.9

416 Slight (213) Note: See Hazardous Chemicals Dato.

(80) Noie: Melting point 21 1.5 (100).

Decohydronaphîhalene CioHi8 (Decalin)

136 (58)

482 (250)

0.7

4.9

@

@

212 (100)

212 (100)

0.9

4.8


Not for Resale

382 (194)

No

NFPA 325 9 4

bY7444b 0528294 116 325-3 1


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Or. Denrily POINT TEMP. Percent by vol. (Water (Air =i) =i) 'FC.C) 'FC.C) Lower Upper Decahydmnaphthalenetrans CioHiB

129 (54)

Decalin

See Decohydronaphtholene. 115 (46)

410 12101

180 (82) (oc)

(2881

c131 (<55)

455 (235)

Decano1 CH3(CHz)&HzOH (Decy Alcohol) 1-Decene CH3(CHz),CH:CH?

491 (255)

0.7

0.8

5.4

0.87

4.77

5.4

0.7

4.9

BOILING POINT "FCC)

Waier Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bilily livily 0

2

0

0

2

0

2

2

1

0

Slight

5

2

1

0

No

2

2

1

0

2

2

0

1

1

0

1

0

369 (187)

345

No

f 1741

550

0.74

4.84

342 (172)

Decyl Acrylale CH~(CN~)~OCOCH:CHZ

441 (227) (oc)

Decyl Alcohol

See Deconol.

Deglamine cH3ícHzi9NHz (1-Aminodecone)

210 (99)

0.8

429 (221)

Decylbenzene CioH2i CaH5

225 (107)

0.9

491-536 (255-280)

190 (88)

0.9

350

0.9

635-680 (335-360)

No

2

1.0-

261 (127) @ 1 1 mm

No

2

518 (2701

No

2

1

1

0

175 (791

Yes

1 5

0

3

0

6

0

4

0

lert-Decylmercaptan ci oH2i SH Deglnaphthaiene CioHzi CioH7

(177)

h e y 1 Nltmïe CWCHd~ONOz

235 (1 13)

0.9

316 (158) @ 50 mm

6.0

(4

Dehydroacetic Acid 315 690 CH,C:CHC(O)(157) (366) I CH(COCH3)C(O)O foc) Note: Melting point 228-232 (109-1 1I ) .

Very

slight

410-424 (210-21 8)

I

(DHAI iMeth;locetopyronone) Denalured Alcohol --```,,`-`-`,,`,,`,`,,`---

Government Formula CD-5 CD-SA CD-1O SD-1

60 (16)

750 (399)

0.8

1.6

60-62 (16-17) 60-61 (15.5-1 6) 49-59 (9-15) 57

SD-26 (13) 59 (151 <19

SD-BA SD-13A SD-17

I< -7)

SD-23A SD-30 SD-396 SD-39C

60 (16) 35 12) 59 (1 5) 60 (16) 59

SD-40M (15) Deulerium D2 (Heovy Hydrogen)

Gas

Diacetone

See Diocetone Alcohol.

5

75


Not for Resale

NFPA 325 9 4 325-32

= 6474446 0528295 o 5 2


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density (Air POINT TEMP. Perceni by vol. (water =1) =1) "F("C) OF(%) Lower Upper Diacetone Alcohol CHJCOCHZC(CH~)ZOH Acetone-free Commercial (Diacetone) (4-Hydroxy-4-Methyl-2Pentononel

148 (64) 136

Diacetyl

See 2.3-Butunediane.

Diallyl Eiher

See Allyl Ether.

Dialiyl Phthalate C~H~(COZC~H~)Z

330 (166)

1,J-Diaminobutane

See 1,3-Butunediamine.

1.3-Diamino-2-Propanol NH~CH~CHOHCH~NHZ

270 (132)

1,3-Diaminopropane

See 1.3-Propanediamine.

Diamyiamine íC5Hit)z"

124 (511 Note: See Hozordous Chemicals Data.

(64)

1118 (603) 1190 (643) 1118 (603)

1.8

6.9

BOILING POINT 'F("C)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Fiamma- ReacHealth bility tivily

328 (164)

Yes

5

1

2

O

1.1

554 (290)

No

2

2

1

O

1.1

266 (130)

Yes

2

2

1

O

356 (180)

Slight

5

3

2

O

0.9

0.8

4.0

5.4

5

0.9

491-536 (255-280)

No

2

O

1

O

. . Diamyibiphenyl C5Hi i(c6H4lzcsHi i (Diaminodiphenyl)

340 (171)

1.0-

687-759 (364-404)

No

2

O

1

O

Di-teri-Amylcyrlohexanol G H ii K n H o 0 H

270 (132)

0.9

554-572 (290-300)

No

2

O

1

O

0.8

302 (150)

O

2

O

505-572 (263-300)

No

2

O

1

O

______~

~~

Diamyldiphenyl

See Dmmylbiphenyl

Diamylene CioHzo

118 148) locl

Diamvl Ether

See Amyl Ether

Diamyl Maleate (CHCOOC5Hii)?

270 (132)

1.0-

Diamyl Naphthalene ci oHdc5Hi IIz

315 (159)

0.9

624 (329)

No

2

O

1

O

0.9

527 (275)

No

2

2

1

O

1.0-

615 (324)

No

2

O

1

O

2

O

1

O

2

2

O

1

O

1

O

(oc)

Di-tari-amyl phenoxy Ethanol CbHdC5Hi i)zOCzH4OH

300 (149)

Diamyl Phihalaie C ~ H ~ ( C O O Ci)? ~HI (Amyl Phihalaie)

245 (118)

1.o

475-490 (246-254) @ 50 mm

No

185

0.9

338-356 (170-1 80)

No

Diamyl Sulfide G H i i)zS

(04

(85) (4

o-Dlaniridlne [~Hz(OCHJIC~H~IZ (o-Dimethovbenzidine)


Dibenzyl Ether (CaH5CHz)zO (Benzyl Eiher)

275 (135)

Diborane BZH6

1000.8 88 125 (38-52) Note: Ignites spontaneouslyin moist air. See Hazardous Chemicals Dato.

8.43

1.o

1.1


--```,,`-`-`,,`,,`,`,,`---

Not for Resale

2

6

437 (225)

(4

1994 Edition

No

1.0-

Gas

Dibutoxy Ethyl Phthalaie 407 C ~ H ~ ( C O O C ~ H ~ O C ~ H (208) ~)Z

568 (298)

No

5 2

O

4 4 3w Reads violenfly with hologenated extinguishing agents.

O

1

O

NFPA 325 9 4

b 4 7 4 4 4 b 0528296 T 9 î

= 325-33

PROPERTIES OF FIAMMAB1,E LIQUIDS, GASES, VOLATILE SOLIDS

FLASH IGNITION POINT TEMP. "F("C) "F("C) Dlbutoxymethane CHz(OC4H9)z

FLAMMABLE Vaaor pLIMITS Sp. Gr. Denkty Percent by vol. (Water (Air '1) =i) lower Upper

140 (60) Note Meltinq point 140 (60)

Dibutoxy Tetraglycol 305 ( C ~ H ~ O C ~ H ~ O C Z H ~ ) ~(1 ? 52) (OC) (Tetraethylene Glycol Dibutyl Ether1

1.1

117 (47)

Dibutylaminoethanol (C~H~~~NCZH~OH

200 (93) (oc)

1-Dibutylamino-2Propanol

See Dibutylisopropanolomine.

N,N-Dibutylaniline CaHsN(CHzCH?CHzCH3)2

230 (1 10)

08

330-370 (166 188)

0.9

635 (335)

0.9

469-482 (243-250)

77 382 1.5 7.6 (25) (194) Nate: See Hazardous Chemical? Data.

2.5-Di-leriButylhydroquinone [C(CH3)31zCóHzIOHh (DTBHQ)

420 (216)

Water Soluble

O

2

O

2 5

2

1

O

2

O

1

O

Slight

5

3

2

O

5

3

3

O

3

2

O

No

Slight

0.8

4.5

322 (161)

0.8

4.5

270-275 (132-135)

Yes

0.9

432 122-4

No

0.9

505-527 (263-275)

No

2

3

1

O

495-511 (257-266)

No

2

O

1

O

286 (141)

Na

1 5

2

3

1

No

2

1

1

O

No

2

O

1

O

5

2

1

O

2

1

1

O

Di-teri-Butyl-p-Cresol 261 C ~ H ~ I C ~ H ~ ) Z ( C H ~ ) O H (1 27) Note: Melting point 154.4 (68). Dibutyl Ether (C4H9)20 (1-8utoxfbutane) (Butyl Ether)

BOILING POINT -F("C)

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility ilvity

0.8

4.5

790 (421)

(04 Note: Melting point 410 (210).

Dibutyl Irophthalate CaHdCOLiHvli

322 i1611

N,N'-Di-~ec-Butyl-pPhenylenediamine CaH4[-NHCH(CH3)CHKHqlv

270 (132)

625 (329)

0.6 @ 329

0.9

5

2

Dibutyllsopropanolamine CH~CHOHCHZN(C~H~)Z

205 (96)

0.8

444 (229)

Slight

Dibutyl Maleate l-CHCOzC4H9)z

285 1141) (oc)

1.0-

Decomposes

Dibutyl Oxalate C4HpOOCCOOC4Hg

220 (104)

1.0+

472 (244)

No

2

O

1

O

Di-ieit-Butyl Peroxide (CH3)3COOClCH3)3

65 (18) (oc) Noie: See Hazardous Chemicals Dota.

0.8

231 1111)

Slight

1

3

2

40x

1.0-

239 1115)

No

3

2

O

1.0+

644 1340)

No

2

O

1

O

1.o-

650 (343)

No

2

O

1

O

0.9

343-347 (173- 175) @ 0.4 mrn

No

2

O

1

O

(04

Dibutyl Phthalate C~H~(COZCIH~)Z (Dibutyl-o-Phthalate)

315 (157)

757 1402)

Dibutyl Sebacate [(CHZ)~COOC~H~I~ (Decanedioic Dibutyl Ester)

353 (178) (oc)

690 1365)

N,N-Dibutyl Siearamlde Ci 7H35CONIC4Hdz

420 (216)

0.5

@

456 1235) 0.44 @ 469 (243)

--```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94 325-34

= b47444b

0528297 925


FLASH POINT 'FPC) n-Dibutyl Tanrate (COOC~H~)Z(CHOH)Z (Dibutyl-d-2.3Dihydroxybutanedioate)

195 (91)

Vanor LIMITS Sp. Gr. Density IGNITION (Air TEMP. Percent by vol. (water 'F(0C) Lower Upper =1) =i) 544 (284)

330

N,N-Dibuíyltoluenesulfonamide CH?C~H~SO?NICAH~~?

(166)

Dicaproate

See Triethylene Glycol.

1.1

650 (343)

1.1

392 (200) @ 10 mm

1.0-

I

Dichloroacetyl Chloride CHCIzCOCI (Dichloroethanoyl Chloride)

151 (66)

No

5

O

2

O

2

O

1

O

98

441-453 (227-234) íd 4.5 mm

No

2

O

1

O

5.1

225-226 (107-1 08)

Decomposes

5

3

2

2w

522 (272)

No

2

3

1

O

33 1 (166) (oc) Note: Melting point 161 (72). See Hazardous Chemicals Data.

o-Dichlorobenzene CsH4ch (o-Dichlorobenzol)

2.2 9.2 151 1198 (66) (648) Note: See Hazordous Chemicals Data.

1.3

5.1

356 (180)

No

3

2

2

O

p-Dichlorobenzene CaH4CIz

150 (66) Note: Melting point 127 153).

1.5

5.1

345 (174)

No

3

2

2

O

o-Dichlorobenzol

See o-Dichlorobenzene

2.3-Dichlorobutadiene-1.3 CHz:C(CI)C(CI):CH2

50 (10)

1.2

4.24

212 (100)

No

1

3

3

2

2

2

O

3

2

O

2

2

O

3

3

2

3

2

1

2

3

O

694 (368)

1.O

12.0

1,CDlchlorobutane CH~CICH~CHZCH~CI

4.38 126

1.1

4.4

31 1

No

3

(155)

(52) Noie: See Hazardous Chemicals Dalo.

2,3-Dichlorobutane CH3CHCICHCICH3

194 (90) loc)

1.1

4.4

241-253 (116-123)

1.3-Dichloro-2-Butene CHzCICH:CCICH3

80 (27)

1.2

4.31

262 (128)

3,4-Dichlorobutene- 1 CHzCICHCICHCHz

113 (45)

1.1

4.31

316 058)

1,J-Dichlorobutene-2 CHzCICH:CCICH3

80 (27)

See Dimethyldichlorosilane.

1,l -DichIomethane

See Ethylidene Dichloride.

1.2-Dichlomethane

See Ethylene Dichloride.

Dichloroethanoyl Chloride

See Dichloroacetyl Chloride.

1.1 -Dichloroethyiene

See Vinylidene Chloride.

2,2'-Dichlomethyl Ether CICHzCHzOCHzCHzCI

860 (460)

5.6

12.8

131 696 2.7 (55) (369) Note: See Hazardous Chemicals Doto.

2.2-Dichloroethyl Formal

See Bir(2-Chloroethyl) Formal

Di-(2-Chloroethyl) Formal

See Bis(?-Chloroethyl) Formol

1.3-Dichloro-2.4Hexadiene CHzC1CH:CCICH:CHCHj

168 (76)

1.3

3.4

1.2

4.93

1

119 (48)

352

No

No

4

5

2

3

3

2

2

1

2

O

(178)


No

1

Dichlorodimethylrilane

sym-Dichloroeihylene 1,t-Dichloroethylene 36 C1CH:CHCI (2) Note: Exists as cis and trans isomers.

I

Water Soluble

3.4-Dichloroaniline NHzC~H~CIZ

1,2-Dlchlorobutane CHzCH2CHCICHzCI

I

BOILING POINT OF(%)

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth biliíy tiviíy

Not for Resale

--```,,`-`-`,,`,,`,`,,`---

FLAMMABLE

NFPA 325 94

= b 4 7 4 4 4 b 0528298 8bL 325-35


FLASH POINT 'F("C)


Water Soluble


--```,,`-`-`,,`,,`,`,,`---

2

2

O

2

2

O

3

2

2

3

5

2

2

3

2

2

O

2

3

O

1

O

2

2

O

No

2

3

O

3

3

O

Dichloroisopropyl Ether CICH2CH(CH3)OCHJCH3)CHzCI [Bis (ß-Chloroisopropyl) Ether]

185 (85)

1.1

6.0

369 (187)

2,2-Dichloro Isopropyl Ether [CICH2CH[CH3)]20 [Bis (2-Chloro-l -Methyleihyl Ether]

185 (85) (oc)

1.1 1

5.90

369 (187)

Dichloromethane

See Methylene Chloride.

1.1 -Dichloro-1 -Nitro Ethane CHJCCI~NO~

168 176)

1.4

5.0

255 (1241

No

1,l -Dichloro-1 -Nitro Propane C?H&CI?NO?

151 (66)

1.3

5.5

289 (1431

Slight

1.0+

4.8

266 (130)

No

1.1

4.9

352-358 (178-181)

No

4

1.4

5.6

410 (210)

Slight

5 2

1.4

4.4

346 (174)

Slight

5

1.2

3.8

219

1 4

(4

1.5-Dichloropentane CHzCI(CH2)3CHzCI (AmyleneChloride) (Peniomethylene Dichloride)

1.2-Dichloropropane

No

3

locl

Dichloropentanes (Mixed) C5HioClz

2,4-Dlchlorophenol C12C6H30H

I

FLAMMABLE Vapor IGNITION LIMITS Sp. Gr. Density TEMP. Percent by Vol. w a t e r (fir 'F("C) Lower Upper =i) =1)

> 80

i > 271 (oc) 237 (114) (oc) Note: Melting point 113 (45).

CW 140 (60)

See Propylene Dichloride.

1,3-Dichloro-2-Propanol CH2CICHOHCH?CI

165 174) (oc)

1,3-Dichlornpropene CHCkCHCHK

95 1351

5.3

2.3-Dichloropropene CHzCCICH2CI

59 1151 ITCC)

2.6

7.8

1.2

3.8

201 194)

Slight

4.1

99

1.2

3.5

47

Yes

Avoid water.

3

4

2w

No

2

2

1

2

14.5

1104)

Dichlorosilane H7SiCI2

-35

136 1361

a$-Dichlorostyrene C~HSCCI:CHCI

225 (107)

Dicyclohexyl

See Bicyclahexy

(04 Dicyelohexylamine íC6HI i Dicyclopentodiene CioHiz

>210 1>991 (oc) 90 937 (32) (503) (oc) Noie: Melting point 91 (33).

Didecyl Ether KiaHzi)zO (Decd Etherl

419 (215)

0.9

496 (258)

Slight

5

3

1

O

1.0-

342 (172)

No

1

1

3

1

O

1

O

10.3

Diesel Fuel Oil No. 1-D

1 O0 Min. (38) or Legal

No

O

2

O


125 Min. 1521 or Legal

No

O

2

O


130 Min. (541 or Legol

No

O

2

O


Not for Resale

NFPA 325 94 325-36

6474446 0528299 7T8


FUMBLE Vaaor FLASH IGNITION LIMITS Jp.Gr. Den& BOILING POINT TEMP. PeKenf by Vol. (Water (fir POINT OF(%) "F ("C) Lower Upper =i) =i) "F("C) Diethanolamine (HOCHzCHzJzNH

342 1224 (172) (662) (oc) Note: Melting point 82 (28).

1,2-Diethoxyethane

See Diethyl Glycol

Diethylacetaldehyde

See 2-Ethylbutyroldehyde.

Dieihylacetic Acid

See 2-EthylbutyricAcid.

N,N-Diethylacetoacetamide CHaCOCHzCON(CzH5lz

(1211 (oc1

Diethyl Acetoacetate CHfZOCICzHshCOOC?Hs

Diethylaluminurn Chloride lCzH5lzAICI [Chlarodiethylaluminum)

1.1

1.0-

250

170 (771

1.0-

5.4

6.4

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Flamma- ReacHealth bility tMty

514 (268)

Yes

5 2

1

1

O

Decomposes

Yes

2

O

1

O

2

2

O

3

4

3w

412-424 (21 1-218) Decomoases

5 Very slighi

Do not use water,

foam or halogenoted extinguishing agents.

Note: Ignites spontaneouslyin air See Hazardous Chemicals Daia.

Diethylaluminurn Hydride (CzH5hAIH

3 3w Do noi use woier, foam or halogenated extinguishing agents.

Noie: Ignites spontaneously in oir. Diethylamlne íCzH5lz"

-9 594 1.8 10.1 (-23) (312) Noie: See Hazardous Chemicals Data.

2-Diethyl (Amino) Ethanol

See N,N-Diethylethanolomine.

2-(Diethylamino) Ethyl Acrylate CHz:CHCOOCHzCH2HNíCHKHzIz

195 (91)

3-(Diethylamino)Propylamine (CzH5)zNCHzCHzCHzNH~ (N,N-Diethyl-l,3Propanediamine)

138 (59) (oc)

N,N-Diethylaniline C6H5NíCzH~Iz (Phenyldiethylamine)

185 (85)

o-Diethyl Benzene c6H~[CzHslz

0.7

2.5

134 (57)

Yes

5

3

3

O

2

2

1

1

0.9

5.9

Decomposes

0.8

4.5

337 (1691

Yes

5

2

2

O

1166 (630)

1.0-

5.0

421 (2161

Slight

5

3

2

O

135 (57)

743 (395)

0.9

4.6

362 (1831

No

2

2

O

m-Diethyl Benzene GH,iC,H& " .. -

133 156) , .

842 14501 , .

0.9

4.6

358 11811 . .

No

2

2

O

p-Diethyl Benzene c6Hdc~blz

132 (55)

806 (4301

0.9

4.6

358 (181)

No

2

2

O

N,N-Diethyl-1.3Buîanediamine CzH5NHCHzCHzCHN(C2H5lCH3 [ i ,3-Bis(ethylamino)Butane]

115 (46) (OC)

0.8

5.0

354-365 (179-1 85)

Yes

5

2

2

O

662 (350)

No

5

O

1

O

369-374 (187-1 90)

Yes

5 2

2

1

2w

259 (126)

No

1

2

3

1

2

1

1

O

0.7

Di-2-EthylbulylPhthalate 381 CsH~[COOCH~CH(CzH~l~1?(194) (oc) Diethyl Carbamyl Chloride (CzH5JzNCOCI

325-342 (163-1 72) (oc)

Diethvi Carbinol

See sec-Amvl Alcohol

Diethyl Carbonate (CzH5lzC03 (Ethyl Carbonate1

1.3-Dieihyl-1.3-Diphenyl Urea [(CZH~)(C~H~)NIZCO

77 1251

302 (150) Noie: Melting point 160 (71).

6.0

1.0+

1.0-

4.1

1.1

620 (327)

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Decomposes

IOCI

Not for Resale

2

NFPA 325 94 M b47444b O528300 2 4 T 325-37

PROPEKIIES OF FLAMMABLE LlQUlDS, GASES, V O L T I L E SOLIDS

FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density BOILING POINT TEMP. Percent by val. (water (Air POINT Lower Upper =i) =i) ?F (?C) ?F (?C) O F (?C) Diethylene Diamine

144 (62)

Diethilene Dioxide

See p-Dioxane

Dlelhylene Glycol O(CH2CH?OH)2 (2,2-Dihydroxyethyl Ether)

(124)

Water Soluble


--```,,`-`-`,,`,,`,`,,`---

299 (150)

Yes

1.1

472 (244)

Yes

5 2

1

1

O

1.1

320 (160) @2mm

No

2

1

1

O

Dlethylene Glycol BIS 379 (2-Buîyoxyethyl (1931 Carbonaie) [CH~ICHZ)~O(CHZ)ZO~COCHzCHzI20 (ButoxyethylDiglycol Carbonatel

1.1

392-403 (200-206) @2mm

Slight

5

1

1

1

Dielhylene Glycol Bis (Butyl Carbonate) [CH~(CHZ)~OOCOCH~CHiIzO (Butyl Diglycol Carbonate)

372 (1891

1.1

327 (164) @2mm

Slight

1

1

1

Diethylene Glycol Bis (Phenylcarbonate) (CaHsOOCOCHzCHdzO (Phenyl Diglycol Carbonate)

460 (238)

1.2

255

Diethylene Glycol Bis (Allylcarbonate) (CHz:CHCHzOCOOCHzCHhO (Allyl Diglycol Carbonate)

435 (224)

3 78 11921 (oc1

437-444 (225-229)

2

5

2

Na

2

O

1

1

Yes

5 2

1

1

O

1

O

O

1

O

@2mm

Diethylene Glycol n-Butyl 230 Ether (i10) C ~ H ~ O C Z H ~ O C ~ H ~ O H (04 (8utoxy Diethylene Glycol)

442 (228)

1.0-

Dieîhylene Glycol Butyl Ether Acetate CHKOOGHaOKiHs

563 (295)

0.98

241 (i 16)

448 (2311

7.05

475 (2461

(oc)

Diethylene Glycol Dibenzoate (CóHsCOOCH2CHz)zO

450

12

457 (2361 @5mm

cd

(232)

68

Yes

5

2

(20) Diethylene Glycol Dibutyl 245 Ether (118) C~HPO(CZH~OJZC~H~ (DibutoxyDiethylene Glycol) Diethylene Glycol Diethyl Ether CHdCH70CH7hCHq

590 (310)

09

180

09

56

(82)

493 (256)

Slight

5 2

1

1

O

372 (189)

Yes

5

1

2

O

O

1

O

foc)

~

Diethylene Glycol Diethyl 340 Lewllnate 1171) (CH~COCZH~COOC~H~)~~

1.14

Diethylene Glycol Dimethyl Ether CH30CHzCHzOCHzCHzOCHj

153 (67)

0.95

324 (162)

260 (1271

1.1

491 -529 (255-276)

Diethylene Glycol Dipropionate ICiH5COOCzH4)20 Diethylene Glycol Ethyl Ether CZHSOCZH~OC~H~OH Dielhylene Glycol Ethyl Ether Phthalate C ~ ~ ~ ~ C (Bis[2-(Ethoxyeihoxy)Ethyl] Phthalaie) (Carbital Phthalate)

O

1.2

196 (91) 406 (2081 ~ ~ ~

9.0

10.4

1.0

4.65

1.12 z

~

~

~

~

z

~

~

396 (202)

13.7 ~

~

> 500 ( > 260)

l

Yes

5

1

2

1

Slight

5 2

1

1

O

Yes

5

1

1

O

O

1

O

z


Not for Resale

NFPA 325 94 325-38

b 4 7 4 4 4 b 0528301 186

m o P t x r i E s OF FLAMMABLE LIQUIDS, GASES, VOLATILE SOLIDS

FLASH POINT "F ("C)

205 (961

FLAMMABLE Vawr IGNITION LIMITS Sp. Gr. Den& TEMP. Percent byvol. (water (Air "F ("C) h r Upper =1) =1) 465 (240)

1.38

22.7

1.04


4.14

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Aamma- ReacHealth biliíy tivlíy

379 (1931

Diethylene Glycol 172 Monobuíyl Ether (78) C~H~OCH~CHZOCHZCH~OH

400 (204)

0.85

24.6

1.0-

0.76

10.7

1.0-

1.2 2 ~ 5

23.5

1.0

Diethylene Glycol Monobuíyl Ether Acetate

240 (1 16)

570 (298.91

Diethylene Glycol Monoethyl Ether CH2OHCH2OCH2CHzOCzHs

201 (94)

400 (204)

(135)

(182)

Diethylene Glycol Monoethyl Ether

225 (1071

680 (360)

1.0 @ 275 (135)

19.4 @ 365 (185)

1.0+

452-485 (233-

O98

107

10-

222 Diethylene Glycol Monoisobuíyl Ether (106) (CH~)ZCHCH~O(CH~)~0íCHi)zOH

Diethylene Glycol MonoMethyl Ether Formol CHz(CH30CH2CH20CHzCH20ì2

2

O

O

2

O

(oc1

Diethylene Glycol Methyl 180 Ether Acetate (82) CHSCOOC~H~OC~H~OCH [OC) ~

Diethylene Glycol Monomethyl Ether CH30(CH2)0(CH2)2OH

2

5.6

448 1231)

Yes

5

1

2

O

476 (2471

Slight

5 2

1

1

O

396

Yes

5

1

1

O

5

1

1

O

1

1

O

(202)

424 (218)

Yes

422-437 (217-225)

Yes

2

5 2

252)

205 (96)

1.0-1

381 (194)

Yes

5

1

1

O

310 (154) (oc)

1.0+

581 (305)

Yes

5 2

1

1

O

5

O

1

O

(4

1.1

Yes

2 Diethylene Oxide

See Tetrahydrofuron.

Diethylene Triamine 208 676 2 6.7 NHZCH~CHZNHCH~CH~NH~ I981 I3581 (OC) Note: See Hazardous Chernicols Doto. N,N-Diethylethanolamine (CzH51zNCzH40H (2-(Diethylomino) Ethonol)

140 (601

608 (320)

Diethyl Ether

See Ethyl Ether.

N,N-Diethylethylenediamine íCzHd2NCzH4"z

115 I461

1.0-

3.56

404 (207)

Yes

5 2

3

1

O

0.9

4.0

324 (162)

Yes

5

3

2

O

0.8

4.0

293 (145)

Yes

5

3

2

O

442 (217)

Slight

5 2

1

1

O

252 (122)

Slight

3

O

783 I4 171

No

1

O

(oc)

(4

Diethyl Fumarote C2HsOCOCH:CHCOOC2H5

220 11041

Diethyl Glycol ICZH~OCH~)~ (1,2-Diethoxyethone)

95 (35)

1.0+ @ 68

(20) 401 (205)

Di-2-Ethylhexyl Adipate 385 C ~ H ~ [ C O O C H ~ C H ( C ~ H S ) (-1 96) C4H912 (Dioctyl Adipate) POAI Diethylhexylamine

See Bis(2-Ethylhexyl)Amine.

Diethylhexrlethanolamine

See Bis(2-Ethylhewl)Ethonolamine.

Dl(2-Ethylhexyl) Maleate

See Bis(2-Ethylhexyl)Maleate.

Di(2-Ethylhexyl) Phosphoric Acid

See Bis(2-Ethylhexyl)Phosphoric Acid.

0.84

4.07

0.9


Not for Resale

5 2

O

--```,,`-`-`,,`,,`,`,,`---

DiethyleneGlycol Methyl Ether CH30C2H40C2H40H (2-(2-Methoxyethoxy) Ethonol)

m

NFPA 325 94

b 4 7 4 4 4 b 0528302 012 325-39


FLAMMABLE Vapor FlâSH IGNITION LIMITS Sp. Gr. Densify (Air POINT TEMP. Percent by Vol. (water "F ('C) 'F ('C) Lower Upper =i) =i) Di(2-Elhylhexyl) Succinate

See Bis(2-Ethylhexyl)Succinote.

Diethyl Ketone C~H~COCZH~ (3-Pentonone)

55 (13) (oc)

842 (450)

1.6

> 150 (>66) (oc)

N,N-Diethyllauramide C i iHnCON(CzH5)z Diethyl Maleate (-C~COzCzH5h

250 (121)

662 (350)

Diethyl Malonate CHz(COOCzH5)z (Ethyl Malonate)

200

Diethyl Oxide

See Ethyl Ether.

BOILING POINT 'F ('C)

0.8

3.0

21 7 (103)

0.9

8.8

331-351 (166-1 77) @2mm

Water Soluble

Slight

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bilify tivify

1 5

1

No

3

O

2

O

1.1

438 (226)

No

2

1

1

O

1.1

390 (199)

No

3

O

1

O

No

O

3

O

4

4

(04 (93) (oc1

3.3-diethyl pentane CH~CHZC(C~H~)~CH~CH~ Diethyl Peroxide CzH500C2Hs Diethyl Phthalate ~ 6 ~ 4 (

~

~

322 ~ (161) ~ z (oc)

554 (290)

0.7

5.7

0.8

4.4

295 (146)

7.7

Explodes on heoting.

Explodes on heating.

2.3

0.8

855 (457) ~ ~

0.7 ~ í@ z 368 1186)

1.1

p-Diethyl Phthalate

See Diethyl Terephthalate.

N.N-Dieihyl-l.3Propanediamine

See 3-(Diethylomino) Propylomine.

2.2-Diethyl-1 3Proponediol HOCH.$(C~H~)ZCHZOH


0.9 @ 142 1611

2.5

1.2

Diethyl Sulfate (CZH~~~SO~ (Ethyl Sulfote)

195 190)

No

2

O

1

O

320 (160) @ 50 mm

Yes

5

2

1

O

226 (108)

No

246-401 (1 19-205) @ 1 mm

No

2

O

1

O

Slight

5 2

1

1

O

5

3

1

1

4.7

0.9

Diethyl Succinate (CH2COOCH2CH3)2

565 (296)

421 (2 16)

1.0+

220 817 (104) (436) Note: See Hazardous Chemicals Data.

Decomposes, No, giving slight Ethyl Ether decomposition

1.2

1.2

Diethyl Tartrate CHOHCOO(C2H5Jz

200

Diethyl Terephthalate C~H~(COOCZW (p-Diethyl Phthalate)

243 1117) Note: Melting point 112 (44)

3,9-Diethyl-6-tridecanol

See Heptodeconol.

536

O

2

2

Yes

5

O

1

O

No

2

O

1

O

(280)

(93)

Diethylzinc ICZH~~ZZ~ [Zinc Diethyl)

2

1.1

576 (302)

3 Note: Ignites spontoneously in oir. See Hozordous Chemicals Doto.

Difluoro-1-Chloroethane CF2CICH3 IR-i 428) (1-Chlore- 1,lDifluoroethane)

Gos

6.2

17.9

4 (-16)

Diglycol Chloiformate O:(CH2CH20COC1)2

295 11461 (oc)

Diglycol Chlorohydrin HOCH~CH2OCHzCHzCI

225 11071 (oc)

1.2

Diglycol Diacetaie (CH3COOCHzCHz)z:O

255 (i 241

1.1

256-261 (124-1 27) @5mm

6.5

387 (197)

Yes

482 1250)

Yes

4 3w Do not use woter, foom or hologenoted extinguishing agents. 4

O

2

O

1

O

5

O

1

O

O

1

O

2

2 5

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94 325-40

m 6474446 0528303 7.59 m


FUMBLE Vamor LIMITS Sp. Gr. Den& F W H IGNITION (Air POINT TEMP. Percent by vol. (water “F (“Cl “F (“Cl Lower Upper =i) =i)


Diglycol Dilevulinote ICHiCH700C-

340 I1711

1.1

Diglycol Laurate CisHmO,

290 11431

1.0-

559-61 7 1293-3251

0.8

451-469 (233-243)

Water Soluble Yes

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING “XRD METHODS IDENTIFICATION Flamma- ReacHealth biliiy tivily

2

O

1

2

O

1

O

No

2

2

1

O

5

2

3

O

1

O

1

O

5

Dihexyl

See Dodecone.

Dihexylamine IWíCHz151z~H

1104)

Dihexyl Eîher

See Hexy Ether.

220 (oc1

Dihydropyran CH2CHzCHz:CHCHO

O (-18)

0.9

2.9

186 (86)

Slight

Slight

o-Dihydroxybenzene CaH4IOH)z ífvrocatecholì

260 (127)

1.34

3.79

473 (245)

p-Dihydroxybenzene C6H4(OH)z (Hydroquinone)

329 959 (165) (515! Note: Melting point 338 (170).

1.36

3.81

547 (2861

1,2-Dihydroxybvtane

See 1.2-8utonediol.

2,2-Dihydronyethyl Ether

See DiethyleneGlycol.

2.5-Dihydroxyhexane

See 2.5-Hexanediol.

Diirobulylaiuminum Hydride I(CH3)zCHCHzIzAlH

3 Do not use water, foom or hologenated extinguishing agents.

Note: Ignites spontaneouslyin oir.

Diirobulylamine [(CH~)ZCHCHZIZ” [Bis(ß-Methylpropyl)Amine]

85 (29)

Diirobuiyl Carbinol [(CH3)zCHCHz]zCHOH (Nonyl Alcohol)

165 (74)

0.7

0.8 @

212 (100)

6.1

273-286 (134-141)

No

No

0.8

5.0

353 (178)

@

212 11001

3

3

O

5

1

2

O

1

1

3

O

1

2

O

O

1

O

2

O

1

O

5

O

1

O

1

Diisobutyiene

See 2,4,4-Trirnethyl-l-Pentene.

Diisobutyiene (CH~)~CCHZC(CH~):CHZ

736 (3911

0.8

4.8

0.7

3.87

(-5)

214 (101)

120 (49)

745 (396)

0.8 @ 200 (93)

7.1 @ 200 (93)

0.8

4.9

335 (168)

No

Diisobutyl Phthalate CaH~(COOCHzCH(CH3)zIz

365 (185)

810 (432)

0.4 @ 448

62 1 (327)

No

Diirodecyl Adipate C~OWI~OZCICHZ~~COZCioHzi

(107)

Diisodecyl Phthalate C6H4(COOCioHzi)z

450 (232)

23

5

3w

(2,4,4-Trimeihyl-l2-Pentone)

Diisobulyl Ketone [(CH3)zCHCHzlzCO (2,6-Dimethyl-4-Heptonone)

(Isovalerone)

(4

1.ot

225

5

2

0.9

660 1349)

1.0-

482 (250)

No

1.0-

698 13701

No

2

O

1

O

1.0-

480 (249)

Yes

5

2

1

O

183 (841

Yes

3

3

O

(4 755 (402)

0.3 @

2

508

(oc)

Diisoocíyl Phthalate ICnHi 7C0017C6Hd

450 12321

Diisopropanolamine [CH3CH(OH)-CHzIzNH

260 (127)

Diiropropyl

See 2,3-Dirnethylbuiane.

Diisopropylamine I(CH3)zCHlz~H

30 (-1)

705 (374)

2

(oc1

600 (3161

1.1

7.1

0.7

3.5

(oc)

Note: See Hozardous Chemicols Dato.


--```,,`-`-`,,`,,`,`,,`---

Not for Resale

1 5

NFPA 325 94

6474446 0528304 995 325-41


--```,,`-`-`,,`,,`,`,,`---

FWH POINT "F ("C)

Diisopropyl Benzene l(Ch)2CHl?CóH4

FLAMMABLE Vaaor IGNITION LIMITS Sp. Gr. Denkîy TEMP. Percent by Vol. (water (Air "F ("C) Lower Upper =i) =i)

170 (77)

840 (4491

0.9


5.6

401 (205)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth billîy tlvity

No

O

2

O

1

2

O

1

1

O

O

4

40x

(oc1

Diisopropyl Ether

See Isopropyl Ether.

DiisopropylMaleate (CH3)2CHOCOCH: CHCOOCH(CH3)2

220 (104)

Diisopropylmethanol

See 2,4-Dimethyl-3-Penianol.

Diisopropyl Peroxydicarbonate (CH3)2CHOCOOCOOCHICHII~

Note: Ropid decomposition a1 53 (1 2). Melting Point 46-50 (8-1O). See Hazardous Chemicals Data.

Diketene CH?:CCHzC(O)O

2.5-Dimethoxyaniline NHZC~H~(OCH~Z

1.0+

444 (2291

Slight

5 2

(4

1.1

93 (341

302 (150)

Explodes heating.

No

on

2.9

735 (391)

261 (127)

Decomposes

5

4

2

2

518 (2701

Yes

2

2

1

O

Slight

2 5

2

1

O

(oc)

Nate: Melting paint 156-1 63 (69-731

5.9

2.5-Dimethoxychlorobenzene CaHpCIO2

243 (1 17)

1.2-Dimethoxyethane

See Ethylene Glycol Dimethyl Ether.

DimethoxyethylPhthalate 410 C ~ H ~ ( C O O C H Z C H Z O C H ~(210) )~ [Bis(2-methoxyethyl) (4 Phthalate]

750 (399)

Dlmethoxymethane

See Methylal.

Dimethoxy Tetraglycol CH30CH?(CH2OCHZ)~CH~OCH~ (TetraethyleneGlycol Dimethyl Ether)

285 (1411

0.7 @ 440 (227)

460-467 (238-242)

1.2

644 (340)

No

5 2

O

1

O

1.01-

528 (276)

Yes

2

1

1

O

330 (1 65)

Yes

5

2

2

O

1.6

45 (71

Yes

6

3

4

O

0.9

3.1

272 (133)

Yes

1 5

2

2

O

0.9

5.4

207 197) @ 40 mm

Yes

5

2

2

O

0.86

3.35

338 11701

2

1

0.8

3.5

278 (137)

Yes

5

3

2

O

1.0-

4.2

379 (193)

Slight

5

3

2

O

1

2

O

5

(oc)

Dimethylacetamide (CH312NC:OCH3 IDMAC) . .

158 (70)

Dlmethylamine ICH3)zNH

Gas

914 (490)

(oc1 . .

752 (400)

18

115

@

@

212

320

2.8

14.4

10

Note: See Hazardous Chemicals Data 2-(Dimethylamino) Ethanol (CHJ)~NCH~CHZOH (Dimeihylethanalamine)

105 141)

2-(Dimethylamino) Ethyl Methacrylate CLIHISNO~

165 (741

34 Dimethylamino)propylamine (CH~)~N(CHZ)~"~

563 (295)

(4 (4

Note: Polymerizes

1 O0 (38) (oc)

Di(MethvlamvllMaleate

See 8isl2.4-DimethvlbutvIl Maleate.

N,N-Dimethylaniline C~N~N(CH~)Z C.P.

145 (63) 165 1741

o-Dimethylaniline

See o-Xylidine

Dimethyl Anthranilate CH300CCaH4NHCH3 (N-Methyl Methyl Anthranilate)

195 (91)

1.2-Dimethylbenzene

See o-Xylene.

1.3-Dimelhrlbenzene

See m-Xylene

700 1371)

1.1


Not for Resale

NFPA 325 94 325-42

b 4 7 4 4 4 b 0528305 821 W

PROPERTIES OF FLAMMABLE LIQUIDS. GASES, VOLATILE SOLIDS

FLASH POINT "F ("C) 1.4-Dimethylbenzene

IGNITION TEMP. "F ("C)

FlAMMBLE Vapor LIMITS Sp. Gr. Density Percent by val. (Water (Air Lower Upper =i) =i)


Water Soluble


See p-Xylene.

205 Dlmelhylbenrylcarblnyl Acetale (96) C~H~CHZC(CH~)~OOCCH~ (olpho, olpho-DimethylNote: Melting point 84-86 (29-30). phenethvlAcetote)

1.0-

1

1

0

2.2-Dimethylbutane (CH3)3CCHzCH3 (Neohexone)

-54 (-48)

761 (405)

1.2

7.0

0.6

3.0

122 (50)

No

1

1

3

0

2,3-Dimelhylbutane ICH~)ZCHCHICHB)Z (Diisopropyl)

-20 (-29)

761 (405)

1.2

7.0

0.7

3.0

136 158)

No

1

1

3

0

680 (360)

0.68

2.91

133 (56)

0

3

0

753 (401)

0.71

2.91

163 (73)

0

3

0

113 (45)

0.9

5.0

284-297 (140-147)

Slight

5

1

2

0

55 1,3-Dirnethylbutylamine CH~CHNH~(CHZ)CH(CH~)~(13) (2-Amino-4-Methylpentone) (oc)

0.7

3.5

223-228 (106-1 09)

No

1

2

3

0

259-270 (126-132)

2

2

0

4

2

1

1.3-Dlmelhylbutanol

See Methyl Isobutyl Carbinol.

2.3-Dimethyl- 1-Butene CH3CH(CH3)C(CH3):CH2

<-4

( < -20)

2.3-Dimelhyl-2-Buiene CH~C(CH~):C(CH~)Z

( < -20)

<-4

1.3-Dimethylbutyl Acetate CH3COOCH[CH3)CH>CHíCH3Jz

Dimelhyl Carbinol

See Isopropyl Alcohol.

Dimclhyl Carbonate

See Methyl Carbonate.

Dimethyl Chloracetal CICHZCH(OCHJ)~

111 (44)

Dimelhylcyanamlde ICH3)zNCN

160 (71)

1,2-Dimelhylcyclohexaina (Ch)&Hio

450 (232)

1.0+ 0.88

2.42

320 1160)

579 (304)

0.8

3.87

260 027)

No

0

0

1,3-Dlmethylcyclohexane lCH3)zC6Hio ( Hexohydroxylene)

-50 1101

583 (306)

0.8

3.87

-256 (124)

No

1

0

3

0

1.4-Dimethylcyclohexane (CH3hC6Hio (Hexahyd roxylol)

52 1111

579 (3041

0.8

3.9

248 (120)

No

1

1

3

0

1.4-Dimethylcyclohexanecis CaHioICHdz

61 (16)

255 (124)

0

3

0

1.4-Dimethylcyclohexanetmns C6HioíCH3)z

51 (11)

246 (119)

Dimethyl Decalin cioHi6(cHz)z

184 (84)

0

2

0

3 3 Decomposes in woier.

1

Dimethyldichlorosilanc (CH3)2SiCIz (Dichlorodimethylsilone)

< 70 (<21)

Dime1hyl-o.o-Dichloravinyl-2,2-Phosphaïe (Technical) (CHsO]2P(O)OCH:CCh (DDVP)

350 (177)

-

455 12351

0.7

@

5.3

1.0

455 (235)

@

200 1931

300 1149)

3.4

>9.5

1.1

4.4

158 170) 248 (120) Q14mm

(oc)

Decomposes

Slight

1

0

1

1

5

(4 289 ( 143) Note: Melting point 120 (49).

Dlmelhylenc Oxide

See Hhvlene Oxide.

N,N-Dimethylethanolamine

See 2-(Dimethylomino) Ethanol.

1.0- @ 122 (50)

585-588 (307-309)


3

2

Dimeîhyldioxane 75 CH~CHCHZOCH~(CH~)CHO (24) 1,ó-Dirnethyl-l,3Diphenylcyclobutane (C6H5CCHdzICHzh

5

No

--```,,`-`-`,,`,,`,`,,`---

Not for Resale

2

0

NFPA 325 94

6474446 0528306 768 325-43

PROPERTIES OF FLAMMABLE LIQUIDS, CASES, VOLATILE SOLIDS

--```,,`-`-`,,`,,`,`,,`---

FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Den& POINT TEMP. Percent by Vol. (Water (Air "FCC) "FW Lower Upper =i) =1) Dimethyl Ether

See Methyl Ether.

Dimethyl Ethyl Carbinol

See l-Methyl-P-8utanol.

2A-Dimethyl-3Ethylpentone CH~CH(CH~)CH(CH~HS) CH(CH3)z(3-Ethyl-2.4Dimethylpentane)

734 13901

N,N-Dlmethylformamide HCON(CH&

136 (58)

833 (445)

2.2

15.2

BOILING POINT 'FCC)

Wahr Soluble

0.74

4.43

279 (137)

0.9

2.5

307 (153)

Yes

0.9

3.3

200 (93)

Slight

8

SEE INTRODUCTIONFOR SUGGESTED E%TINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHeahh bilih tivih

O

3

O

5

1

2

O

1 5

2

3

O

2

O

1

O

O

3

O

212 (100) 2,5-Dimethylkmn OC(CH3J:CHCH:C(CH3)

45 17) IOCI

1.8 3.3-Dimethylheptane CHJ(CHZ)~C(CH~)~CHZCH~ 2.6-DIm~hyl-4-Heptanone 2,3-Dimethylhexane CH3CH(CH3)CH(CH+ CIHGCH~

I

I

4.43

279 11371

45 (7)

820

0.7

3.9

237 1114)

No

1

O

3

O

0.7

3.9

229 11091

No

1

O

3

O

0.85

4.35

302 (150)

O

2

O

0.8

2.0

145 1631

(438)

loc)

(10)

Dimethyl Hexynol C4H&CH3(0H)C i CH (3.5-Dimethyl-1 -Hexvn-3-011

135 157)

DimethylhydrazineUnr).mmetricol

0.73

See Diisobutyl Ketone.

2.4-Dimethylhexane CH3CH(CH3)CH(CH3)CZH~CH~

1.1-Dimethylhydrazine íCHil7NNHi (Diiefhylhydrairine, Unsvrnrnetricolì

617 1325)

446 12301

50 (oc)

(oc)

5 (-15)

480 (2491

2

95

Yes

5 1

4

3

1

No

2

O

1

O

257 (125)

Yes

1 5

2

3

O

393 (201)

No

2

1

1

O

Yes

5

2

2

O

See 1.1 -Dimethylhydrazine.

Dimelhylisophtholote CHjOOCCaH&OOCH3

280 1138) Note: Melting point 153-154 (67-68).

N,N-Dimethylisopropanolamine (CH~IZNCH~CH(OH)CH~

(35)

Dimethyl Ketone

See Acetone.

Dimethyl Maleate (-CHCOOCH3)z

235 (113)

95

0.9

3.6

(oc)

1.2

(oc1 . .

2.6-Dimethylmorpholine 112 CH(CH~)CHZOCHZCHICH~INH (44)

3,4-Dimethylodane C3H7CH(CH3)CH(CH3)C3H7 2.3-Dimethylpentaldehyde CH~CHZCH(CH~)CH(CH3)CHO

2.3-dimethyl pentane CHjCH(CH3)CH(CHJICHZCH~ 2.4-dimethyl pentane (CH3)?CHCH2CHíCH3)2

2.4-Dimethyl-3-Pentanol (CH3)2CHCHOHCH(CH3)2 (Diisopropylrnethonol)

0.9

4.0

296 (1471

0.74

4.91

327 (164)

O

2

O

0.75

4.91

324 1162)

O

2

O

0.8

3.9

293 (1451

1

2

3

O

0.7

3.5

194 (90)

No

1

O

3

O

10 1-12)

0.7

3.5

177 (81)

No

1

O

3

O

120 (49)

0.8

4.0

284 (140)

Very slight

O

2

O

i131 ( < 55)

94 134 (oc)

<20 ( < -7)

635 (335)

1.1

6.7


Not for Resale

~

NFPA 325 94 325-44

= 6474446 0528307

bT4


FIAMMABLE Vaoor FLASH IGNITION LIMITS Sp. Gr. Der& BOILING (Air POINT POINT TEMP. Perceni bvol. (Water "F("C) "F CC) Lower Upper =1) =i) 'F("C) Dimeîhyl Phthalate C~H~(COOCH~)Z

295 (146)

915 (490)

0.9

1.2

540 (282)

(3

Water Soluble No

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHeaiih bit* tidy

2

O

1

O

2

2

O

O

4

O

2

O

358 (1801 Dimethylpiperazine-cis CaHidNz

0.92

155 (68)

3.94

329 ( 1651

(oc)

2.2-dimethyl propane

Gas

(CH314C (Neooentone) ~

842 (450)

7.5

2.5

49 (91

No

3.72

31 1 (155)

Yes

6

~

2.2-Dimethyl-1 -Propanol

See led-Butyl Carbinol.

f5-Dimethy lpymzine

147 (64)

CH3C:CHN:C(CH3)CH:N

1.4

0.99

I (oc1 --```,,`-`-`,,`,,`,`,,`---

1

Dimethyl Sebacaie I- (CH~).ICOOCHJIZ (Methyl Sebacate)

293 (1451

Dimethyl Sulfate (CH312S04 (Methyl Sulfate)

182 (831

Dimethyl Sulfide (CHsliS Dimethyl Sulfoxide (CHMO

1.0-

565 (2961

2

O

1

O

(oc) Note: Melting point 76 (24).

370 (1881

1.3

4.4

370 (188)

Very slighi

3

4

2

O

0.8

2.1

99 (371

Slighi

1

1

4

O

372 (1 89)

Yes

5

1

1

O

543 (2841

No

5 2

1

1

O

No

2

3

1

3

3

1

4

3

1

4

3

1

3

O

1

O

O

1

O

O

1

O

O

1

O

(4

Note: See Hazardous Chernicols Doto.

CO 403 2.2 19.7 (<-la) (206) Note: See Hozordous Chemicals Dato. 203 1951

419 1215)

2.6

42

1.1

(4

Noie: Melting point 65 (18) Dimeîhyl Terephthalate C~H~(COOCH~)Z (Dimethyl-1.4-BenzeneDicorboxylote] (DMTl 2.4-Dinitroaniline PJOZ)ZC~H~NHZ

308

(153)

965 (518)

(oc)

435 (224)

1.6

Note: Melting point 370 (188). 1,2-DInltro Benzol C6H!("&b lo-Dinitrobenzene1 Dinitrochlorobenzene CAH~CI(NO.>I~ - - . IChlorodinitrobenzeneJ 2A-Dinitrotoluene (NO~ZCIHJCHJ

302 (1501

1.57

5.79

Note: Meltina- .Doint 244 Il . 181. .

2.0

382 11941

22

1.7

604 (3181 599 I3 151

No

2

Note: Melting point 109 (43). See Hazardous Chernicols Doto

404 12071

1.52

6.27

572 (300)

Note: Melting point 158 (70).

Diodyl Adipoie [ - (CHzJ2COOCH2CH(CZH~IC~-H~IZ [Bis(Z-Ethylhexyl]Adipote] [Di(P-EthylhexyI)Adipate]

402 (206)

Diodylamine

See Bi$-Ethylhexyl) Amine.

Diot3yl Azelate (CH2)71COOCH2CH(C2H5)C4Hvl2 [Bis(Z-Ethylhexyl)Arelalel [Di(2-Eihylhexyl]Arelole]

440 (227)

Diociyl Ether (CeHi7120 (Octyl Ether) Dio& Phthalate CaH&02CH2CHlCiH4CaHoli [Di(2-Eihyl/;é~l)%tholotel [Bis(Z-Elhyihexyl)Phthalate]

710 (3771

(4

705 (374)

(oc)

>212

0.9

B

0.3

0.9

B

401 (205)

420 (215)

735 (390)

0.82

0.3

8.36

1.0-

No

709 (3761

No

5 2

5 2

558 (2921 No

d 474


680 (3601

510 (266)

( > 100)

foc1

0.4 467 (2421

Not for Resale

2

m

NFPA 325 94

6474446 0528308 530

m 325-45


FLAMMABLE Vapor FIASH IGNITION LIMITS Sp.Gr. Density POINT TEMP. PeKentbyVol. (Water (Air “F (“Cl “F (“Cl Lower Upper =1) =i)

u

(DiethyleneDioxide) Dioxolane OCHZCH~OCH~

u

54 (12)

22

2.0

356 (180)

1.0+

3.0

214 (101)

Water Soluble Yes

1 5

2

3

1

O

2

O

3

1

O

O

1

O

Note: See Hazardous Chemicals Doto.

1

35 (21

5

(oc1

Dipentene CioHia (Cinene) (Limonene)

113 (45)

Diphenyl

See Biphenyi.

Diphenylamine (CsHslzNH (Phenylaniline)

307 1173 (153) (634! Note: Melting paint 127 (53).

458 (237)

0.7

6.1

0.9

302 (150)

1.2

0.98 1,3-DiphenyI-2buîen-1-one

See Dypnone.

Diphenyldichlorarilane (c6Hs)zsich

288 (142)

4.7

8

(3

302 11501

7.26

1.0+

1.1-Diphenylethane (uns) íCaH5lzCHCH3

No

575 (302)

No

2

561 (294)

1.2

Diphenyldodecyi Phosphite 425 ( ~ 6 ~ 5 ~ ~ z ~ ~ ~ i(2181 o ~ z i (oc) Melting point 64 (1 8).

339 (1 70)

581 (3051

Yes

2

3

1

O

No

2

O

1

O

>212 (>loo]

824 (440)

1.0

6.29

546 (286)

O

1

O

If-Diphenylethane (sym) C6HsCHzCHzCaH5

264 (129)

896 (480)

1.0

6.29

544 1284)

O

1

O

Diphenyi Ether

See Diphenyl Oxide.

Diphenylrnethane (C6H5)zW (Ditanel

266 905 (1301 (485! Note: MeltinQpoint 79 (26).

2

1

1

O

Diphenyl (o-Xenyi) Phosohate

437 (2251

2

O

1

O

Diphenyl Oxide (c6 H5)20 (Diphenyl Ether)

239 1144 0.7 (115) Note: Melting point 81 (271.

2

1

1

O

1 .o

508 (264)

1.2

482-545 (250-2851

1.1

496 (2581

~

Diphenyl Phthalate c6~.i(cooc6~s)?

No

~

435 (2241 Note: Melting point 158 (70).

6.0

No

0.97

7.74

586 (308)

O

1

O

0.97

6.77

54 1 (283)

O

1

O

O

1

O

761 (405)

1.3

No

2

3w 3 Do not use water, foam or halogenoted extinguishing ogents.

Dipropylaluminum Hydride (GH7)zAIH Note: Ignites spontoneouslyin oir.

Dipropylene Glycol [CH3CHOHCH2120

250 (121)

0.7

3.5

).O+

4.63

229 (1091

No

1

3

3

O

449

Yes

2 5

O

1

O

O

2

O

(232)

foc)

Dipropylene Glycol Methyl Ethor CH~OCJH~OC~H~OH

1.86 (86)

Dipropyl Ether

See n-Propyl Ether.

Dipropyl Ketone

See 4-Heptonone.

Ditane

See Diphenylrnethane.

1.1

3.01.0

5.11

Q

408 í209ì

Partly

200°C


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

p-Dioxane OCHZCH~OCH~CH~


SEE INTRODUCIION ï O R SUOOESTE0 EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bilily iiviíy

NFPA 325 94 325-46

m 6474446 0528309 477 m


FLAMMABLE Vapor F W H IGNITION LIMITS Sp.0r. Densliy BOILING POINT TEMP. percent by vol. (Water (Air POINT "F("C) "F('C) lower Upper =i) =i) "F("C) Divinyl Acetylene (iCCH:CH2)2 (1.5-Hexadien-3-yne)

< -4 ( < -20)

Divinylbenzene CóHd(CH:CHz)?

2.69

169 (76)

0.7

6.2

0.9

1.7

27

0.8

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility ti+

183 (84) 392 (200)

No

83

NO

3

3

1

2

2

1

2

4

2

2

O

1

O

O

2

O

2

1

O

(oc)

Ddnyl Ether (CH2:CH)iO (Ethenyloxyethene) (Vinyl Ether)

i-22

( < -30)

680 (360)

(28)

Note: See Hazardous Chemicols Doto.

Di(o-Xenyl) Phenyl 482 Phosphate (250) (C~HSC~H~)ZPO(OC~H~) Dodecane CHdCHz)ioCH3 (Dihexyl)

165 (74)

1-Dodecanethiol CHdCHdiiSH (DodecylMercaptan) ILOUNI MercaDtanì

262 (128)

1-Dodecanol CH3íCHz)iiOH (Lauryl Alcohol)

260 (127)

Dodecyl Benzene (Crude) C6kCi?Hz5 (Alkane) (DetergentAlkylote)

285

1.2

545-626 (285-330) @5mm

397 (203)

0.8

0.6

5.9

0.8

(4

Dodecyl Bromide Dodecylene (a) C i &Hi1 CH:CHz (1-Dodecane)

2.4

421 (216)

No

289 (143)

No

5

2

@J 15mm

527 (275)

0.8

49 1 (255)

No

2

O

1

O

0.9

554-770 (290-410)

No

2

1

1

O

O

1

O

2

1

O

1

O

See Lauryl Bromide.

c212 ( < 100)

491 (255)

Dodenl Mercaaton

See 1-Dodeconethiol.

tert-Dodecyl Mercaptan Ci zHzeSH

205 (96) (oc)

4-Dodecyloxy-2-HydroxyBenzophenone C25H3403

498 (254)

0.76

5.81

0.9

406 (208)

428-451 (220-233)

715 (379)

No

No

2

597-633 (314-334)

No

2

O

1

O

475 (2461 @ 50 mm

Slight

2 5

1

1

O

1

O

3

2

Note: Melting point 109 (43). 0.9

Dypnone C6H5COCH:C(CHj)CaH5 (1,8-Diphenyl-2Buten-1-one) Eicorane c20H42

350 (177) (oc)

1.1

>212 ( > 100)

450 (232)

88 (31)

772 (411)

Epichlorohydrin CH~CHOCHZCI

U

9.0

3.8

21.0

0.79

9.75

651 (344)

1.2

3.2

239 (115)

Yes

5

3

(2-ChloropropyleneOxide) (y-ChloropropyleneOxide) Note: See Hazardous Chemicols Data 1,l-Epoxyethane

See Ethylene Oxide.

Erythrene

See 1,3-Butodiene.

~~

Ethanal

See Acetaldehyde.

Eîhane CHjCHj

Gas

1,2-Ethanediol

See Ethylene Glycol

1.2-Eïhanediol Diformate HCOOCH2CH2OOCH (Ethylene Formate) (EthyleneGlycol Diformate) (Glycol Diformate)

200 (93) (oc)

882 (472)

3.0

1.o

12.5

12

--```,,`-`-`,,`,,`,`,,`---


-128

No

345 (174)

Decomposes

í - 89)

Not for Resale

6

1

4

1 2 Decomposes in woter

O

O

NFPA 325 ïi1

m

b Y ï Y 4 4 b 0528310 199 W 325-47


FLAMMABLE Vapor LIMITS Sp.Gr. Density FLASH IGNITION POINT TEMP. Percent by vol. (Water (Air "F("C) "F ("C) Lower Upper =1) =i) Ethanethiol

See Ethyl Mercopton.

Ethanoic Acid

See Acetic Acid.

Ethanoic Anhydride

See Acetic Anhydride.

Ethanol

See Ethyl Alcohol.

Ethanolamine NHzCH2CHzOH (2-Amino Ethonol) (ß-Aminoethyl Alcohol]

186 (86)

Ethanoyl Chloride

See Acetyl Chloride.

Ethene

See Ethylene.

E t h e n y l Ethanoate

See Vin$ Acetale.

Eihenyloxyethene

See Divinyl Ether.

Ether

See Ethyl Eiher.

Ethine

See Acetylene.

Ethoxyocetylene CzH5OC:CH

770 (410)

3.0

23.5


1.0+

2.1

342 (172)

Yes

5

3

2

O

0.8

2.4

124 (511

No

1

2

3

1

4.2

342 (1 72)

No

O

2

O

289 (143)

Very slight

2

2

1

Yes

2

2

O

2

2

O

@ 140°C

< 20

I<-71

Ethoxybenzene CaHsOCzH5 (Ethyl Phenyl Ether) (Phenetole)

145 (63)

1.0-

2-Ethoxy-JA-Dihydro-2Pyran C7HlZoZ

111 144) (oc1

1.0-

2-Ethoxy Ethanol

See Ethylene Glycol Monoeihyl Ether.

2-Ethoxyethyl Aceiate CH~COOCHZCHZOC~H~ (Ethyl Glycol Acetale1

117 1471

3-Eíhoxypropanol CiH~OC~HK.HO -

1O0 i381

1.7

1.0-

4.6

313 (1 56)

0.98

3.52

275 1135)

3.5

275 11351

Yes

5

2

3

O

426 12191

Yes

5

2

1

O

1.0+

492 1256)

Yes

2 5

O

1

O

1.o-i

662 1350)

No

2

O

1

O

230 (1 10)

0.9

401 (2051

Yes

5 2

1

1

O

N-Ethyl Acetanilide CH~CONICZH~)(C~H~I

126 (52)

0.9

5.6

400 (2041

No

O

2

O

Ethyl Aceiate CH3COOC2H5 (Acetic Ester) [Acetic Ether) (Ethyl Ethanoate)

24 (-41

800 (426)

0.9

3.0

171 1771

Slight

1 5

1

3

O

Ethyl Acetoncatate C~HSCOZCHZCOCH~ (Acetoacetic Acid, Ethyl Ester) (Ethyl 3-Oxobutanoate)

135 (57)

563 (295)

1.0+

4.5

356 (180)

Slight

5

2

2

O

Ethyl AceW Glycolate CH~COOCH~COOCZH~ (Ethyl Glycolate Acetate)

180 (82)

1.09

5.04

O

2

O

Ethyl Acrylate CHz:CHCOOCzH5

50 110)

2

3

2

_ _

716 (380)

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bilhy tivity

5

(3-Ethoxypropionaldehyde)

1-Ethoxypropane

See Ethyl Propyl Ether.

3-Ethoxypropionaldehyde CzH50CHzCHzCHO

1O0 138)

0.9

3-EthoxypropionicAcid C~H~OCHZCHZCOOH

225

1 .o+

(107)

Ethoxytrlglycol CzH50(CzH40)3H (Triethylene Glycol, Ethyl Ether) --```,,`-`-`,,`,,`,`,,`---

N-Eîhylacetamide CHaCONHC2H5 (Acetoethylamide)

275 (135)

2

(4

2.0

1.4

11.5

95

@

@

200

350 (1761

(93)

1.4 14 0.9 3.5 702 (372) ( 4 Note: Polymerizes. See Hazardous ChernicolsDoto.

-365 (-185) 21 1 1991

NO

Slight

1

5


Not for Resale

NFPA 325 94 325-48

m 6474446

0528311 025

m


FLñMMñBLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density (Air POINT TEMP. Percent by vol. (Water "F ("Cl "F("C) Lomr Upper =i) =i) Ethyl Alcohol czH5oH (Grain Alcohol, Cologne Spirits, Ethanol] Ethyl 96% Alcohol and 95% Water 80%

55 '(13)

685 (363)

3.3

19

0.8

BOILING POINT "F ("Cl

1.6

173 (78)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth biliíy IMíy

Yes

1 5

3

O

62

(63' (17)

68

(;l

70%

(;l

60%

(;il

50%

(241 79 (261 85 (291 97

40% 30%

20% 10%

',",o

5%

(491 144 (621

Ethylaluminum Dichloride CzH5AICIz (Dichloroethylaluminum) Notes: Fumes vigorously in air. May ignite spontaneously. Ethylaluminum Sesquichloride (CzH513AIzC13

-4 ( - 201

1.1

297 (1471

Note: ignites spontaneously in air. Ethylamine CzH5NHz 70% aqueous solution (Aminoethane)

O

0.8

1.6

62 (17)

160 (71) Iod

0.92

3.06

322 (1611

185 (85)

1.0-

4.2

401 (205)

No

0.9

3.7

277 (136)

Na

414 (212)

No

291-298 (144-148)

No

594 (3 121 Slight decomp.

No

(<-18)

725 (385)

3.5

14.0

Yes

3 3 Do not use water, foam or halogenated extinguishing agents.

3w

3 Do not use water, foam or halogenated extinguishing ogenk.

3w

4

O

2

O

3

2

O

2

3

O

1

1

O

2

O

1

O

5 2

2

1

O

2

3

O

2

1

O

2

O

3

O

1 5

3

Note: See Hazardous Chemicals Data.

Ethyl Amino Ethanol CzH5NHCzHlOH 12-IEihvlaminolethanoll

(oc1

Note: See Hazardous Chemicals Data. Ethylbenzene CzH5CaH5 (Ethylbenzol) (Phenylethane)

70 (21)

Note: See Hazardous Chemicals Daia.

Ethyl Benzoate CsHsCOOC?Hs

190 (881

Ethylbenzol

810 14321

0.8

6.7

914 (4901

1.0+

See Ethylbenzene. 1.1

1.0+

Ethyl Borate (CzH513803

52 (111

Ethyl Bromlde CTHsBr (6amoethane)

None

952 (511)

6.8

118 (48)

2-Ethrlbutanol

See 2-Ethvlbuivraldehvde.

Ethyl Butonoate

See Ethyl Buîyrate

2-Ethyl-1 -Butanol

8.0

0.9

5.0

233 (11-21

Decomposes

1.4

3.8

100 (38)

Slight

1

1.5

Ethyl Bmmoacetate BrCHzCOOCzH5

2-Ethyl-1 -Butene (CzH5lzC:CHz

1

See 2-EthylbutylAlcohol. <-4 ( < -20)

599 (315)

0.69

2.90

144 (621

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Not for Resale

O

NFPA 325 94

6474446 0528332 Tb3 325-49


FLAMMABLE Vaoor - - ~ FLASH IGNITION LIMITS Sp.Gr. Deiibity BOILING (Air POINT POINT TEMP. Pement by vol. (Water 'F("C) "F ("C) Lower Upper =i) =i) "F ("e) ~

~

J-(l-EthyIbutoxy) 280 Propionic Acld (138) C H ~ C H ~ C H ( C ~ H ~ ) C H Z - (oc) OCHzCH2COOH

10-

2-Ethylbuíyl Acetate CH~COOCHZCH(C~H~)Z

130 (54) lacì

0.9

2-Ethylbuíyl Acrylate CH2:CHCOOCHzCHlCiHs)CiHs

125 (52) [oc)

0.9

2-Ethylbutyl Alcohol (CzH5)zCHCHzOH (2-Ethyl-1-Butanol)

135 (57)

0.8

Ethylbuíylamine CH3CHzCHzCHzNHCH3CHz

64 (18) (oc)

Ethyl Butylcarbamate

See N-Butylurethone.

Ethyl Butyl Carbonate (CZHS)(C~HPJCOB

(50)

Ethyl Butyl Ether CzH50C.iH9 (Butyl Ethyl Ether)

2

1

O

rnrn

No

1

2

O

180 (82) @ 1Omm

No

2

2

O

5.0

3.5

301 (149)

No

1

2

O

0.7

3.5

232 (1111

No

3

3

O

0.9

5.0

275 (135)

2

2

1

0.8

3.7

198 (92)

2

3

O

O

2

O

1

2

O

'

(oc)

122 40 (4)

Slight

1

1

5

0.90

5.05

386 (197)

0.8

4.0

299 (148)

No

352 (178) @ 50 rnrn

Yes

2 5

2

1

O

(oc)

280 (138)

2-Ethylbutyraldehyde (C2H5)zCHCHO (Diethyl Acetaldehyde) (2-Ethylbutanal)

70 (21) (oc)

Eíhyl Buîyrate CH~CH~CHZCOOCZH~ (Butyric Acid, Ethyl Ester) (Butyric Ester) (Ethyl Butonoote)

75 (24)

2-Elhylbutyrlc Acid (CzH5)2CHCOOH (Diethyl Acetic Acid)

210 (99) [OC)

2-Ethrlcaprooldehyde

See 2-Ethylhexanal.

Ethyl Caproate C5Hi iCOOCzH5 [Ethyl Hexode) [Ethyl Hexanoate)

120 (49)

0.9

Ethyl Caprylate CH~(CHZ)&OOC~H~ (Ethyl Octoate) (Ethyl Octanoate)

175 (79)

0.9

Ethyl Carbonate

See Diethyl Carbonate.

Ethyl Chloroacetate CICHzCOOCzH5

2

324 (162)

2-Ethyl-2-Buîyl-l,3Propanediol HOCHzC(CzHd(C.iH9)CHiOH

Ethyl Chloride CzH5CI (Chloroeihane) (Hydrochloric Ether) (Muriatic Ether)

No

(200) @ 100

2-Ethyl Butyl Glycol 180 (C~HS)ZCHCH~OCZH~OH (82) 12-12-Ethvlbutoxvlethanoll (oc1

(3-Heptanonel

392

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility tim

0.9

@

(4

122°F (50°C)

Note. Melting point 107 (42).

-58 (-50)

0.8

3.5

242 (117)

No

1 5

2

3

1

865 (463)

0.9

4.0

248 (120)

Na

1 5

O

3

O

752 (400)

0.9

380 1193)

Slight

5

2

1

O

333 (167)

No

5

2

2

O

405-408 (207-209)

No

5

2

2

O

54 (12)

Slight

1

1

4

O

295 1146)

No

3

3

O

201 (94)

Decomposes

3

1

1.2

966 (519)

3.8

7.7

15.4

0.9

4.97

2.2

Note: See Hazardous Chemicals Data. 147 164) (oc)

1.2

~

Ethyl Chlorocarbanate Ethyl Chlorofomte CICOOCZHS (Ethyl Chloracarbonate) (Ethyl Chlorarneihanoate)

See Ethyl Chlaroformate. 61 (16)

932 1500)

1.1

3.7

4

--```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94 325-50

m 6474446 0528333

9T8


F W H IGNITION POINT TEMP. 'F (OC) "F (OC) Ethyl Chloromethanoate

BOILING POINT "F (OC)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Flamma- ReacHealth bility tivity

See Ethyl Chloroformate.

Ethyl Crotonaie CH~CH:CHCOOCZH~

36

0.9

282 (139)

3.9

(21

Ethyl Cyanwcetate CHLNCOOCvHz Ethylcyclobutane CzH5GH7

FIAMMABLE Vapor LIMITS Sp. Gr. Density Percent by vol. (water (Air Lower Upper =i) =i)

1.1

230 (1 101 <4 11-16)

Ethylcyclohexane CzH5C6Hii

95 1351

Ethylcyclopentane CZH~C~H~ Ethyl Decanoate CPH~~COOC~H~ IEthvl Caarateì

<70 (<21)

410 (210)

1.2

7.7

460 12381

0.9

6.6

500 (260)

1.1

6.7

401 -408 1205-2091

2

1

O O

0.8

3.9

269 (132)

No

1

3

O

0.8

4.4

3

3

O

0.8

3.4

1

3

O

Slight

1 5

218 1103) 469 1243)

No

5

O

1

O

168 (75.5)

Yes

1

3

3

O

487 12531

Yes

2

2

1

O

-155 (-104)

Yes

6

1

4

2

290 (143)

351 (1 77)

Yes

2 5

2

1

1

(04

@ 100 mm

Yes

2 5

1

1

2

241 1116)

Yes

5

3

2

O

239-252 (115-122)

Yes

5

183 (84)

No

4

2

3

O

387 (197)

Yes

5 2

1

1

O

340 (171)

Yes

5

1

2

O

399

No

5

1

2

O

Slight

5 1

1

3

O

N-Ethyldiethanolamlne CzHsN(CzH40Wz

280

1.0+

(1 38)

Ethyl Dimethyl Methane

See Isopentone

Ethylene HzC:CHz (Ethene)

Note: See Hazardous Chernicals Dato.

Ethylene Acetate

See Glycol Diacetate.

Ethylene Carbonate OCHzCHzOCO

4.45

5

loc1

Gas

842 (450)

2.7

1 .o

36.0

Noie: Melting point 96 (36). Ethylene Chlorohydrin

See 2-Chloroethanol.

Eihylene Cyanohydrin CHz(0H)CHzCN (Hydracrylonitrile)

265 (1 29)

445 (229)

1.1

(4

Decomposes

Noie: See Hazardous Chemicals Data.

104 (40) 150 (661

725 (385)

2.5 12.0 @ 100°C

0.9 1.0-

2.1

(oc1

Ethylene Dichloride CH2CICHzCI ( 1 ,2-Dichloroethanel (Glycol Dichloride)


Ethvlene Dlnanide

See Succinonitrile.

56 (13)

775 (413)

6.2

2.2-Eihylenedioxydiethanol

See Tneihylene Glycol

Ethvlene Formate

See 1 .2-€thanediol Diformate.

Ethylene Glycol HOCzH40H (1,Z-Ethonediol) (Glycol)

232 (111)

Ethylene Glycol N-Butyl Ether HOCH~CHZOC~H~

150 1661

748 (398)

3.2

1.1

16

1.3

3.4

1.1

10.6 0.897

4.10

See Glycol Diocetaie.

Ethylene Glycol DibEther C~H~OCZH~OC~H~

185 (85)

Ethylene Glycol Diethyl Ether C~H~OCHZCHZOCZH~

95 (351

Ethylene Glycol Diformate

See 1.2-Eihonediol Diformate.


2

3

1.1

1994 Edition

O

1

30 (-1)

Ethylene Glycol Diacetate

3

No

Ethyl Dichlorosilane CzH5SiHC12

76%

2

160 1711

0.9

Ethylenediamine HzNCHzCHzNHz hydrous

1

2.9

>212

(>loo)

u

No

0.8

(204)

406

0.8

4.07

(oc1

--```,,`-`-`,,`,,`,`,,`---

Not for Resale

251 (122)

NFPA 325 94

6474446 0528334 834 325-5 1

PROPERTIES O F FLAMMABLE LIQUlDS, GASES, VOLATILE SOLIDS

FLASH POINT “F (“C) Ethylene Glycol Dimethyl Ether CH30(CH2)20CH3 (1,2-Dimethoxyethone]

29 (-21

Ethylene Glycol Ethylbutyl Ether IC~H~)~CHCH~OCH,CH,OH

180 (851 loci

FLAMMABLE Vapor IGNITION LIMITS Sp. Gr. Density (Air TEMP. Percent by vol. (Water “F (“e) l o w e r Upper =1) =l) 395 (2021


0.9

174 (79) @ 630

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD IDENTIACATION METHODS Flamma- ReacHealth biiity tivity

Slight

5

2

2

O

rnm

0.9

386 (197)

No

5

1

2

O

Ethylene Glycol Ethylhexyl 230 Eiher (110) C ~ H ~ C H ( C Z H ~ ) C H ~ O C H ~(OC) CHiOH

0.9

442 (228)

No

5 2

O

1

O

Ethylene Glycol Isopropyl Ether (CH3)zCHOCHiCHzOH

92 (331

0.9

289 (143)

Yes

5 1

1

3

O

Ethylene Glycol Monoacetate CH2OHCH200CCH3 (Glycol Monoacetote)

215 (102)

1.1

357 (181)

Yes

5 2

O

1

O

Ethylene Glycol Monoacrylate CHz:CHCOOC2H40H (2-H ydroxyethylocrylate)

220 ( 104)

1.1

410 (210)

Yes

5 2

2

1

1

Ethylene Glycol Monobenzyl Ether C&I~CH~OCHZCH~OH

265 (129)

1.1

493 (256)

No

5 2

2

1

O

Ethylene Glycol Monobutyl Ether C.ibO(CHz)zOH (2-Butoxyethanol)

143 (62)

460 (238)

340 (1711

Yes

5

2

2

O

Ethylene Glycol Monobuiyl Ether Acetate C4H90(CH2)200CCH3

160 (71)

645 (340)

377 (192)

No

5

1

2

O

Ethylene Glycol Monoethyl Ether HOCHZCHZOC~H~ (2-Ethoxyethainol)

110 143)

455 (2351

O

Ethylene Glycol Monoethyl Ether Acetate CHJCOOCH~CH~OC~HS (CellosolveAcetate)

124 (52)

7 15 (3791

1.7

136 Ethylene Glycol Monoisobutyl Ether (58) (CH~)ZCHCH~OCH~CH~OH

540 (282)

1.2

Ethylene Glycol Monomethyl Eiher CH~OCHZCH~OH (2-Methorpthanol)

102 (39)

545 (285)

Ethylene Glycol Monomethyl Ether Acetal CH3CH(OCHzCHzOCH&

200 (93)

Ethylene Glycol Monomethyl Ether Acetate CH~O(CHZ)~OOCCHJ

120 (49)

Ethylene Glycol Monomethyl Ether Formal CHz(OCHzCH2OCH3)z

155 (68)

~

3.58

--```,,`-`-`,,`,,`,`,,`---

(4 (04

(OC1 ~~

(oc)

@

12.7

0.88

8.54

@

275 (135)

1.7

15.6

@

4.1

0.9

@

200 (93)

200 (931

0.9

@

275 (1351

0.9

3.0

275 (1351

Yes

5

2

2

1.0-

4.72

313 (1561

Yes

5

1

2

0.9

4.1

316-323 1158-1 621

Yes

5

2

2

1.0-

2.6

255 (124)

Yes

5

2

2

405 (207)

Yes

5

1

2

@

200 (93)

9.4

@

200 1931 1.8

C?

STP

275 1135) 14

@

STP 1.0-

O

740 (392)

1.5 @ 200 (93)

12.3

1.0+

4.1

293 (145)

Yes

5

1

2

1.0-

5.65

394 (201)

Yes

5

1

2

1.1

4.8

473 (245)

No

2

O

1

0.9

1.5

51 (11)

Yes

1

@

200 (93)

(oc1

260 (127)

Eihylene Oxide CH2OCH2

-20

(DirnethyleneOxide) (1,i-Epoxyethone) (Oxirane)

1.1 200 (931

(oc)

Ethylene Glycol Phenyl Eiher C6HsOCzH40H (2-Phenoxyethanol)

U

665 (352)

1058 with No

3.0

100

3 4 Vopors explosive.

O

3

Air

Note: See Hozordous Chemicals Dato.


Not for Resale

NFPA 325 94 325-52

m

b47444b 0528315 770


FLASH IGNITION POINT TEMP. "F ("C) "F("C)

Ethyienimlne NHCHzCHz

12 (-11)

608 (320)

FLAMMBLE Vanor LIMITS Sp.Gr. Den& (Air Percent bY vol. (Water Lower Upper =i) =i)

3.3

54.8

0.8

1.5

0.9

3.0


Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HA7AñD METHODS IDENTIFICATION Flamma- ReocHealth biiiiy tiviiy

132 (56)

Yes

5

4

3

3

322

Yes

5

1

2

O

Slight

1 5

1

4

1

No

1 5

2

3

O

O

3

O

U (Aziridine)


Ethyl Ethanoate

See Ethvl Acetate

N-Ethylethanolamine CZH~NHCZH~OH

160 (71)

(161)

(oc)

I

I

-49 (-45)

Ethyl Ether CzH50CzHs [Diethyl Ether) IDiethvl Oxidel [Etherj (Ethyl Oxide]

356 (180)

19

36.0

0.7

2.6

95 (35)

Note: See Hazardous Chemicals Daia.

EthylethyleneGlycol

See 1.2-Butanediol.

~

Ethyl Fluoride CzW (1 -Fluoroethane) Ethyl Formote HCOiCiHs (Ethyl Methanoate) (FormicAcid, Ethyl Ester)

0.72

- 36

1.66

i 38)

@ 7.2 atm

-4 (-20)

Ethyl Formate (oriho) ICzH50)3CH (Triethyl Orthoformatel

851 (455)

2.8

16.0

86 130)

~

0.9

2.6

130 (54)

0.90

5 11

291 (1441

08

44

325 (163)

Very slight

472 (2441

Slight

2 5

1

1

O

~~

Ethyl Glycol Acetate

See 2-Ethoxyethyl Acetote.

2-Ethylhexaldehyde

See 2-Ethvlhexanol ~

2-Ethylhexanal C~HPCH(CZHS)CHO

112 (44)

375 1190)

085 @

72 @

(öutylethylacetoldehyde)

200

275

[ 2-Ethylcaproaldehyde) (2-Ethylhexaldehyde)

(93)

(1351

2-EthyI-l.3-Hexanediol C3H,CH(OH)CHíCzH5lCHzOH

260 (127)

2-Ethylhexanoic Acid C~H~CH(CZH~)COOH (2-Ethyl Hemic k i d )

245 (118)

2-Ethylhexanal C~H~CH(CZH~JCHZOH (2-HhylhexylAlcohol) (Odyl Alcohol)

164 173)

2-Ethylhexenyl

See 2-Ethyl-3-Propylocrolein.

2-Ethylhexoic Acid

See 2-EthylhexanoicAcid.

680 (360)

09

(oc1

700 (371)

0.8

6.0

0.9

5.0

440 (227)

No

2

1

1

O

448 (231)

0.88

9.7

0.8

4.5

359 1182)

Slight

5

2

2

O

8.14

0.9

5.9

390 (199)

No

2

2

O

266 (1301

No

2

2

2

(oc)

2-Ethyihexyl Acetate 160 C H ~ C O O C H Z C H ( C ~ H ~ ) C ~(7 H1 )~ ( O e l Acetate)

515 (268)

0.76

0.9

Ca 2-Ethylhexylomine C~H~CH(CZH~)CHZNHZ

140 160)

0.8

4.5

50mm

337 (1 69)

Yes

5

2

2

O

379 (193)

No

2

3

1

O

2

2

O

(4

N-2-(Ethylhexyl) Aniline 325 C ~ H ~ N H C H Z C H ( C Z H ~ ) C ~(163) H~ (oc)

0.9

2-Ethylhenyl Chloride C~H~CH(CZH~)CH~CI

0.9

140 (60)

@ 50 mm

5.1

343 (1 73)

No

342 (1 72)

No

2

2

1

O

No

2

1

1

O

lot)

0.8

(n 50 m m . .

.

2-Ethylhexyl Ether [C~H9CWzHs)CHzIz0

235 (1 13)

0.8

517 1269)


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

~

NFPA 325 94

= 6474446 05283Lb 607 = 325-53


FWMABLE Vataor LIMITS Sp. Gr. Density FLASH IGNITION (Air POINT TEMP. Percent by Vol. (Water 'FCC) "FW) Lower Upper =i) =i) 2-fthylhexyl Vinyl Ether

2 (-17)

1.2-Ethylidene Dichloride CICHzCHzCI

55 (13)

Ethyl Isobuíyrate (CH~)ZCHCOOC~H~

< 70 l<21)

2-Ethylirohexanol (CH3)zCHCHzCH(CzH5)CHIOH (2-Ethyl Isohexyl Alcohol) 12-Ethvl-4-MethvIPentanol1

158 (70)

Ethyl Lactate CH3CHOHCOOC2H5 Tech.

115 (46) 131 155)

Ethyl Mercaptan CzH5SH (Ethanethiol) (Ethyl Sulfhydrate)

Water Soluble

See Vinyl-2-EthylhexylEther.

1,l -Ethylidene Dichloride CH3CHCI2 (1,l -Dichloroelhane)

Ethyl Malonate

BOILING POINT "FCC)

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Flamma- ReorHealth bllity tivlty

5.4

824 (440)

6.2

11.41.2

16

600 (3161

135-138 (57-59)

752

1.5

@

4 5

2

3

O

1.25

3.42

183 (84)

2

3

O

0.87

4.0

230 (110)

O

3

O

343-358 ( I 73-181)

1

2

0.8

WOI

Slight

1.0f

4.1

309 (1541

Yes

5

2

2

O

0.8

2.1

95 (35)

No

1

2

4

O

0.9

3.9

239-248 (115-120)

No

1

2

3

O

507 12641

Very sliaht

2

O

1

O

Yes

1 5

2

3

O

O

1

O

2

3

4

3

4

4

212 (100)

See Diethyl Malonale.
572 (300)

2.8

18.0

~

Ethyl Methocrylate CHZ:C(CH~)COOC~H~ (Ethyl Methyl Acrylate)

68

(20)

(04

Ethyl Methanoate

See Ethyl Formote.

Ethyl Methyl Acrylate

See Ethyl Methacrylale.

Nhyl Methyl Ether

See Methyl Ethyl Ether

7-Ethyl-2-Methyl-4Hendeconol

285 11411

Ethyl Methyl Ketone

See Methyl Ethyl Ketone.

4-Ethylmorphoiine CHZCHZOCZH~NCHZCHJ

90 (321

u

Ethyl Nitrite C~HSONO (Nitrous Ether)

0.8

0.9

4.0

280 (1381

1.02

5.39

496 12581

1.1

3.1

(4 896 (4801

1-Ethylnaphthalene CioH7CzH5

Ethyl Nitrate CH3CHzONOz (Nitric Ether)

~___

50 (101

4.0

190

No

4

(88)

-31 194 4.0 50. (-35) (90) Decomposer Note: See Hazardous Chemicals Data.

0.9

2.6

63 (17)

No

3-Ethyloctone C5Hi iCH(CzH5ICzH5

446 (2301

0.74

4.91

333 (167)

O

2

O

4-Ethyloctane C&W"ZH~IC~H~

445 (229)

0.74

4.91

328 (164)

O

2

O

1.1

5.0

367 (186)

Slight grodual decomposition

O

2

O

426 (219)

Slight

2

1

O

529

No

O

1

Ethyl Orthosilicaie

See Ethyl Silicaie.

Ethyl Oxalate (COOCZHSIZ (Oxalic Ether) (Diethyl Oxalate)

168 (76)

Ethyl Oxide

See Ethyl Ether.

Ethyl 3-Oxobutanoate

S e Elhyl Acetoacetote.

p-Ethylphenol HOCbH4CzH5

219 (1041

1.0Q 140°F

5

2

(60°C) Note: Meltina ooint Il5 1461. Ethyl Phenylaceiate C6H5CH2COOC2H5

210 (99)

E t h y l Phenyl Nher

See Ethoxybenrene.

1.o-I

(274

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 9Y W bY74Y4b 0528317 543 325-54

PROPERTIES OF FLAMMABLE LiQUiDS, GASES, VOLATILE SOLIDS

FLASH POINT 4CC)

FLAMMABLE Vapor Sp.Gr. Density IGNITION LIMITS TEMP. Percent by vol. (Water (Air 'FCC) Lawer Upper =1) =i)

Ethyl Phenyl Ketone CZH~COC~H~ (Propiophenane)

210 (99) ( 4 Note: Melting paint 70 (21).

Ethyl Phosphate

See Triethyl Phosphate.

Ethyl Phtholyl Ethyl Glycolate C2H50COCaH40COCHZOCOC~H~

365 11851

Ethyl Propenyl Ether CH,CH:CHOCH?CH3

1.01

> 19 ( > -7)

BOILING

POINT "F ("C)

4.63

54 112)

2-Ethyl-3-Propylacrolein C3H7CH:C(C2H5)CHO (2-Ethylhexenal) 2-Ethyl-3-Propylacrylic Acid CSH~CH:C(C~H~)COOH

824 14401

1.2

608 (320)

0.8

158 (70)

O

2 5

O

1

O

1

2

3

1

3

O

3.5

210 (991

No

1

155 (68) (oc)

0.9

4.4

347 (175)

No

5

2

2

1

330 (166) facl

0.9

450 (232)

Slight

2

2

1

1

1

3

O

2

2

O

1.7

Ethyl Slllcate (CzH5)4Si04 (Ethyl Orthosilicate) (Tetraethyl Orthosilicate)

125 (52) lac)

Ethyl Sulfate

See Diethyl Sulfate.

Ethyl Sulfhydrate

See Ethyl Mercaptan.

11

Yes

1

0.9

< -4 ( < -20)

1.9

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamme- ReacHealth bility tiviiy

425 (218)

(4 E t h y l Propionate CzH,COOC,H5

Ethyl Propyl Ether CzH50C3H7 (1-Ethaypropane)

m

9.0

m-Ethyltoluene CWaH4CzH5 (1-MethyJ-3-Ethylbenzene)

0.8

147 (64)

5 Yes

5

0.9

7.2

334 (168)

Decomposes

0.88

4.15

322 1161)

2

O

o-Ethyltoluene CH~C~H~CZH~ (1-Methyl-2-Ethylbenzene)

824 (440)

0.88

4.15

329 1165)

2

O

p-Ethyltoluene CHJC~H~CZ~ Il-Methvl-4-Ethvlbenzenel

887 (475)

0.88

4.15

324 (1621

2

O

2

1

O

2

1

O

Ethyl p-Toluene Sulfonamide

260 11271

1.3

208 1981

@ 745 mm

Ethyltrlchloro Silane CH3CHzSiC13

72

1.2

345 (174)

1.2

208 (98) @ 745

(22)

(4

Na

1

3

3

2w

2

O

1

O

3

O

mm

E t h r l Vinvl Ether

See Vinvl Ethvl Ether.

Ethyne

See Aceiylene

Fish Oil

420 12161

Fluorobenzene CAH~F

_ _

No

5 (-151 . .

1.03

Formal

See Methylal.

Fonnalln

See Formaldehyde.

Formaldehyde HCHO 37% Methanol-free

Gas

37%. 15% Methanol (Formalin) (Methylene Oxide)


185 185)

795 (424)

7.0

73

122 150) Note: See Hazardous Chemicals Data.

3.31

185 (851 . .

1.0

-3 (-19) 214 1101)

--```,,`-`-`,,`,,`,`,,`---

Not for Resale

Yes

6

3

4

O

5

3

2

O

3

2

O

NFPA 325 94

b47444b 0528338 4 8 T

m 325-55


FLAMMABLE Vaoor Sp. Gr. Density BOILING FLASH IGNITION LIMITS POINT POINT TEMP. Percent by vol. (Water (Air "F ("C) "F rC) Lower Upper =i) =i) 'FrC) 310 (154)

1.1

(oc)

Fonnic Acid HCOOH 90% Solution

156 1004 (691 (539) 122 813 18 57 (50) (434) Note: See Hazardous Chemicals Dato.

Formic Acid, Butyl Ester

See Butyl Formate.

Formic Acid, Ethyl Esier

See Ethyl Formate.

Formic Acid, Methyl Ester

1.2

1.6


Yes

2

2

1

213 (101)

Yes

5

3

2

O

304-574 (151-301)

No

O

2

O

See Methyl Formate.

Fuel Oil No. 1 (Kerosene] (Range Oil) (Coal Oil)

100-162 (38-721

410 (21O)

Fuel Oil No. 2

126-204 62-96)

494 12571

<1

No

O

2

O

Fuel Oil No. 4

142-240 (61-1 16)

505 (263)

<1

No

O

2

O

<1

No

O

2

O

It-

No

O

2

O

Fuel Oll No. 5 Light Heavy

Fuel Oil No. 6

5

<1

156-336 (69-1 69) 160-250 (71-121) 150-270 (66-1 32)

765 1407)

2-Furaldehyde

See Furfural.

Furan CH:CHCH:CHO

(
u

0.7

i32

2.3

14.3

0.9

2.3

88 (311

No

1

1

4

1

2.1

19.3

1.2

3.3

322 (161)

Slight

5

3

2

O

1.1

4.8

356-367 (180- 186)

No

3

1

2

1

1.1

3.4

340 (1711

Ye5

5

1

2

1

1.05

3.35

295 046)

3

O

O

[Furfuran) Furiural 0CH:CHCH:CHCHO

u

(2-Furaldehyde) (Furfuroldehyde) (Furol)

140 (60)

600 (316)


Furfuraldehyde

See Furfural.

Furhiran

See Furan.

FurfurylAcetate 0CH:CHCH:CCHzOOCCHs

ia5 (85)

u ~~

Furfuryl Alcohol 0CH:CHCH:CCHzOH

u

167 (751

915 1491)

1.8

16.3

(4

Furfuqlamine C~H~OCHZNH? Furol

See Furfural

FuselOil

See Isoamyl Alcohol.

Gas, Blast Furnace

35

74

6

2

4

Gas, Coal Gas

5.3

32

6

2

4

O

Gas, Coke-Oven

4.4

34

6

2

4

O

3.86.5

1317

6

1

4

O

Gas, Natural (Natural Gas]

9001170 (4826321

Gas, Oil Gas

4.8

32.5

6

2

4

O

20-30

70-80

6

2

4

O

Gas, Water

7.0

72

6

2

4

O

Gas, Water ICarbureted)

5.6

46.2

6

2

4

O

0.5

5.0

O

2

O

Gas, Producer

Gas Oil

150+ 166~1

640 (338)

<1

500-700 (260-371)

No


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Formamide HCONHz

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING H&ZARD METHODS IDENTIFICATION Flarnma- ReacHeolth biiity tivity

NFPA 32s 94 325-56

b 4 7 4 4 4 b 0528339 33b


FLASH IGNITION POINT TEMP. “F (“C) “F [“C) Gasoline C5HlZ to C9bO 56-60 Octone 73 Octane 92 Octane 1O0 Octone

- 45 (-43) -45 (-43)

FLAMMABLE Vaaor _.___ LIMITS Sp. Gr. De& (Air Percent by vol- (Water Lower Upper =1) =1)

1.4 536 (280)

7.6

1.4

7.6

1.4 1.5 1.4

7.6 7.6 7.4

0.8


3-4

100-400 (38-204)

Water Soluble No

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Aarnrna- ReacHealth bile liviiy

‘1

1

3

O

-36 853 (-38) (456) Note: Volues may vary considerably for different grodes of gasoline. ~

~

Gasoline 100-1 30 (Aviation Grode)

-50 ( - 46) (approx.)

824 (440)

1.3

7.1

1

3

O

Gasoline 115-145 (Aviation Grade)

-50 (-46) íopprox.)

880 (471)

1.2

7.1

1

3

O

No

1

1

4

O

446 (230)

No

5

O

1

O

0.9

468-473 (242-245)

No

5

O

1

O

0.9

304 (151)

No

5

O

1

O

0.9

235 (113)

No

5

O

2

O

5

O

1

O

No

2

1

1

O

340 (171)

Yes

2 5

1

1

O

496

Slight

2 5

1

1

O

Gasoline (Casinghead)

O (-18) or less

Geraniol (CH,)zC:CH(CH2)?C(CH3):CHCHzOH (Irons-3.7-Dimethyl-2.6. Octadien- 1-01)

2212 (>loo)

0.9

>212

Geranyl Acetale CH~C~OC~OHIT (Geraniol Acetate)

( > 100)

~

Geranyi Butyrate C+WX”ioHi 7 (Geraniol Butyrate)

>212 (>loo)

Geranyì Formate HCOOCloHi 7 (Geraniol Formate) Geranyl Propionate CzH5COOCioHi7 (Geraniol Propionote)

185

(85) >212 ( > 100)

0.9

Gin

See Ethyl Alcohol and Water.

Glucose Pentapropionate C6H706íCOC2H5ì5 (PentapropionylGlucose) (Tetrapropionyl Glucasyl Propionote)

509 (265)

Glycerine HOCHzCHOHCH20H (Glycerol)

390 (199)

401

1.2

(205)

@2mm

1.3

698 (370)

a,p-Glycerin Dichlorohydrin CHZCICHCICH~OH

200 (93)

Glycerol

See Glycerine.

Glyceryl Triacetate (C3H5K00CCH313 (Triacetin)

280 (138)

3.1

1.4

812 (433)

1.0

1.2

63

(2581

373 f 1891

0.5

Glyceryl Tributyrate C~H~(OOCCJH~)~ (Tributyrin) (Butyrin) (Glycerol Tributyrate)

356 (180) (oc)

Glvcenl Trichlorohrdrin

See 1.2.3-Trichloro~rooone.

Glyceryl Trinilrale

See Nitroglycerine.

Glyceryl Tripmpionate (CZH~COO)~C~H~ (Tripropionin)

332 (167) (oc)

790 (421)

141 (61)

779 (415)

765 (407)

1.0+

597 (314)

No

5 2

O

1

O

1.1

540 (282)

No

5 2

O

1

O

@ 406 (208)

~~

Glycidyi Acrylate CH2:CHCOOCHzCHCHzO

u

0.8

63

367 1.1

4.4

135 (57) @2mm

No

O

2

O

1.07

5.20

493 (256)

No

O

1

O

IOCI ~~

~

~

Glycol

See Ethylene Glycol.

Giycol Benzyl Ether C~H~CH~OCHZCHZOH (2-Benzylonpthonol)

264 (129)

662 (350)

--```,,`-`-`,,`,,`,`,,`---

(04


Not for Resale

NFPA 325 94

= b 4 7 4 4 4 b 0528320 038 W 325-57

PROPERTIES OF FIAMMABLE LIQUIDS, GASES, VOLATILE SOLIDS

FIAMMABLE Vapor FLASH IGNITION LIMITS Sp.Gr. Density POINT TEMP. Percent by vol. (Water (Air =i) 'F('C) "FCC) Lower Upper =1) Glycol Diacetate (CHIOOCCHJ~ (EthyleneAcei&) 1EthvleneGlvcol Dioceatel

191 1881

900 14821

1.6

Glycol Dichloride

See Eihylene Dichloride.

Glycol Ditormate

See 1.2-Ethonediol Diformote.

Glycol Dimercaptoacetate

396

8.4

BOILING POINT OF(%)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility tivlty

1.1

375 11911

Slight

5

1

1

O

1.3

280 (1 38)

No

5

2

1

O

2

12mm

Glycol Monoacetate

See Ethylene Glycol Monooceioie.

Grain Alcohol

See Eihvl Alcohol.

Heavy Hydrogen

See Deuterium

Hendecane CH~(CHZ)~CH~ (Undecone)

149 165)

0.7

5.4

384 (196)

No

1

O

2

O

588

No

2

O

1

O

1

1

3

O

O

2

O

O

2

O

2

2

O

(oc1

Heptadecanol 310 C ~ H ~ C H ( C Z H ~ J C Z H ~ - (1541 C H ( O ~ ) C Z H & ~ ( C Z H ~ ) Z (oc1 (3,9-Diethyl-6-Trideconol) Noie: Melting point 130 (54). Heptane CH~(CHZ)~CH~

25 (-4)

2-Heptan01 CH,(CHz)4CH(OH)CH3

399 (204)

1.05

0.8

(309)

6.7

0.7

3.5

209 (981

No

160 (71)

0.8

4.0

320 (160)

No

3-Heptan01 CH~CHZCH(OH)CAH~

140 (60)

0.8

4.0

313 (156)

Slight

3-Heptanone

See Ethyl Butyl Ketone.

4-Heptanone (C3H7)zCO (Butyrone) (Dipropyl Ketone)

120 (491

0.8

3.9

290 (143)

No

5

1-Heptene

See Heptylene.

3-Heptene (mixed cis and trans) C~H~CH:CHCZC~ (3-Heptylene)

21 (-61

0.7

3.39

203 (951

No

1

O

3

O

Heptylamine CH~(CHZ)~HZ (1-Aminoheptane)

130 (541 lot)

0.8

4.0

31 1 (1551

Slight

5

2

2

O

Heptylene C5Hi iCH:CH2 (1-Heptene)

<32 (
0.7

3.39

201 (94)

O

3

O

Heptylene-2-trans C4H9CH:CHCHs (2-Heptene-trans)

< 32 (
0.7

3.34

208

O

3

O

2

1

1

2

1

1

O

1

O

O

1

O

O

1

O

3

1

O

500 (260)

198)

Hexachlorobutadiene CCI.i:CCICCI :cc19

1130 16101

Hexachloro Diphenyl Oxide íC6HzCI~ìz0 [Bis(Trichlorophenyl]Ether]

1148 (6201

Hexadecane Ch(CHz1I4CH3 (Cetone)

No

>212 396 ( > 100) (202! Note: Melting point 68 (20).

8.99 13.0

0.8

7.8

549 (287)

No

298-307 (148-153) Q 1 1 mm

No

525

No

@

68

(20) tetî-Hcxadecanethiol Ci6H33sH (Hexodecy-ieri-Mercapton)

Hexadecylene-1 CH,(CH~)IJCH:CH~ (1-Hexadecene)

265 (12'4

0.9

(oc)

>212 ( > 100)

464 (240)

Hexadecyl-tart-Mercaptan

See tert-Hexodeconethiol.

Hexadecyltrlchlororilane C16H33SiC13

295 (146)

0.78

7.72

2

(2741

1.0-

516 1269)

Yes

2

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94 W 6474446 0528323 T 7 4 325-58


FIAMMAELE Vapor F W H IGNITION LIMITS Sp. Gr. Densiiy POINT TEMP. Percent by vol. (Water (Air =1) =i) "F("C) "F("C) Lower Upper 154 (68)

2.4-Hexadienal CH,CH:CHCH:CHC(O)H

1.3

8.1

0.9

2.0

6.1

0.7


Water Soluble

339 (171)

Very slight

2.8

151 (66)

No

0.8

3.6

268 (131)

0.7

3.0

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flammo- ReacHealth biliiy tiviiy 2

2

O

1

O

3

O

No

1

2

3

1

156 (69)

No

1

1

3

O

429 1221)

Yes

2

2

1

O

352 (1 78)

Yes

1

1

O

1

3

O

(OC1

1.4-Hexadiene CH3CH:CHCHzCH:CHz (Allylpropenyl)

-6

(-21)

Hexahydroaniline

See Cyclohexylamine.

Hexahydrobenzene

See Cyclohexane.

Hexohydropyridine

See Piperidine.

Hexahydroioluene

See Meihylcyclohexane.

Hexahvdroxvlol

See 1,4-Dimethylcyclohexane.

Hexoklehyde

See Hexanol.

Hexalln

See Cvclohexanol.

Hexalin Acetate

See CyclohexylAcetate.

Hexamethylene

See Cyclohexane.

Hexanal CHj(CH?)&HO (Caproaldehyde) (Hexaldehyde)

90 (321

(4

Hexane CH~(CHZI~CH, IHexyl Hydride1

-7

1-22)

~~

437 (225)

1.1

7.5

~

If-Hexanediol

See Hexylene Glycol.

2.5-Hexanediol CH&H(OH)CHzCHzCH(OH)CH, (2.5-Dihvdrowhexane)

230 (110)

2.5-Hexanedione

See Acetonyl Acetone.

1.2.6-Hexanetriol HOCHzCH(0H)(CHZ)~CHZOH

375 (191)

Hexanoic Acid

See Caproic Acid.

1.o

5

~

1.1

(4

2 5

@5mm

1-Hexanal

See Hexyl Alcohol.

2-Hexanone

See Methyl Butyl Ketone.

3-Hexanone CZH~COCJH~ (Eihyl n-Propyl Ketone)

95 (35)

-1

-8

0.82

3.46

253 1123)

487 (253)

0.7

3.0

146 (631

No

1

1

3

O

473 (245)

0.7

3.0

155 (68)

No

1

1

3

O

< -4 (< -20)

O69

290

156 (69)

O

3

O

3-Hexenol-cis CHBCH~CH CHCHzCHzOH (3-Hexen-1-01) (Leaf Alcohol)

130 (54)

O85

345

313 (1561

5

1

2

O

Hexone

See Methyl Isobutyl Ketone

5

1

2

O

5

1

2

O

O

2

O

2

3

O

(4

c20

1-Hexene CHz:CH(CH&ZH3 (ûutyi Ethylene)

( < -7)

2-Hexene (Mixed clr and lrans isomers) CHnCH:CHlCH,l,CHR

1 < - 7)

<20 ____

2-Hexene-cis C3H7CH CHCH3

Slight

Hexyl Alcohol CH~(CHZJ.~CHZOH (Amyl Carbinol) (1-Hexanol) sec-Hexyl Alcohol C4H9CH(OH)CH, (2-Hexanol)

145 (631

0.8

3.5

31 1 (155)

136

0.81

3.53

284 (140)

0.8

3.5

269 (132)

(58)


Not for Resale

Slight

Slight

1

5

--```,,`-`-`,,`,,`,`,,`---

~~

Hexyl k R t & 113 (CH~)ZCH(CHZ)~OOCCH~ (45) (Meihylamyl Acetate)

NFPA 325 94

m

b 4 7 4 4 4 b O528322 700

m 325-59

PROPERTIES O F FIAMMABLE LIQUIDS, CASES, VOLATILE SOLIDS

FLAMMABLE VaDor LIMITS Sp. Gr. Densliy (Air Perceni by vol. (water Lower Upper = 1) =i)

F W H IGNITION POINT TEMP. O F (“Cl “F (“C)

Water Soluble

See 1-Chlorohexone.

Hexyl Cinnamic Aldehyde > 2 12 C ~ H I ~ C ( C H O ) : C H C ~ H ~ ( > 100) (Hexyl Cinnamoldehyde)

1.0-

486 (252)

5

Hexylene Glycol CHZOHCHOH(CHZ)~CH~ (1,Z-Hexanediol)

215 (1 02)

0.9

385 (196)

2

Hexyl Ether C6Hi30C6Hi3 íDihexvl Ether)

170 (77)

Hexyl Hydride

See Hexane.

Hexyl Methacrylate C~HI~OOCC(CH~):CH~

180 182) (oc)

Hexvl Methvl Ketone

See 2-Octanone.

Hydmctylonitrile

See Ethylene Cyonohydrin.

Hydmlin

See Cyclohexonol.

Hydrazine (Anhydrous) HiNNH2

1O0 2.9 98 1.0+ 1.1 236 138) 11131 Ignition temperatures vory widely in contact with iron rust 74 (23); black iron 270 (132); stoinless steel 313 (156); glass 518 (270). Note: See Hazardous Chemicals Dota.

1 4

Hydrocyanic Acid-96% HCN (Prussic Acid) (Hydrogen Cyanide)

0.8

6.4

440 (2271

0.9

5.9

388-464 (198-240)

565 (296)

0.9

O

(-18)

1000 (538)

5.6

40.0

1

O

2

2

O

O

2

O

3 3 Vapors explosive.

Yes

318 11591

3

O

5

0.7

0.9

79 (26)

o. 1

-422 í - 2521

2 4 4 Vapors edremely toxic.

Yes

Noie: See Hazardous Chemicals Data. Gas 932 4.0 75 I5001 Note: See Hazardous Chernicols Data.

Hydrogen Cyanide

See HydrocyonicAcid.

Hydrogen Sulfide HzS

500 4.0 44.0 (260) Note: See Hazardous Chemicols Data.

Hydroquinone CaH4(0H)z íHQ) (Quinol) (Hydroquinol)

329 (165)

960 (516)

Hydroquinone Di(ß-Hydroxyethyl) Eiher C6Hd(-OCH2CH20H)?

435 (224)

875 (468)

1.2

Gas

-76

Slight

6

O

4

O

Yes

6

4

4

O

No

5

2

1

O

I- 60) 1.3

547 (286)

365-392

2

Slight

2

1

O

No

2

1

O

Slight

5

1

O

1

2

@

0.3 mm (185-200)

Note: Melting point 201-205 (94-96). HydroqulnoneMonomeihyl Ether CH30CbHdOH (HQMME) (4-Methoxy Phenol) (Para-Hydroxyanisole)

270 (132) ( 4

o-Hydroxybenzaldehyde

See Solicyloldehyde.

3-Hydroxybvlanal

See Aldol.

Hydroxycitronellal ICH~IZC(OH)(CHZ)~CH(CH3)CHzCHO (Citronellal Hydrate) (3.7-Dimeihyl-7Hydroxyoctanal)

1

See Ethyl Chloride.

Hydrogen Hz

ß-Hydroxybuiyraldehyde

No

O

(oc)

Hydnndane CPH16 (Hexohydroindane) (Odahydroindene) Hydrochloric Eiher

365 11851

1

790 (421)

1.5

475 (246)

0.9

201-205 (94-96) @ 1 mm

1.1

410 (210)


See Aldol. >212 (>loo)

N-(P-Hydroxyethyl)acetamide

See N-Acetyl Ethanolamine.

2-Hydroxyeihyl Acrylaie (HUI

214 (1011

1.8 @ 100°C

Yes

2


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Hexyl Chloride


SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZAûD METHODS IDENTIFICATION Flamma- ReacHealih billiy tivhy

NFPA 325 94 325-60

b47444b 0528323 847 W


__

FLAMMABLE V.a-rw-r ~ . ._ FLASH IGNITION LIMITS Sp.Gr. Density BOILING POINT TEMP. ParCent by vol. (water (Air POINT "F("g 'FrC) Lomr Upper =1) =1) "F ("C)

ß-bdroxvethrlaniline . .

. .

See 2-Anilinoethanol.

N-(2-Hydroxyethyl) Crclohemlamine c,i, NHC~~I~OH

249 11211 . .

,

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Flamma- ReacHealth blliiy iivity

Yes

2 5

3

1

O

460-464 (238-240)

Yes

2 5

1

1

O

437 (2251

Yes

5

2

1

O

475 (246)

Yes

2 5

O

1

O

465 (241)

Yes

2

2

1

O

1.2

158 170)

Yes

2

O

3

0.9

259-262 (126-1 28) @ 12 mm

Slight

5

0.9

284 (1401 @lamm

No

5

2

3

1W

(4

275 (2-Hydroxyethyl)Ethylenediamine (135) CH~OHCHZNHCHZCHZNHZ

1.0+

210 1991

4-(2-Hydroqethyl) Morpholine CZH~OCZH~NCZH~OH

1.1

(4

u

1-(2-Hydroxyethyl) Piperazine

255 (124)

1.1

n-(2-Hydroxyethyl) Propylenediamine CH3CH(NHCzHdOH)CHzNHz

260 (127)

1.0-

Hydroxylamine "*OH (Oximmonium)

Explodes

4.5

~

5

(OC)

8 265 (129) Note: Melting poinl 92 (33). See Hazardous Chemicals Doto.

4-Hydroxy-4-Methyl-2Pentanone

See Diacetone Alcohol.

Z-Hvdroxv-2-me(hvlbropiónitriie

See Acetone Cyanohydrin. . .

-

Hydroqpropyl Acrylate

See Propylene Glycol Monoocrylote.

o-Hydroxyioluene

See o-Cresol.

lonone Alpha (a-lonone) z 212 C(CH~)ZCHZCHZCH:C(CH~)( Z100) CHCH:CHC(CH3):O (a-Cyclocitrylideneocetone) [4-(2,6,6-Trirnethyl2-Cvclohexen-1-vl)-3., Buten-2-one] lonone Beta (p-lonone) C(CH3)zCHzCHzCHzC(CH,):CCHCHC(CH3):0 (P-Cyclocitrylideneacetone) [4-(2,6,6-Trimethyl-lCvclohexen-l -vl)-3., Buten-2-onel

> 21 2 (2100)

Iron Carbonyl FelC0)s

Isano Oil

5

1.45

680 (360)

Isoamyl Alcohol (CHj)zCHCHzCH2OH (Isobutyl Carbinol) (Fusel Oil) (3-Methyl-1-Butanol)

662 (350)

109 (43)

1.0

0.9

4.5

290 (143)

Slight

5 1

1

3

O

9.0

0.8

3.0

270 (132)

Slight

5

1

2

O

0.88

5.45

352 (178)

2

0.89

3 67

212 1100)

3

212 (100)

1.2

@ 212 (100)

See 2-Methyl-2-Butanol.

< 70 (
1.5

7.4


1 3 May explode above 502 (261).

7.5

@

Isoamyl Bufymte 138 C~H~COZICHZIZCHICH~)~1591 (IsopentylButyrate) isoamyl Chloride (CH3)2CHCHzCHzCI ( 1-Chloro-3-Methylbutane)

22 1 (105)

1.0Exothermic reaction above 502 (261) may become explosive.

Isoamyl Acetate 77 CH~COOCHZCHZCH(CH~)Z (25) (Banano Oil) (3-Methyl-1-Butanol Acetote) (2-Methyl Butyl Ethanoate)

terl-Isoamyl Alcohol

6.74

(-15)

Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Note: Melting point 97-102 (36-39).

NFPA 325 94

6474446 0528324 783 325-61

PROPERTIES OF FIAMMABLE I.IQUiDS, GASES, VOL.4TII.E SOI.IDS

FLASH IGNITION POINT TEMP. "F ("C) "F("C)

FIAMMABLE Vonor LIMITS Sp.Gr. Dekity Percent by Vol. (Writer (Air Lower Upper =i) =i)

IsobornylAcetate C,,Hl,OOCCH3

190 (88)

Isobutone íCMCH (2-methyl propone)

Gos

860 (460)

1.8

8.4

Isobutyl Acetak CH3COOCHzCH(CH3)2 (ß-MethylPropyl Ethonoote)

64 (18)

790 (421)

1.3

10.5

Isobutyl Acrylate (CH3)2CHCHzOOCCH:CH?

86 (30) (oc1

800 (427)

Isobutyl Alcohol (CH3)zCHCHzOH (Isopropyl Corbinol) (2-Methyl-1-Propanol)

82 (28)

780 (415)

Isabutylamine ICHdzCHCHzNHz

15 1-91

712 (378)

Irobutylbenzene (CH~JZCHCHZC~H~

131

(55)

802 (427)

Isobutyl Butyrate C~H~COZCHZCH(CH~]Z

122 (501

Isobutyl Carbinol

See Isoomyl Alcohol.

Isobuíyiene Isobutyl Formate HCOOCHKH(CHd7

1.7

8 123 (51)

0.8

4 70 k211

2.0

10.6 @ 202 (94)

6.0

8.8

525 (274)

Isobutylcyclohexone (CH3ìzCHCHzC6Hii

5

1

2

O

2.0

11 (-121

No

6

1

4

O

4.0

244 (1 18)

No

5

1

3

O

1

3

1

4.42

1

5

142-145 (61-63) @ 15mm

1

0.8

2.6

225 (1071

Yes

5 1

1

3

O

0.7

2.5

150 1661

Yes

5 1

2

3

O

0.9

4.6

343 (173)

No

2

2

O

0.87

5.0

315 (157)

O

2

0.9

3.2

156 (691

2

3

336 (169)

O

0.8

O

O

See 2-Methylpropene. 470 (<211

608 (3201

Isobutyl Heptyl Ketone (CH3)2CHCHzCOCHzCH(CHB)CH~CH(CH~)? (2,6,8-Trimethyl-4Non- anone)

195 (911

770 i4101

Isobutyl Isobutymie (CH3)2CHCOOCHzC W h h

101 1381

-1.7

-8

0.88

3.52

0.8

208 198)

3

412-426 (211-219)

No

5

291-304 (144-151)

No

5

O

2

O

5

O

1

O

(4

810 (4321

0.96

7.59

0.9

Isobutyl Phenyiacetote >212 >~100) ~ C H ~ ) Z C H C H ~ O O C C H Z1C H~

1.o

Isobutyl Phosphate POI(CHZCH(CH~)ZI~ (Triisobutyl Phosphote]

275 (135)

0.98

Isobutyl Vinyl Ether

See Vinyl Isobutyl Ether.

Isobutyroldehyde (CH3)zCHCHO (2-MethvloroDonoll

No

4.97

477 12471 9.12

302

1

wu

4 20 mm

(oc)

-1 (-18)

385 (196)

1.6

10.6

0.8

2.5

142 (61)

Slight

5 1

2

3

1

Isobutyric Acid ICHIIKHCOOH

132 (56)

900 14811

2.0

9.2

1.0-

3.0

306 (1521

Yes

5

1

2

O

Isobutyric Anhydride I(CH3lzCHC0lz0

139 (59)

625 (329)

1.0

6.2

1.0-

5.5

360 (18 2 )

Decomposes

5

1

2

1\41

Isobutyronitrile (CH3)zCHCN [ 2-methyl proponenitrile) [ Isopropylcyanide]

47 (8)

900 (482)

0.8

2.38

214-216 (101-102)

Slight

5 1

3

3

O

0.8

5.4

387 (197)

O

2

O

0.73

4.91

333 (167)

O

2

O

0.9

5.9

489 (254)

O

1

O

Isodecoldehyde C9HI&o Isodecane C7Hi5CHíCH3lz (2-Methylnonone) Isodecanoic Acid C9HlpCOOH

410 (210) 300 (1491 (oc1

No

No

2


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Isobutyl Chloride (CH3)zCHCHzCI (1-Chloro-3-Methylpropane)

0.9

Water Soluble

428-435 (220-224)

1.0-

0.9


SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Fiammo- ReocHealth bility tivity

b47444b 0528325 bLT

NFPA 325 94

FLAMMABLE Vaoor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by Vol. (Water (Air 'F('C) "F("C) Lower Upper =i) =i) isodecanol, Mixed Isomers CiaHziOH

220 (1041

0.8


5.5

Water Soluble


428 1220)

No

2

O

1

O

514 12681

No

5

O

1

O

194 1901

No

1

O

3

O

!oc)

isoevgenoi (CH3CHCHICbH30HOCH3 (1-Hydroxy-2-Methoxy4 Propenylbenzene)

>212 I > 100)

Isoheptane (CH~I~CHC~HP (2 Methylhexone)(Ethyl isobutylmethane)

10

60

O7

345

428 (220)

I O

6O

0.7

176-195 (80-91)

No

1

1

3

O

( < - 18)

< -20 ( < -29)

507 (264)

I O

7.0

0.7

134-142 (57-61)

No

1

1

3

O

2

O

Isoheptane, Mixed Isomers Isohexane (Mixture of Hexone

1 1

Isomers)

tert-isohexyl Alcohol CZHS~CH~ICIOWZHS 13-Methvl-3-Pentonoli

1I5 1461

Isooctane ~CH~IZCHCH?CICH~I~

40 14 51

(2.2,4-Trimethylpentane)

--```,,`-`-`,,`,,`,`,,`---

784 (4181

o7

394

210 199)

No

1

O

3

O

738 (392)

09

50


No

2

O

1

O

3.87

1

O

3

O

5

O

2

O

(oc1

Isooctanoic Acid (Mixed isomers) CAH ,COOH

270 (132)

isooctenes

< 20 1-71

O7

180

08

(oc1

can16 Isooctyl Alcohol CiHisCHzOH

1821

[lsoocionol)

190-200 (88-93)

83-91 ( I 82-1 95)

No

106-109 (41-43)

No

(oc1

10-

1

@ I rnm

Isooctyl Vinyl Ether

See Vinyl Isoociyl Ether

Isopentaldehyde ICH3)zCHCHzCHO

48 191

250 11211

Slight

5 I

2

3

O

O6

82 128)

No

1

1

4

O

09

361 (183)

No

I

O9

419 12\51

Slighl

2

0.8

2.97

IOCI

Isopentane (CH3)?CHCH?CH3 (2-Methylbutone) (Ethyl Dimethyl Methane)

< -60 (<-51)

788 (420)

Isopentanoic Acid (CH3)2CHCH?COOH (Isovoleric Acid)

781 14161

Isophorone 184 COCHC(CH31CH2C(CH3)2CH? (84)

860 (460)

1 4

O8

7.6

3.8

356 11801

Isophthaloyl Chloride C,ddICOCIIi (m-PhtholylDichloride)

O

2

O

1

O

14

69

529 (2761

No

2

O 7

24

93 1341

No

1

1

4

2

o9

35

207 1971

Slight

5 1

2

3

O

0.7

23

92 (331

Slight

1 5

L

4

2

0.9

39

149 (651

Slighi

5

1

2

I

1 4

Note: Melting point 109 9 143)

I

Isoprene CHZ:C(CH~)CH.CHZ (2-Melhyl-1,3-Buiodiene)

-65 1-54)

743

1.5

Isopropanol

See Isopropyl Alcohol

Isacwooanolarnine . .

See 1 ~Amino~Z~Prooonol

Isopropenyl Acetate CH3COOC(CH3)CH2 (1 -MethylvinylAcetoie)

60 (161

Isopropenyi Acetylene CH?:C(CH3)CCH

8.9

13951

808 14311

cl9

i < -71 (04

2-lsooroooxvirrooone

See IsoDrooyl Eiher

3-lsopropoxypropionitrile (CH3)2CHOCHzCH?CN

1 55 1681

@lOmm


Not for Resale

NFPA 325 94

m

b 4 7 4 4 4 b 0528326 55b

m 325-63


FLASH POINT 'FCC)

IGNITION TEMP, "FCC)

FIAMMABLE Vapor LIMITS Sp. Gr. Densify BOILING Percent by vol. (Water (Air POINT Lower Upper =1) =i) 'F('C)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bilify tiviiy

Isopropyl Acetate (CH~)ZCHOOCCH~

35 121

860 (460)

1.8 (a 1 O0 1381

8

09

3.5

194 (90)

Slight

5 1

1

3

O

Isopropyl Alcohol (CH3)zCHOH (Isopropanol) (Dimethyl Carbinol) (2-Propanol) 87 9% i s 0

53 (12)

750 (3991

2.0

12.7

0.8

2.1

181 (83)

Yes

5 1

1

3

O

0.7

2.0

89

Yes

5 1

3

4

O

1

1

200 (93)

57 1141 -35 (-37)

@

756 (402)

(32)

(oc)

IsoDroDvlbenzene

See Cumene

Isopropyl Benzoate CbH5COOCH(CH3)2

210 1991

Isopropyl Bicyclohexyl C15H28

255 (124)

1.0+

~

--```,,`-`-`,,`,,`,`,,`---

446 (230)

2-lsopropylbiphenyl Ci5H16

285 (141)

Isopropyl Carbinol

See Isobutyl Alcohol.

Isopropyl Chloride (CH3)zCHCI 12-Chloropropane)

-26 (-32)

Isopropylcyclohexane (CH3lzCHC6HiI (Hexahydrocumene) (Normanthane)

815 (435)

1100 (593)

05

41

(a

@

302 (150)

400 (204)

05 @I

32

530-541 (277-283)

2

O

1

O

518 (270)

2

O

1

O

1

2

4

O

10-

(u

347 1175)

392 (700)

2.8

10.7

541 (283)

Isopropylcyclohexylamine CaHi iNHCHC2Hb

09

0.9

2.7

95 (35)

0.8

93 (34)

Very slight

310 (154.5)

0.8

4.9

0.7

3.5

1

O

No

1

3

3

O

156 (69)

Very slight

5

1

3

1

Slight

2

3

O

2

2

O

O

2

O

1

3

O

O

2

O

IOCI

Isopropyl Ether (CH~)ZCHOCH(CH~!Z (2-lsopropoxypropane! i~iisoDroDvìEther1

-18 (-28)

830 (443)

1.4

1

Note: See Hazardous Chemicols Dato.

Isopropylethylene

See 3-Methyl-1-Butene

Isopropyl Formate HCOOCH(CH3)z (Isopropyl Methanoate)

(-61

22

4-lropropylheptane C3H7'WC3H7)C3H7 im-Dihvdroxvbenzenel

905 14851

0.9

3.0

153 1671

491 12551

0.87

3.04

155 (68)

1.0-

4.2

Isopropyl-2HvdroxvDroDanoaie

See Isopropyl Loidate.

Isopropyl Lactate CH~CHOHCCOCH(CH~)Z (Isopropyl-2Hydroxypropionate)

130 (54)

Isopropyl Methanoate

See Isopropyl Formole

4-Isopropyl-1 -Methyl Benzene

See p-cyrnene.

331-334 (166-1 68)

Yes

5

(oc)

Isopropyl Vinyl Ether

See Vinyl Isopropyl Ether.

Isovalerone

See Diisobubl Ketone.

Jet Fuels Jet A and Jet A-1

7.9

400-550 1204-211111

110-150 f 43 -66I

Jet Fuels Jet B

-1010 +30 1-23to - 1 )

Jet Fuels JP-4

-101ot30 ( - 2 3 t o -1)

Jet Fuels JP-5

95-145 135-631

464 (240)

1.3

8.0

475 (246) (approx.!


Not for Resale

NFPA 325 94

m 6474446 0528327 492 m

325-(ì4

FLASH POINT "F("C) Jet Fuels JP-6

100 1381

FLAMMABLE Vapor IGNITION LIMITS Sp. Gr. Density TEMP. Percent by vol. (Water (Air 'F("C) Lower Upper =i) = 1 ) 446 (230)

0 6

37

08

BOILING POINT OF("C)

Water Soluble

250 (1211

No

36 1 (183)

Yes

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth biliiy tiviîy

(oc)

Kaichung Oil

See Peonul Oil (cookins]

Kerosene

See Fuel Oil No 1

Kerosene, Deodorized

See Ultrorene ~

--```,,`-`-`,,`,,`,`,,`---

Lactonitrile CH3CH(OH)CN

1 71 (771

Lanolin (Wool Grease)

l a r d Oil (Commercial or Animal)

098

245

4

2

1

460 (238)

833 (445)

No

2

0

1

0

395 (202)

833

No

2

0

1

0

(445)

No

2

0

1

0

1

1

0

440 12271

No 1

Lard Oil (Pure)

500 12601 419 (2151 404 12071

No 2

Minerol

09

L a u y l Alcohol

See 1 Dodeconol.

l a u r y l Bromide CH3iCH71ioCH2Br (Dodecyl Bromide)

291 11441

Lauryl MercaDtan

1.0+

356 (1801 @ 45 mm

No

2

0.9

383-390 1195-1 99)

No

5

0.9

600+ (316+)

No

2

0

1

0

680 (3601

No

2

0

1

0

0

2

0

0

1

0

2

0

See 1 -Dodeconethiol ~

Linalool (Ex Bois de Rose; Synthetic) (CH317C CHCHzCHzClCH3) OHCA CH2 (3,7 Dimeihyl 1,6 Oclodiene-3-01) linseed Oil, Raw

160 1711

432

(2221 Boiled

650 (343)

403 1206) See Camphor Oil (light)

Liquid Camphor lubricating Oil, Mineral (Paraffin Orl, includes Motor 01)

300-450 ( I 49-232)

Lubricating Oil, Spindle (Spindle 0111

169 I761

478 12481

Lubricating Oil, Turbine (Turbine Oil1

400 (204)

700 (371)

500-700 (2603711

<1

NO

NO

2

No

5

Slighi

5 2

3

1

1

No

2

0

1

0

315 (157)

Yes

5

2

2

266

Slight

1 5

2

3

< 1

/oc1

Lynalyl Acetate (Ex Bois de Rose; Synthetic) (CH3)2CCHCHiCH2Cl-OOCCH3)CH CH2 (Bergomol)

185 I851

09

Maleic Anhydride (COCHI70

215 890 14 (102) (477) Note Melt>ngpoint 127 (53) See Hozordous Chemicals Dolo

Marsh Gas

See Methone

Menhaden Oil

435 i2241

1Poav Oil1

226-230 11 08- 1 101

71

828 14421

2-Mercaptoethanol HSCH2CH70H

I65 (74)

Mesitylene

See 1.3 5-Trimethylbenzene

Mesityl Oxide (CH3)7CCHCOCH3

87 652 14 7.2 1311 (3441 Note: See Hozordous Chemicals Dolo

o9

396 (2021

09

I 1

2.7

0.9

3.4

(oc1

I

11301


Not for Resale

1

NFPA 325 94

= 6474446 0528328 329 M 325-65


--```,,`-`-`,,`,,`,`,,`---

FLAMMABLE VoDor FLASH IGNITION LIMITS Sp. Or. Density POINT TEMP. Percent by Vol. (Water (Air "F("C) 'F("C) Lower Upper =i) =i)

Metaldehyde (CZH4014 u-Methacrolein

97 (36)

BOILING POINT "F ("C) subl.

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICI\TION Flamma- Reoctiviiy Health bility

No

1

1

3

1

Yes

5

3

2

2

2

3

2

2

3

O

233-240 (112-116)

See 2-Methylpropenal

Methacrylic Acid CH?:C(CH3)COOH

171 (77)

(4

154 168)

1.6

8.8

1.0+

2.97

316 (158)

6.8

0.8

2.3

194 (90)

Slight

0.9

2.5

237 (114)

Slight

Note: Polymerizes. See Hazardous Chemicals Data. Methacrylonitrile C4H5N Methallyl Alcohol CHzC(CH$CH?OH Methallyl Chloride CH~C(CH~)CHZCI

2

34 (1.1) (TCCI 92 (331 11 (-12)

3.2

8.1

5.0

15.0

Methane CH4 (Marsh Gas)

Gas

Methanol

See Methyl Alcohol.

Methanethiol

See Methyi Mercaptan.

Methox

See Methoxy Ethyl Phthalate.

o-Methoxybenzaldehyde CH30C6H&HO lo-Anisoldehvdel Methoxybenzene

999 (537)

104 (40) foc1

0.9

1 5

3.1

162 (72)

No

1 5

2

3

1

0.6

-259 (-162)

NO

6

1

4

O

275 (135)

No

2

2

1

O

Yes

5

1

2

O

Slight

5

1

2

O

1.1

See Anisole

3-Methoxybutanol CHsCH(OCH31CH2CHzOH

165 (74) ( 4

0.9

3.6

322 (161)

3-Methoxybutyl Aceloh CH~OCH(CH~)CH~CHZOOCCH3

170 (77)

1.0-

5.0

275-343 (135-1 73)

140 (60)

0.94

3.52

262 1128)

O

2

O

1.01

4.49

142 (61) @17mm

O

2

O

O

1

O

(Butoxyl)

3-Methoxybuiyraldehyde CH~CH(OCH~)CHZCHO (Aldol Ether) 2-Methoxyethanol

See Ethylene Glycol Monomethyl Ether.

2-Methoxyethyl Acrylate CZH~COOCZH~OCH~ Methoxy Ethyl Phthalote (Methox)

180

(82)

(4

2

275 (135)

1.2

149 (651

0.92

2.94

320 (1601

4

2

1

3.07

241 1116)

2

3

O

3-MethoxypropionHrile CH30CzH4CN

376-412 (191-211)

(oc)

3-Methoxypropylamine CH~OC~H~NHZ

90 132)

0.86

Methoxy Triglycol CH~O(CZH~O)~H (Triethylene Glycol, Methyl Ether)

245 (1 18)

1 .o+

480 (2491

Yes

5 2

O

1

O

MethoxylriglycolAcetah CH3COO(C2H40)3CH3

260 (127)

1.1

266 (1301

Yes

2

O

1

O

(4 5

(4 Methyl Abietate CI~H~~COOCH~ (Abalyn) Methyl Acetote CHiCOOCHq (Ac& Acid Methyl Ester) (Methyl Acetic Ester) Methyl AceHc Ester

1 .o+

356 (180)

(w) (-

14 101

850 (4541

3.1

16

0.9

680-689 (360-365) Decomposes

No

2

O

1

O

140 i601

Yes

1 5

1

3

O

2.8

See Methyl Acetate


Not for Resale

325-66


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp.Gr. Denrily POINT TEMP. Percent by Vol. (Water (Air 'F("C) "F ("C) Lower Upper =i) =i) Methyl Acetoacetate CH~COZCHZCOCH~

170 (77)

p-Methyl Acetophenone CH~CAH~COCH~ [Methyl para-Tolyl Ketone) (p-Acetatoluene)

205 196)

536 (280)

1.1

4.0

1.0-

Methylacetylene

See Propyne.

a-Methylacrolein

See 2-Meihylpropenal.

Methyl Acrylate CH2:CHCOOCHs

27 875 2.8 1-31 (468) (oc) Note: Polymerizes. See Hazardous Chemicals Dota.

Methylal CHjOCHzOCH3 [Dimethoxyrnethane) (Formal)


Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility tivily

338 (170)

Yes

5

2

2

O

439 (226)

No

5

O

1

O

25

1.0-

3.0

176 (80)

Very slight

1

3

3

2

-26 (-32) (oc)

459 (237)

2.2

13.8

0.9

2.6

111 (44)

Yes

1 5

2

3

2

Methyl Alcohol CH30H (Methanol) v a a d Alcohol) ICalumbian Spirits)

52 111)

867 (464)

6.0

36

0.8

1.1

147 164)

Yes

1 5

1

3

O

Methylaluminum Sesquibromide ICH3)3AIzBr3

Nate: Ignites spontaneouslyin air.

3 3w Do not use water, foam or halogenated extinguishing agents.

Methylalumlnum Sesquichloride (CW3AIzCh

Note: Ignites spontaneouslyin air.

3 3w Da not use water, foam or halogenated edinguishing agents.

Methylamine CHBNHZ

Gas

2-(Methylamino) Ethanol

See N-Methylethanolornine.

Methylamyl Acetate

See Hexyl Acetate.

Methylamyl Alcohol

See Methyl Isobutyl Carbinol.

Methyl Amyl Ketone CH3CO(CHz).&H3 2-Heptanone

102 (391

2-Methylaniline

See o.Taluidine.

740 (393)

4-Methylaniline

See p-Toluidine.

Methyl Anthranilate H2NCbHiC02CH3 (Meihyl-ortho-Amino Benzoate) (Nevoli Oil, Artificial)

>212

1.1

7.9

166)

1121)

,F1 ,5,

See Toluol.

Methyl Benzoate CaH5COOCH3 (Niobe Oil)

181 183)

u-Methvlbenzvl . - Alcohol

21 1-6)

Yes

6

3

4

O

0.8

3.9

302 (150)

Slight

5

1

2

O

275 815mm (135)

Slight

5

O

1

O

1.2

[>loo)

Methylbenzene

1.o

--```,,`-`-`,,`,,`,`,,`---

806 4.9 20.7 (430) Note: See Hazardous Chemicals Data.

1.1

4.7

302 (150)

No

3

O

2

O

See Phenyl . Methyl . Carbinol

a-Methylbenzylamine CaH5CH(CH3)NHz

175 (79) ( 4

1.0-

4.2

371 (188)

Slight

5

2

2

O

a-Methylbenzyl Dimethyl Amine C~H~CH(CH~)N(CH~)Z

175 (79) (oc)

0.9

5.2

384 (196)

Slight

5

2

2

O

u-Methylbenzyl Ether C&I5CH(CH3)0CH(CHdCaH5

275 (135) (oc)

1.o

548 (287)

No

2 5

2

1

O

2-Methylbiphenyl CaH5CaH4CH3

280 (137) (oc)

936 (502)

492

l.O+

(255)


Not for Resale

2

O

NFPA 325 94

6474446 0528330 T87 W 325-67

i'KOPEHI'IES OF FLAMMABLE LIQUIDS, GASES, VOLATILE SOLIDS

FLAMMABLE Vawr FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol- (Water (Air OF(%) "F(.C) Lower Upper =i) =i) < 80

Methyl Borate WCH3)3 (TrirnethylBorate)


0.9

3.6

156 (69)

Decomposes

2

3

1

1.7

3.3

38.4 (4)

No

3

1

O

0.85

3.59

230 (110)

No

2

3

O

( <27)

Methyl Bromide CH$r (Bromarnethane)

Procticolly

999 (537)

10

16.0

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED U
non-flom-

moble Note: See Hozordous Chemicals Dota. 2-Methyl-1,%Butadiene

See Isoprene.

2-Methylbutane

See Isopentone.

3-Methyl-2-Butanethiol C5HiiSH (sec-Isoamyl Mercaptan)

37 (3) (oc)

2-Methyl- 1-Butanol CH~CHZCH(CH~)CH~OH

122 (50)

725 (385)

5 1

0.8

3.0

262 (128)

Slight

5

2

2

O

0.8

3.0

215 (102)

Slight

5 1

1

3

O

(4 2-Methyl-2-Butanol CH~CHZ(CH~)ZCOH (tert-IsoamylAlcohol) (Dimethyl Ethyl Carbinol)

67 (19)

819 (437)

3-Methyl-1-Butanol

See Isoamyl Alcohol.

3-Methyl-1-Butanol Acetate

See Isoamyl Acetate.

1.2

9.0

2-Methyl-1-Butene (Technical Grade) CH~:C(CH~)CHZCH~

< 20 ( < -7)

0.7

2.4

ô8 (31)

No

1

2

4

O

2-Methyl-2-Butene (CH3)2C:CCHCH3 ITrimethvlethvlenel

< 20 ( < -71

0.7

2.4

1 o1 (381

Slight

1 5

2

3

O

O6

24

68 120)

No

1

2

4

O

0.7

3.0

196 (911

Yes

1 5

3

3

O

0.8

3.5

262

Slight

1

2

3

O

~

3-Methyl-1-Butene (CH3)zCHCH:CHz (Isopropylethylene)

<20 ( < -7)

689 (365)

15

91

N-Methylbutylamine 55 C H ~ C H Z C H ~ C H ~ N H C H ~ (13)

(4

2-Methyl Butyl Ethanoate

See IsoamylAcetate.

Methyl Butyl Ketone CH3CO(CH2)3CH3 (2-Hexanone)

(25)

77

3-Methyl Butynol (CHJ)~C(OH)C:CH

77 1251

795 1423)

8

(128)

5

0.9

2.9

218 (103)

Yes

1 5

2

3

O

49 (9) (oc) Note: See Hazardous Chemicols Doto.

0.8

2.97

198-199 (92-93)

No

5 1

2

3

O

Methyl Butyrate CH300CCH2CH2CH3

57 1141

0.9

3.5

215 11021

Slight

1

2

3

O

Methyl Carbonate CO(OCH3)z (Dimethyl Corbonate)

66 119) (04

1.1

3.1

192 (89)

Slight

3

3

O

1.0

4.07

292 (144)

Yes

O

2

O

1.8

- 11 ( - 24)

Slight

1

4

O

1.2

3.8

266 (130)

Very slight

2

2

1

1.0-

4.21

2

O

(4 2-Methylbutyraldehyde CH3CH2CH(CH3)CHO

~~

I

Methyl Cellosolve Acetate CH3COOCzH40CH3 (2-Methoxyethyl Acetate)

I

-111 1-44

1.7

8.2

-50

Methyl Chloride CH3CI (Chloromethane)

1170 8.1 17.4 1632) Noie: See Hozordous Chemicals Doto

Methyl Chloroacetate CH2CICOOCH3 (Methyl Chloroethonoate)

135 (571

Methyl Chloroethanoate

See Methyl Chloroacetote.

Methyl para-Cresol CH3C6H40CH3 (p-Methylanisole) (p-Cresyl Methyl Ether, o-Methom Toluenel

140 (60)

7.5

18.5

1 5

6

(oc)

--```,,`-`-`,,`,,`,`,,`---


5

5

1994 Edition

Not for Resale

NFPA 325 94 325-68

m

6 4 7 4 4 4 b 0528331 913

m


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Densiiy POINT TEMP. Percent by vol. (Water (Air “F (“Cl Lower Upper =1) =i) “F (“Cl Methyl Cyanide

See Acetonitrile.

Methylcyclohexane CHz(CH2)4CHCH3

25 (-4)

482 (250)

149 165)

565 12961

3-Methylcyclohexanol CH&H 1oOH

-158 (-70)

563 (295)

4-MethylcyclohexanoI C7Hi30H

158 (70)

563 (295)

Methyicyclohexanone C7Hi2O

I

1.2

6.7

BOILING POINT O F (“C)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth biliiy tiviiy

0.8

3.4

214 (101 1

No

1

0.9

39

329 (1 651

Slight

5

2

3

O

2

O

2

O

2

O

2

O

1

3

O

(Cyclohexylmethone) IHexahvdromtoluene) 2-Methylcyclohexonol C7HiiOH

O

--```,,`-`-`,,`,,`,`,,`---

0.9

39

343 (1 73)

Slight

118 (48)

0.9

3.9

325 11631

No

4-Methykyclohexene 30 CH:CHCH~CH(CH~)CHZCHZ ( - 1 )

0.8

3.3

217 (1031

No

MethylcyclohexylAcetate C9Hl602

147 (64)

0.9

351-381 (1 77-1 94)

1

2

O

Methyl Cyclopentadiene C6H8

120 (49)

0.9

163 (73)

1

2

1

2

3

O

O

2

O

3

3

2w

O

2

O

1

1

O

2

1

O

3

1

O

1

2

1W

u (4

Methylcyclopentane c6H12

<20 ( < -7)

2-Methyldecane CH3íCH2)7CH(CH3)2 Methyldichlorosilane CH3HSiCI2

833 (445)

496 (258)

1.3

@

7.6

@

212 11001

212 (100)

1.0

8.35

437 (225)

15 >600 6.0 55 (-9) (316) Note: See Hozardous Chemicals Data.

85 1 (455)

1-Methyl-3,5-Diethylbenzene (CH~IC~H~(CZH~)~ 13.5-Diethvltoluenel

0.8

2.9

161 (72)

0.74

5.39

374 (190)

1.1

3.97

106 (41)

0.86

5.12

394 (201)

Methyl Dihydroabietate C19H31COOCH3

361 (183)

l.O+

Methylene Chloride CHICI? (Dichloromethane)

1033 13 23 None (556) Note: See Hazardous Chemicols Dota.

1.3

Methylenedianiline 428 HzNC~H~CH~C~H~NH~ (MDAJ (p,p‘-Diominodi(220) Phenylmethane) Note: Melting point 198-1 99 (92-93).

1.1

Methylene Dlisocyanate CWNCOJ2

1

2

689-698 (365-370) 104 (40)

Slight

748-750 (398-399) @ 78 mm

Slight

2.9

1

2

185

See Formaldehyde.

N-Meîhylethanolamlne CHJNHCH~CH~OH (2-(Methylamino) Ethanol)

165 (74)

0.9

2.6

319 (159)

Yes

5

2

2

O

-11

Yes

6

1

4

1

No

1

2

3

O

(04

Methyl Ether (CH3)2O (Dimethyl Ether) (Methyl Oxide)

Gas

Meihyl Ethyl Carbinol

See sec-ButylAlcohol.

662 (350)

2-Methyl-2-Ethyl74 1,3-Dioxolane (23) (CHJ)(C~H~)COCH~CH~O (OC)

3.4

27.0

1.6

( - 24)

0.9

4.0

u

See Propvlene Glvcol.


Yes

1

(85) Iod

Maihilene Oxide

Methyl Ethrlene Gbcol

No

5

Not for Resale

244 (118)

b 4 7 4 4 4 b 0528332 85T

NFPA 325

325-69


FLAMMABLE VaDor FLASH IGNITION LIMITS Sp. Gr. Denky POINT TEMP. Percent by vol. (water (Air "F ("C) "F ("C) lower Upper =i) = 1 ) --```,,`-`-`,,`,,`,`,,`---

I

Methyl Ethyl Ether CH30CzH5 (Ethyl Methyl Ether)

-35 374 2.0 10.1 (-37) (190) Note: See Hazardous Chemicals Doto.

2-Methyl-4-Ethylhexone <70 ( C H ~ ) ~ C H C H Z C H ( C ~ H ~ )(<21) ~ I4-Ethvl-2-Methvlhexone~

536 (280)

-0.7

3-Methyl-4-Eihylhexane 75 G H ~ C H ( C H ~ ) C H ( C ~ H ~ ) Z (24)

0.7

BOILING POINT "F pC)

2.1

51 11 1)

Methyl Ethyl Ketoxime CH&(C2H5]:NOH

16 (-9)

759 (404)

1.4

11.4

@

@

200

200

(93)

(93)

156-1 70 (69-77)

2-Methyl-3-Ethylpentane ~CH~IZCHCH(CZH~)~ (3-Ethyl-?-Methylpentone)

-

< 70 (~21)

860 (460)

Yes

1

1

4

1

5

0.72

4.43

273 (1 34)

0

3

0

0.72

4.43

284 (140)

0

3

0

0.8

2.5

176 180)

1

3

0

0.9

3.0

306-307 (1 52-153)

2

0

0.72

3.94

241 (1 16)

0.8

4.4

0.9

4.2

(3-Ethyl-4-Methylhexane)

Methyl Ethyl Ketone C2H5COCH3 (2-Butanone) (Ethyl Methyl Ketone)

Water Soiuble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Flamma- ReacHealth bility tivity

Yes

1 5

Slight

5

326 (1 63)

Slight

5

2

2

0

353 (1 78)

Slight

5

3

2

0

196-203 (91-95)

No

5

0

1

0

90 132)

Yes

1 5

2

4

0

144-147 (62-64)

No

1

2

3

1

1

2

0

I

2-Methyl-5-Ethylpyridine 1 55 N:C[CH~)CH:CHC[CZH~):CH (68) (oc)

Methyl Eugenol (CH30J2CaH3CHzCH:CHz (4-Allyl-1,P-Dimethoxybenzene) (4-AllylVeratrole) ( 1,2-Dimethoxy-4-Allylbenzene) (Eugenyl Methyl Ether) Methyl Formate CH300CH (FormicAcid, Methyl Ester] (Methyl Methanoate)

1.1

6.6

210 (99)

-2 (-19)

1.0+

840 (449)

4.5

23

1.0-

2.1

Note: See Hazardous Chemicals Doto. 2-Methylfuran CdHjOCHj (Sylvon)

- 22 ( - 30)

0.9

Methyl Glycol Acetate 111 CHZOHCHOHCH~CO~CH~ (44) (Propylene Glycol Acetate) Methyl Heptadecyl Ketone C i 7H35COCH3

I

4.6

255 1124) Note: Melting point 127 (53)

Methylheptenone (CH&C:CH(CH~)ZCOCH~ (6-Methyl-5-Hepten-2one)

135 (57)

0.9

Methyl Heptine Carbonate CH3(CHz)&:CCOOCH? (Methyl 2-Octynoate)

190 (88)

0.9

Methyl Hepiyl Ketone C7Hi5COCH3 (5-Methyl-2-Octonone)

140 (60)

680 (360)

2-Methyihemne
(280)

3-Methylhexane 25 C H ~ C H Z C H ( C H ~ ) C H ~ C H ~( C -4) H~

536 (280)

Methyl H q l Ketone CH3COCdH13 (2-Octanone) (Octanone)

125 (52)

M;yN2;yZine

17 1-8)

0.9

5.9

8

8

313 (156)

86 (30)

536

382 (194)

0.8

@ 180 (82)

2.5

92

4.35

329 (1 65)

No

2

0

1

0

343-345 (173-174)

No

5

1

2

0

2

0

0

2

0

5

4.9

361-383 (183-1 95)

No

0.68

3.46

194 190)

0

3

0

0.69

3.46

198 192)

0

3

0

0.8

4.41

344 (173.5)

0.9

1.6

190

(88)

No

5

0

2

0

Slight

1 5

4

3

2


Not for Resale

NFPA 325 94 325-70

m 6474446 0528333

79b

m


FLAMMABLE Vapor F W H IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol. (Water (Air =i) =i) Lower Upper "F("C) "FCC) Methyl-3-Hydroxybutyrate CH~CHOHCHZCOOCH~

180

1.1


4.1

(82)

Water Soluble


347 (1751

Yes

5

1

2

O

291 (144)

No

5

O

1

O

294 (146)

No

1

2

O

lor1

Methyl lonone Ci4HZZO (Irane)

0.9

>212

(>loo)

Methyl Isoamyl Ketone 96 CH~COCHZCH~CH(CH~)~ (36)

@ 16mm

375 (191)

1.0

8.2

O

O

200 (93)

200 193)

1.0

5.5

0.8

8.0

0.8

Methyl Isobutyl Carbinol CH3CHOHCH2CHCH3CH3 (1,3-DimethylbutonoI) (4-Methyl-2-Pentanol) [Methylamvl Alcohol1

106 (41)

Methyllrobutylcarbinol Acetate

See 4-Methyl-2-PentonolAcetate.

Methyl Isobutyl Ketone CH~COCH~CH(CH~)Z (Hexone) (4-Methyl-2-Penlanane)

64 (18)

840 (448)

Methyl IropropenylKetone CH2COC:CHz(CH3)

1.2

@ 200

0.8

3.9

266-271 (130- 133)

Slight

5

2

2

O

3.5

244 (118)

Slight

5 1

2

3

1

2.9

208

@

(93)

200 (93)

1.8

9.0

2

O

(98)

Methyl Isocyanate CH3NCO (Methyl Carbonimide)

19 (-7)

994 (534)

5.3

26

Methyl Iso Eugenol >212 CH~CH:CHC~H~(OCH~)Z( > 100) (PropenylGuaiacol) Methyl Ladate CH3CHOHCOOCH3

121 (49)

1.0-

1.1

725 (385)

2.2

102 (39)

Yes

5

4

3

2w

504-507 (262-264)

No

5

O

1

O

1

2

O

4

4

O

2

O

1.97

1.1

3.6

293 (145)

Yes Decomposes

0.9

1.7

42.4 16)

Yes

1.03

3.60

-329 (-165)

0.9

3.6

212 (100)

Very slight

0.9

3.5

239 (115)

Yes

472 (244)

O 212 (100)

Methyl Mercaptan CH3SH (Methanethial)

3.9

21.8

ß-Methyl Mercaptopropionaldehyde CH~SCZH~CHO (3-(Methylthio)PropionaldeWe)

142 (61)

Methyl Methacrylate CHz:C(CHj)COOCH3

50 1.7 8.2 (10) (oc) Note: Polymerizes. See Hazardous Chemicals Data.

Methyl Methanoate

See Methyl Formate.

4-Methylmorpholine CZH~OCZH~NCH~

75 (24)

1-Methylnaphthalene CioH7CH3

491

(255)

984 (529)

Methyl Nonyl Ketone CsH1 &OCHS

192 (89)

1

2

3

2

1

2

3

O

No

2

2

O

433 (223)

No

O

2

O

313 1154 @3mm

No

O

1

O

O

3

O

1.0+ 0.8

5

5.9

O

5

86 130ì

Methvl Oxide

See Melhvl Ether.

2-Methyl-l.3-Pentadiane CHZC[CH~)CH:CHCH~

< -4

0.72

2.83

169 (76)

( < -201

-

4-Methyl-1,3-Pentadiene CHz:CHCHz:C(CH3)z

Methylpentaldehyde CH~CHZCHZC(CH~)HCHO

- 30 ( - 34)

0.7

68 (20)

0.8

168 (76) 3.5

243 (117)

lot)

(Methyl Pentanal) Methyl Pentanal

See Methylpentaldehyde.

i994 Edition --```,,`-`-`,,`,,`,`,,`---


2

Not for Resale

No

1

O

3

1

Very slight

1

2

3

1

6474446 0528334 622

NFPA 325

325-7 1


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp.Gr. Densiiy POINT TEMP. percent by vol. (Water (Air "F ("C) "F ("C) Lower Upper =i) =1)

<20

2-Methylpentane (CH~)ZCH(CHZ)ZCH~ (Isohexone)

( < -7)

3-methyl pentme CH3CH2CH(CH3)CH2CH3

<20 ( < - 7)


Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bfliiy tiviîy

583 (306)

1.2

7.0

0.7

3.0

140 (60)

No

1

1

3

O

532 (278)

1.2

7.0

0.7

3.0

146 (63)

No

1

1

3

O

2

2

1

O

2-Methyl-1.3-Pentanediol CH3CH2CH(OH)CH(CH&H7OH

230 (110)

1.0-

2-Methyl-2,4-Pentanediol (CH3)7C(OH)CH2CHIOHlCH?

205 (96)

0.92

4.07

385 (196)

Yes

O

1

O

2-Methyl-1-Pentanol CH3(CH2)2CH(CH3)CH20H

129 (54)

9.65

0.8

3.5

298 (148)

No

O

2

O

4-Methyl-2-Pentanol

See Methyl Isobutyl Carbinol

4-Methyl-2-PentanoI Acetate CH~COOCH(CH~JCHZCHíCHdi (Methylisobutylcarbinol Acetate)

110 (43)

583

09

50

295 (146)

Very slight

1

2

O

4-Methyl-2-Pentanone

See Methyl Isobutyl Ketone.

419 (2151

(oc1

590 (310)

660 (349)

1.1

09

.

"

,

(OC)

@ 212 (100)

2-Methyl-1-Pentene <20 CH~:C(CH~)CHZCH~CH~( < -7)

572 (300)

0.7

2.9

143 162)

1

1

3

O

<20

572 (3001

0.7

2.9

129 (54)

1

1

3

O

2.9

153 (671 . .

1

1

3

O

133-137 (56-58)

1

1

3

O

4-Methyl-1-Pentene CH7:CHCHiCHíCH&

i<-71

2-Methyl-2-Pentene (CHIlKCHCHKH.

< 20 1<-71 , .

0.7

4-Methyl-2-Pentene CH3CH:CHCH(CH3)?

< 20 (<-7)

0.7

101 (381

0.9

- -

3-Methyl-1-Pentynoi (C~HS)(CH~)C(OH)C:CH

3.4

250 (1211

Yes

5

1

2

O

(oc) _

_

_

~

o-Meihyl Phenol

See o-Cresol 195 (91)

11

424 (218)

No

5

O

2

O

Methylphenyl carbinol CaH5CH(CH3)0H (a-Methylbenryl Alcohol) (Styrolyl Alcohol) (sec-PhenethylAlcohol)

200 (93)

1o+

399 (204)

Slight

5

O

2

O

Methyl Phenyl Carbinyl Acetate C&H&H(CH3)00CH3 (u-Methyl-BenzylAcetate) [Styrolyl Acetate) [sec-PhenylethylAcetate) (PhenylMethylcorbinyl Acetate)

195 (91i

1 o+

No

5

O

2

O

Methyl Phenyl Ether

See Anisole

Methyl Phihalyi Ethyl Glvcolate CH~COOC~H~COOCHZCOOC~H~

380 11931 . .

590 13101

No

2

2

1

O

280

Yes

5

2

2

O

No

1

2

3

O

--```,,`-`-`,,`,,`,`,,`---

Meihyl Phenylacetaie CbH5CH2COOCH3

-

(4

1-Methyl Piperazine 1O8 CH~NCH~CH~NHCH~CHZ (42)

3.5

(1381

See Isobutyroldehyde.

2-Methrl~roDane .. .

I

0.9

(4

2-methyl propanal

2-Methyl-2-Propanethiol iCH,i-CSH (tert-Buty Mercaptan)

1.2

See Isobutane. < - 20 i<-29)

0.8

3.1

149-153 (65-671


Not for Resale

NFPA 325 94 325-72

= b47444b

0528335 569


FLAMMBLE Vapor FiASH IGNITION LIMITS Sp. Gr. Densiíy POINT TEMP. Percent by vol. (Water (Air "F ("C) "F("C) Lower Upper =i) =i) 2-Methyl Propanol-1

See IsobutylAlcohol.

2-Methyl-2-Propanol

See tert-Butyl Alcohol.

2-Methylpropenal CH2:C(CH3)CHO (Methocrolein) (u-MethylAcrolein)

35 (2) (oc)

2-methyl propene CHz:C(CH3)CH? (y-Butylene) (Isobutylene)

Gas

869 I4651

1.8

9.6

Methyl Propionate CH~COOCHZCH~

28 (-2)

876 (469)

2.5

13

Methyl Propyl Acetylene C H ~ C Z Hj~CCH3 C (2-Hexyne)

0.8

2.4

0.9

3.0


154 (681

Yes

1 5

3

3

2

176

No

1

1

3

O

(80)

< 14

0.73

2.83

185 (85)

0.8

3.0

247 (1 19)

0.91

2.56

102 (39)

0.8

3.0

216 (102)

1.02

3.25

(<-lo)

Methyl Propyl Carbinol CHzCHOHC3H7 (?-Pentanol)

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flommo- ReocHealth biliíy tiviiy

105 (41)

3

No

O

2

O

O

3

O

2

3

O

2

2

O

See sec-Amylamine.

Methylpropylcarbinylamine

Methyl n-Propyl Ether CHjOC3H7

< -4 ( < -20)

Methyl Propyl Ketone CH3COC3H7 (?-Pentanone)

45 (7)

2-Methylpyrazlne N:C(CHz)CH:NCH:CH

122 (50)

2-Methyl Pyridine

See 2-Picoline.

Methylpyrrole N(CH3)CH:CHCH:CH

61 (16)

0.9

2.8

234 (112)

No

1

2

3

1

7 ( - 14)

0.8

2.9

180 (821

Slight

5 1

2

3

1

3.4

396

Yes

5

2

1

O

1-Methyl-2-Pyrrolidone CH~NCOCH~CHZCH~

u

(n-Methyl-2-Pyrrolidone)

Methyl Salicylate HOCbH4COOCH3 (Oil of Wintergreen) (Gaultheria Oil) (8etulo Oil) (Sweet-BirchOil)

8.2

Slight

1 5

(04

204 (96)

655 (3461

1.0+

205 (961

850 (4541

1.2

432 (222)

No

2

1

1

O

0.9

42 1 (216)

No

2

O

1

O

2

1

O

3

3

2w

2

1

1

O

5

1

3

O

(4

Methyl Stearate CiiH35COOCH3

307 (1531

a-Methylstyrene 1-Meihyleihenyl Benzine 1-Methyl-1-phenyiethene

129 (54)

Methylstyrene CHZCHC~H~CH~ [Vin+ Toluene)

See Vinyl Toluene

Methyl Sulfate

See Dimethyl Sulfate

2-Methyltetrahydrofuran CAH~OCH~

1.5

1066 (574)

(202)

1.9

6.1

0.9

329-331 (165-1 66)

No --```,,`-`-`,,`,,`,`,,`---

Methylpyrrolidlne CH3NCdH8

846 (452)

12 (-111

0.9

3.0

176

Slight

1 5

(80) ~

Methyl Toluene Sulfonate CH&H&OiCH? .. . .

306 (1521

315 i1571 68mm

(4

No

-

~~

2

Note: Melting point 75 (24). Methyltrichlorosilone CH3SiC13 (Methyl Silico Chloroform) (Trichloromethylsilone)

15 (-9)

Methyl Undecyl Ketone CiiHdOCH3 (2-Tridecanone)

225 (107)

>760 (>404)

7.6

>201.29

5.16

248 (120)

0.8

0.8

3.45


151 (66)

Not for Resale

240 (116)

No

1

NFPA 325 94

m

b47LtY4b 0528336 4 T 5

m 325-73

PROPERTIES OF FLAMMABLE LIQCIDS, GASES, VOLATILE SOLIDS

FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol. (water (Air "F ("C) "F ("C) Lower Upper =i) =i) 1-Methylvinyl Acetate

See Isopropenyl Acetate.

Methyl Vinvl Ether

See Vinvl Methvl Ether

Methyl Vinyl Ketone CHjCOCH:CH?

20 (-7)

915 (491)

2.1

15.6

Mineral Oil

2.4 0.8-0.9

Mineral Seal Oll Typical (Signal Oil)

275 (1 351

0.8

BOILING POINT "F YC)

Water Soluble

177 (811

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HhïARD METHODS IDENTIFICATION Flamrna- ReacHealth bility tivity

1

4

3

2

2

O

1

O

680 (360)

No

480-680 (249-360)

No

O

2

O

O

2

O

3

3

O

(04 Mineral Spirits Mineral Spirits, 360" End Point (182)

104 (40)

Mineral Wax

See Wax. Ozocerite

Manachlorobenzene

See Chlorobenzene.

Morpholine OC~H~NHCH~CHZ

98 137)

473 (245)

0.8

3.9

300 (149)

No

11.21.0

3.0

262 (1 28)

Yes

3.4

304 1151)

No

3

2

O

No

2

2

O

0.8 @

212

(100)

u

555

1.4

(290)

5

(4

Note: Decomposes at 489 (250). Note: See Hazardous Chemicals Data.

Muriatic Ether

See Ethyl Chloride

Mustard Oil C3HsN:C:S (Allyl Isothian/anate)

115 (46)

Naphtha 49" Be-Coal Tar Type

107 (42)

1.0+

531 (277)

Naphtha, Petroleum

See Petroleum Ether.

Naphtha, Safety Solvent

See Cleaning Solvent.

Naphtha V.M. 8 P., 50" Flash (10 )

50

(10)

450 (232)

0.9

6.7 cl

4.1

240-290 (116-143)

No

1

1

3

O

4.3

280-350 (138-177)

No

1

1

3

O

212-320 il 00-1601

No

1

1

3

O

424 (218)

No

2

2

O

1

O

Note: Flash point and ignition temperoture will vary depending on the manufacturer.

Naphtha V.M. 8 P., High Flash

85

450

1.0

6.0 < 1

(29) (232) Note: Flash point and ignition temperature will vary depending on the manufacturer.

Naphtha V.M. 8 P., Regular

28 450 0.9 6.0 < 1 (-21 1232) Note: Flash point and ignition temperoture will vary deDendina on the manufacturer.

Naphthalene CioHs (WhiteTar)

174

979

0.9

5.9 1.1

4.4

(79) (5261 Note: Melting point 176 (80). See Hozardous Chemicals Data.

ß-Naphthol CioH70H (ß-Hydroq Naphthalene) (P.Naphthal)

307 (1 53)

1-Naphthylamine CioH7NHz

315 (157)

Natural Gas

See Gas.

Neatsfaot Oil

470 (243)

1.22

4.98

545 (285)

Note: Melting point 253 (1 23).

1.2

572 (300)


828

0.9

No

2

2

1

O

No

2

O

1

O

Yes

2

1

1

O

4

3

3

(442!

Note: Melting point 84-106 (29-41). Neohexane

See 2.2-Dimethylbutane.

Neopentane

See 2.2-dimethyl propane.

265

Neopentyl Glycol HOCH2C(CH,),CH,OH (2,2-Dimethyl 1,3 Propanediol)

(129)

750 (399)

410 (210)

1.1

(04 Note: Melting point 255-266 (124-130).

Nickel Carbonyl Ni(C0)4

4

-4

2

1.32

5.89

( < -24)

1994 Edition

--```,,`-`-`,,`,,`,`,,`---


110 (43)

Not for Resale

NFPA 325 94 325-74

m

b47444b 0528337 331

m


FLAMMABLE Vanor FLASH IGNITION LIMITS Sp.Gr. De&iiy BOILING PemeWl>rVOl. (Water (Ah POINT POINT TEMP. OF(%) OF(0C) lower Upper =i) =i) OF(%) Nicotine CioHi4Nz

471 (244)

Niobe Oil

0.7

4.0

1.0

5.6

475 (246)

Water Soluble Yes

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth billiy ìivliy

2

4

1

O

3

1

2

3

2

1

5

See Methyl Benzoate.

Nitric Ether

See Ethvl Nitrote

2,2',2"-Nitriiotriethonol

See Triethanolamine.

1.1 ',1 "-Nitriiotri-2propanol

See Triisopropanolamine.

p-Nitroaniline NOzCaHaNHz

390 (1991 Note: Melting point 298 (148).

Nitrobenzene' C&NOz (Nitrobenzol) (Oil of Mirbane)

190 (88)

900 (482)

1.8

1.44

4.77

637 (336)

1.2

4.3

412 (21 1)

1.44

6.59

397 (203)

@?

No

3

200 (931 Note: See Hazardous Chemicals Data.

1.3-Nitrobenzotrifluoride C~H~NOZCF~ (0,a.a-Trifluoronitrotoluene)

2 17 (1031

Nitrobenzol

See Nitrobenzene.

1

1.2

626 (330)

No

2

2

1

O

457 (2361

No

2

3

1

1

Nitrocellulose

See Cellulose Nitroie.

Nitrochlorobenzene C~H~CINOZ

26 1 027) Note: Melting point 111 (44). Note: See Hazardous Chemicals Data.

1.5

p-Nitrochlorobenzene CdH4CIN02 (1-Chloro-4-Nitrobenzene)

261 [ i 27)

1.37

5.44

468 1242)

2

1

3

1.07

4.46


2

2

3

82 778 3.4 (28) (414) Note: See Hazardous Chemicals Daia.

1.1

2.6

Nitroglycerine C3HdN03)3 (GlycerylTrinitrote)

Explodes

1.6

Nitromethane CH3NOz

95 785 7.3 1.1 (351 (418) Note: May detonate under high temperature and pressure conditions. See Hazardous Chemicals Data.

1-Nitronaphthalene CioH7NOz

327 (164) Noie: Melting poini 140 (60).

1.3

1-Nitropropane CH~CHZCH~NOZ

96 789 2.2 (36) (421) Note: See Hozordous Chemicals Dota.

1.0

2-Nitropropane CH~CH(NO~)CHJ (sec- Nitropropanel

75 802 2.6 11.0 (24) (428) Note: See Hazordous Chemicals Daia.

1.0-

Nitrocyclohexane CH~(CHZ)~CHNO~

Note: Melting point 181 (83). 190 (88) IOCI

~~~~

~~

518 (270)

237 (114)

502 (261) Explodes 2.1

Slight

4 5

No

1

1

3 3 Explodes on heating.

2

2

4

1

3

4

1

O

214 (101)

Slight

579 (304)

No

2

1

3.1

268 (131)

Slight

5

1

3.1

248 (120)

Slight

5

1

5

3 2 May explode on heating. 3

2

May explode on

heating.

~

sec-Nitropropane

See 2-Ndropropane

Nitrotoluene

See p-Nitrotoluol

m-Nitrotoluena CaH4CH3NO2

223 (106) Noie: Melting point 61 (16).

1.16

4.73

o-Nitrotoluene C~H~CH~NOZ

223 (106) Nde: Melting point 25 (-4).

1.16

4.73

p-Nitrotoluene NOZC~H~CHJ


3

1

1

432

3

1

1

3

1

1

(222) 1.3 461 (238) Note: See Hozordous Chemicois Daia.


450 (232)

Not for Resale

No

2

--```,,`-`-`,,`,,`,`,,`---

(4

NFPA 325 94

= 6474446 0528338 278 325-75


FI.AMM&BLE Vapor FLASH IGNITION LIMITS Sp. Gr. Denshy POINT TEMP. Pertent by Vol. (Water (Air "F("C) "F ("Cl Lower Upper =11 =1) .. 2-Nitro-p-toluidine CH~C~H~("Z)NOZ

315 (157) Note: Melting point 259 (1 26).

Nitrous Ether

1.31

5.25

0.79

9.27

628 (331)

0.7

4.4

303 (151)

0.71

4.43

290 (143)

0.72

4.43

291 (1 44)

0.72

4.43

288 (142)

0.7

4.35

270-290 (132-143)

0.9

6.4

378 (192)

Water Soluble

2

1

4

O

1

O

O

3

O

O

3

O

O

3

O

See Ethyl Nitrite.

>212 446 (>loo) (230). Note: Melting point 90 (32).

Nonane C9HZO

88 (31)

Nonane (iso) C6Hi 3CWCH3)z (2-Methyloctane)

401 (205)

0.8

2.9

428 (220)

Nonane (Iso) C4H4WCWC3H7 (4-Methylodone)

437 (225)

Nonene c9H18 (Nonylene)

78 (26)

N o d Acetate CHZCOOCPHI~

155 (68)

Nonyl Alcohol

See Diisobuíyl Carbinol.

No

1

No

1

O

3

O

Very slight

5

1

2

O

O

(4

210 (99)

0.9

0.9

8.8

468-486 (242-252)

No

O

1

626-653 (330-345)

N~

O

2

O ~~

1.0-

-6

23-Norbornadiene

559-567 1293-2971

0.9

3.17

193 (89)

(-21)

c7b

Vely sliaht

2

No

1

2

1

O

3

1

5

(NED) Oöodecane C18H38

>212 441 (>loo) (227) Note: Melting point 82 (28).

0.78

8.73

603 (317)

O

1

O

Octadecylene ct CH3(CHz)i5CH:CHz (1 -0ctadecene)

>212 482 (>loo) (250) Note: Melting point 64 (18).

0.79

8.71

599 (315)

O

1

O

3

2

2

Octadecyltrichlorosilane Ci~H37SiC13

(Trichloroodadecylsilane]

1 .o

193 (89)

Octadecyi Vlnyl Ether

See Vinyl Octadecy Ether.

Octanal

See Caprylaldehyde.

Octane Ch(CHz)aCH3

56 (13)

1-0cîaneîhiol CeHi7SH (n-Octyl Mercaptan]

156 (69) (oc)

403 1206)

1-Octano1

See Odv Alcohol.

2-Ocîanol CH~CHOH(CHP)~CH~

190 (88)

1-Octene CHz:C7H,4

70 (21)

446 (230)

1.0

6.5

716 1380)

Yes

0.7

3.9

258 (126)

No

1

O

3

O

0.85

5.04

390 (199)

No

5

2

2

O

0.8

4.5

363 (1 84)

No

1

2

O

0.7

3.9

250 (121)

No

1

1

3

O

0.7

3.9

257

No

1

1

3

O

(oc1

2-Octene (Mixed cis and trans isomers) CH3CH:CHC5Hii

70 (21)

ochl Acetate

See 2-Ethvlhexvl Acetate.

0 25)

(oc)


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Nonadecane CHdCHzìi 7CH3

BOILING POINT "F ("Cl . .

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFIC&TION Flamma- ReacHeakh bilih tivih

NFPA 325 94 325-76

m 6474446 0528339 L O 4 m


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by Vol. (Water (Air "FpC) "FCC) Lower Upper =i) =i)

BOILING POINT -F("C)

Waîer Soluble

Odyi Aicohol CH~(CHZJ~CHZOH (1-0danol)

178 (81)

0.8

4.5

381 (1941

Na

Odylamlne CH~(CHZI~CHZ"Z (1-Aminaoctane)

140 (60)

0.8

4.5

338 (170)

Slight

1.41

4.46

284 (1401

0.9

5.1

359 (182)

No

475 (246)

No

318-329 (159-165)

No

158 (70) Odylene Glycol iCHdCHzì2CHOHIz

230 (110)

635 (335)

0.9 0.8

p-Odylphenyl Salicylate cZ1HZ603

5.0

420 780 (216) (416) ( 4 Note: Melting point 162-1 65 (72-74).

Oil of Mirbane

See Nitrobenzene.

Oil of Winïermreen

See Methyl Solicylote.

Oleic Acid 372 C~H~~CH:CH(CHZ)~COOH(1891 (Red Oil) Dirtilled 364 11841 Oleo Oil

685 (363)

450

Oxallc Ether

See Ethyl Oxolote

Oxammonlum

See Hvdroxvlamine

Oxirane

See Ethylene Oxide.

Palm Butter

See Polm Oil

Palm Kernel Oll (Palm Nut Oil)

398 (203) Note: Melting poini 78-86 (26-30).

Palm Nut Oil

See Polm Kernel Oil.

Palm Oil (Polm Butter)

323 600 (162) 1316; Note: Melting point 80-1 10 (27-43).

Paraffin Oll (See olso Lubricating Oil)

444 (229)

Paraformaldehyde HO(CHzO1.H

158 572 7.0 73 WO! (70) Note: Melting point 248-356 (120-180) See Hazardous Chemicals Dato.

650 13431

2

O

2

2

O

3

O

1

2

O

1

1

O

2

2

O

2

1

1

O

5

2

547 (286)

No

2

O

1

O

0.9

464 (240)

No

2

O

1

O

0.9

No

2

O

1

O

0.9

No

2

O

1

O

0.9

No

2

O

1

O

2

O

1

O

5

3

1

O

1

2

3

1

1

O

,

437 12251

1

0.9

12321 . . Olive Oll ISweet Oil1

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD IDENTIFICATION METHODS Flamma- ReacHealth biiity tivity

<

Slight

96 460 1.3 (36) (238) (Oc) Note: Melting point 54 (12). See Hozardous Chemicals Data

1.0-

540

0.9

4.5

255 11241

Slight

5

~

Peanut Oil Cooking (KotchungOil)

~

(282)

833 (445)

Pentaborane W

0.42

0.6

NO

2.2

9

140 (60)

2

1

Note: Ignites spontaneously in air. See Hazardous Chemicols Dato. Pent-Acetale Mixture of IsomericAmyl Acetates ond Amyl Alcohols

98 (37)

260 (1271

0.9

--```,,`-`-`,,`,,`,`,,`---


Not for Resale

No

1

O

4 4 Reacts violently with halogenated edinguishing agents. 2

3

2

O

NFPA 325 94

m 6474446 0528340

92b 325-77


FIAMMAELE Vapor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol. (Water (Air “F CC) “F (“Cl Lower Upper =i) =i)

- 20 I - 29)

1.1-Pentadiene (cis and trans mix) CHz:CHCH:CHCH3 (Piperylene) 1.2,3,4,5-Pentamethyl Benzene 9S% CsH(CH3)5 fPentomethvlbenzenel

200 193)

0.7

0.9

800est 1427)

See 1,5-DichIoropentane

Pentamethylene Glvcol

See 1.5-Pentanediol -4 ( - 20)

U

2.35

-45

Water Soluble No

1

O

4

2

2

O

I - 43)

Pentamethylene Dichloride

Pentamethylene Oxide OíCHhCHz


SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility tiviîy

449 (232)

No

0.9

3.0

178 (811

Yes

1 5

2

3

1

0.6

2.5

97 136)

No

1

1

4

O

468 (242)

Yes

2 5

1

1

O

5

2

2

O

2

1

O

(Tetrahydropyran) Pentanal Pentane CH3ICbì3CH3

See Valeraldehvde

< -40 ( < -40)

500 (260)

1.5

7.8

1,5-Pcntancdiol HO(CH2)sOH (PentamethyleneGlycol)

265 (129) (oc)

635 (335)

1.0-

2A-Pentanedione CH~COCHZCOCH~ (Acetyl Acetone)

93 134)

644 (340)

1.0-

3.5

284 (140)

Yes

Pentanoic Acid C&isCOOH (voleric Acid)

205 196) (oc)

752 (400)

0.9

3.5

366 (186)

Very slight

08

30

241 1116)

Slight

5

1

2

O

482 1250)

No

2

2

1

O

1

1

4

O

1-Pentanol

See Amyl Alcohol.

2-Pentanol

See Methyl Propyl Carbinol

3-Pentanol CH3CH2CH(OH)CH2CH3 (tert-n-Amyl Alcohol)

105 (41)

815 (435)

12

1-Pentanol Acetate

See Amvl Acetate.

2-Pentanol Acetate

See sec-AmylAcetate

2-Pentanone

See Methyl Propyl Ketone.

3-Pentanone

See Diethyl Ketone.

Pentaphen c5HiiC6HdoH (p-terf-Amyl Phenol)

232 1111)

90

0.9


PentapropionylGlucooe

See Glucose Pentoprapionote.

1-Peniene CH~(CHZ)~CH:CHZ (Amylene)

O

(-18) (04

527 (275)

1-Pentene-&

See ß-Amylene-cis

2-Pentene-trans

See ß-Amylene-trans.

Pentylamine

See Amylamine

Penhloxvoentane

See Amvl Ether.

Pentyl Propionote

See Amyl Propionate

1-Penîyne HC CC3Hr (n-PropylAcetylene)

< -4

1.5

8.7

0.7

2.4

86 (30)

(c-20)

Peracetic Acid Diluted with 6096 acetic acid CH3COOOH

105 1411 Note: Decomposes violently at 230 (110). See Hazordous Chemicals Dota.

Perchloroethylene, Tetrachloroethylene CI2C=CC12

None

Perhydrophenanthrene

None

475 1246)

c14”24

None

1.6

0.9

5.8

221 (105)

Yes

3

250 1121)

No

2

2 40x Explodes on heating. O

187-192 (86-89)

O

O

(Tetrodecahydro Phenanthrene) Perilla Oil

522 (272)

0.9

No

2

O

1

O

--```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94 325-78

b 4 7 4 4 4 b 0528343 8 6 2

PROPERTIES OF FIAMMAELE LIQUIDS, GASES, VOLATILE SOLIDS

FLASH POINT 'FrC)

FLAMMABLE Vapor IGNITION LIMITS Sp.Gr. Density (Air TEMP. Percent i>r Vol. (Water Lomr Upper =i) =i) 'F("C)


Water Soluble

SEE INTRODUCTION FOR SUGGESTED HAZARD EXTINGUISHING METHODS IDENTIFICATION Flamma- ReacHealth bility tivity

Petroleum, Crude, Sour

20-90 1-7 to 32)

<1

No

1

2

3

O

Petroleum, Crude, Sweet

20-90 (-7 to 32)

<1

No

1

1

3

O

No

1

1

4

O

No

2

O

1

O

O

2

O

1

O

Petroleum Ether (Benzine) (Naphtho. Petroleum]

550 (288)

Petraleum Pitch

See Asphalt (Typical).

Petroleum Sulfonate

400 (204) (oc)

ß-Phellandrene CH2:CCH:CHCH[CH(CH,),l-

1.1

5.9

120 (49)

0.6

2.5

95-140

(35-60)

-0.9

4.68

340 (171)

L

No

CH2CH2

2 (p-Meniho-l(7), ?-Diene) Phenanthrene (C6hCH)z. (Phenonthrin)

340 11711 (oc1 Note: Melting 212 (100). _ point .

1.1

Phenethyl Alcohol CAHSCH~CH~OH (Benzyl Carbinol) (PhenylethylAlcohol)

205

l.O+

430 1221)

No

2

1

1

O

1961 . ,

o-Phenetidine H2NCsH40CzHs (2-Ethoxyoniline) (o-Amino-Phenetole)

239 (1 151

442-446 (228-230)

No

5

2

1

O

p-Phenetidine CZH~OC~H~NH? (1-Amino-4-Ethoxybenzene) lo-Aminonhenetoleì

24 1 (1 161

378-484 (192-251)

Ver/ slight

2

2

1

O

Phenetole

See Ethoxybenzene.

Phenol C6H@H (Carbolic Acid)

175 1319 1.8 8.6 (791 (7151 Note: See Hozordous Chemicals Doto. Melting point 108 (42).

Yes

5

4

2

O

2-Phenoxyethanol

See Ethylene Glycol, Phenyl Ether.

Phenoxy Ethyl Alcohol C~H~O(CHZ)~~H (2-Phenoxyethonol) (Phenyl Cellosolve)

250 (1211 (oc1 Note: Melting point 58 (14).

O

1

O

. _ -

- -

2

(oc1

1.1

1.1

3.2

358 (1811

1.11

4.77

468 (2421

1.1

ß-PhenoxyethylChloride

See ß-Chlorophenetole.

Phenylacetaldehyde' C6H5CH2CHO (a-Toluic Aldehyde)

160 (71)

1.0+

Phenyl Acetate CHKOOC6Hs

176 (80)

1.1

Phenylacetic Acld C6H5CH2COOH (a-Toluic Acid] Phenylamine

2212 (>loo) Note: Melting point 169-1 71 (76-77).

-

4.7

1.1

383 (195)

No

5

1

2

O

384 1196)

Slight

5

I

2

O

504 12621

Yes

5

1

1

O

2

O

See Aniline.

~~

N-Phenylaniline

See Diphenylamine.

Phenylbensene

See Biphenyl.

Phenyl Bromide

See Bromobenzene.

1-Phenyl-2-Butene CaH5CH2CH:CHCH3

160 (71I locl


0.9

4.6

346 (1741

--```,,`-`-`,,`,,`,`,,`---

Not for Resale

325-79

PROPERTIES OF FLAMMABLE I.IQ.UIDS, GASES, VOLATILE SOLIDS

FIASH IGNITION POINT TEMP. 'F("C)

Phenyl Carbinol

'F("C)

FLAMMABLE Vanor LIMITS Sp. Gr. ben& Percent by Vol. (water (Air Lower Upper =1) =i)


Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHeakh biliiy tiviiy

See 8enrvl Alcohol.

Phenyl Chloride

See Chlorobenzene

Phenvlcrclohexane

See Cvclohewlbenzene

Phenyl Didecyl Phosphite (C6~50)PíOCioHzi)z

425 (218)

N-Phenyldieihanolamine C6HsN(CzH40Hlz

385 (196)

0.9

2

O

1

O

(oc)

730 (387)

0.7

376 (191)

No

2

1

1

O

545-626 (285-330)

No

2

O

1

1

1

O

1.1

(04 Noie: Melting point 136 (58). Phenyldiethylamine

See N,N-Diethyloniline.

Phenyl Diglycol Carbonate

See DiethyleneGlycol Bis (Phenylcarbonate).

1.2

o-Phenylenediamine NHzC~H~NH~ (1 ,2-Diaminobenzene)

313 (1 56)

Phenylethane

See Ethylbenzene.

N-Phenylethanolamine CdHsNHC+t
052)

1.5

3.73

513 1267)


305

1.1

545 (285)

Slight

2 5

1

1

O

514 (268) 740

Slight

2 5

2

1

O

Slight

5

3

2

O

2

1

O

5 2

2

1

O

5

1

1

O

O

1

O

1

O

1

O

2

O

(4 Note: See Horardous Chemicols Doia.

Phenylethyl Alcohol

See Pheneihyl Alcohol.

Phenylethylene

See Styrene

N-Phenyl-N-Ethylethanolamine C~H~N(CZH~)CZH~OH

270 (132) (oc)

485

0.8

1.0+

(362)

@I

mm

Phenylhydrazine C~H~NHNHZ

(881

Phenylmethane

See Toluol.

Phenylmethyl Ethanol Amine C~H.SN(CH~)CZH~OH (Z-(N-Methylaniline)Ethonol)

280 (1 38) (oc)

190

Decomposes

1.1

107

522

378 (1921 @ 100 mm

Phenyl Methyl Ketone

See Acetophenone

4-Phenylmorpholine C~H~NC?H~OCHZCHZ

220 (104)

Phenylpentane

See Amylbenzene.

o-Phenyiphenol C6HsC6H40H

(124)

PhenytDroDane

see Prodbenzene

2-Phenylpropane

See Cumene

Phenylpropyl Alcohol C6HdCHz130H (HydrocinnamicAlcohol) (3-Phenyl-I-proponol) (Phenylethyl Carbinol)

212 (1001

1.ot

Phenyl Propyl Aldehyde C&CH2CH2CHO (3-Phenylpropionaldehyde) (HydrocinnamicAldehyde)

205

1.0+

1.1

518 (270)

Slight

1.2

547 (2861

Slight

426 (219)

No

(oc)

Phenyl Toluene o C6HsC6H4Ch (2-Methylbiphenyl)

255

984 (530).

2


5

5

(96)

2212 (>loo)

Phenyl Trichloro Silane C&,SiC13 (Trichloro(pheny1)silone)

196 (91)

923 (495)

1.01

5.82

1.32

7.36

500 (2601 394

(4

--```,,`-`-`,,`,,`,`,,`---


3

(2011

Not for Resale

1994 Edition

NFPA 325 94 325-80

= 6474446 0528343 635


FLAMMABLE Vapor F W H IGNITION LIMITS Sp. Gr. Densiíy POINT TEMP. Percent by vol. (Water (Air =i) =1) OF(%) 'FCC) Lower Upper Phorone (CH~)ZCCHCOCHC(CH~]Z


0.9

4.8

388 11 98)

0.57 1.17 @ 20 atm

Phosphine m3

Phthalic Acid C6H4lCOOH)z


Phthalic Anhydride c6H41c0 zO

305 1058 1.7 WO! (152) Note: Meltino ooint 262 11281.

m-Phthalyl Dichloride

See Isophthaloyl Chloride

2-Picoline CH3CsHdN (2-Meth ylpyridine)

102 139)

1.59

10.5

1000 (538)

Water Soluble No

-126

I- 881

1.5

2

O

4

4

2

O 1 1 Forms anhydride (Dustexplosion hazard.)

552 1289)

5.73

2

543 (284)

No

1.0-

3.2

262 (128)

No

1.0-

3.2

292 (144)

Yes

2

3

1

O

2

2

O

2

2

O

(oc)

4-Picoline CH~CSH~N Pimelic Ketone

BOILING POINT OF(%)

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING H-RD METHODS IDENTIFICATION Flamma- ReacHeolth biliíy thrity

5

See Cyclohexanone ~

Pinane CioHia

523 (273)

0.7

7.2

@

@

320 (160)

320 (160)

u-Pinene CIOH16 Pine O i l Steam Distilled

0.8

0.9 172 (78) 138

O

336 (151)

4.7

312 1156)

No

0.9

367-439 (186-226)

No

11

490 12541

No

208 (98)

1

O

1

3

O

O

2

O

O

1

O

No

O

2

O

No

O

2

O

(591

Pine Pitch

Pine Tar

I

-

285 11411 Note': Melting point 148 (64) 130 (54)

671

(355)

2

Pine Tar O i l (wood Tar Oil)

144 (621

0.9

Piperozine HNCH2CHzNHCHzCHz

178 181) (oc)

1.1

3.0

294 (146)

Slight

5

2

2

O

Piperidine (CHzìN (Hexahydropyridine)

61 116)

0.9

3.0

223 (106)

Yes

1 5

3

3

O

667-747 (353-397)

No

2

O

1

O

Yes

5 2

O

1

O

O

1

O

5 2

O

1

O

Yes

5

O

2

O

No

2

O

1

O

2

1

O

Pogy Oil

See Menhoden Oil.

Poiyamyl Naphthalene Mixture of Polymers

360 (1 82)

0.9

(4 Polyethylene Glycols 360-550 O H ( C Z H ~ O ) ~ C Z H ~ O H(182-287) 0.95

Polypropylene Glycols OH(C3HaO).C3H60H Polyvinyl Alcohol Mixture of Polymers

365 1185) (oc1

l.O+

Decompores

175 179) (oc)

Poppy Seed Oil

49 1 (2551

Potassium Xanthate KSzC-OCzH5

205

0.9 9.6

1.56

5.53

(96)


Not for Resale

392 12001 Decomposes

Yes

--```,,`-`-`,,`,,`,`,,`---

(oc1

NFPA 325 94

b 4 7 4 4 4 b 0528344 571 325-81

PROPERTIES OF FLAMMABLE LIQUIDS, GASES, VOLAl'lLE SOLIDS

FLASH IGNITION POINT TEMP. "F ("C) "F ["C)

I

-22 405 2.6 17 (-30) (207) Note: See Hazardous Chemicals Dalo.

Propanal CH3CHzCHO (Propionoldehyde) Propane CH3CHzCH3

Gor

1.3-Propanediamine NHzCH~CH~CHZNHZ (1.3-Diominopropane) (Trimethvlenediominel

75 (24)

1.2-Propanedlol

See Propylene Glycol.

13-Prorranedioi

See Trimethylene Glycol.

--```,,`-`-`,,`,,`,`,,`---

I I

I

FLAMMABLE Vapor LIMITS Sp. Gr. Densiíy Percent by vol. (water (Air Lower Upper =1) =i)

842 (450)

2.1

0.8

BOILING POINT "F ["C)

Slight

1 5

2

3

2

-44 ( - 42)

No

6

1

4

O

2.6

276 (136)

Yes

1 5

2

3

O

2.0

120 (491

1.6 0.9

9.5

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAïARD METHODS IDENTIFICATION Flamma- ReacHealth blliíy tlvity

(4

1-Propano¡

See Propyl Alcohol.

2-Pro~anol

See IsoorowI Alcohol.

Z-Propanone

See Acetone.

Propanoyl Chloride

See Propionyl Chloride.

Ropargyl Alcohol HCiCCHqOH (2-Propyn-1-01)

97 136) , ,

0.97

1.93

239 (115)

4

3

3

Propargyl Bromlde HCiCCH28r (3-Bromopropyne)

50 615 3.0 (10) (324) Note: See Hazardous Chemicals Doto.

1.57

4.10

192 (89)

3

3

4

Propene

See Propylene.

2-Propenylamine

See Allylamine. 0.8

1.3

158 (70)

1

2

3

O

1.1

2.5

311 (1551

Yes

5

O

2

O

5

3

2

O

Propenyl Ethyl Ether CH3CH:CHOCHzCH3

(4

< 20 ( < -7)

(4 165 174)

p-Propioloctone C2Hd02

II

2.9

Propionaldehyde

See Propanal.

Propionlc Acid CH3CHzCOOH

870 2.9 12.1 (465) Note: See Hazardous Chemicals Doto.

1.0-

2.5

297 (147)

Yes

Propionic Anhydride (CH~CHZCO)~~

145 (631

1.0+

4.5

336 (169)

Decomposes

Propionic Nitrile CHjCHzCN (Propionitrile)

36

0.78

1.90

207 (97)

Yes

Propionyl Chloride CH3CHzCOCI (PropanoylChloride)

54 (12)

1.1

3.2

176 (80)

Decomposes

1

Propyl Acetale C3H700CCHj (Acetic Acid, n-Propyl Ester)

55 (13)

8

0.9

3.5

215 (102)

Slight

1 5

1

3

O

Propyl Alcohol CHjCHiCHzOH (1-Proponal)

74 (23)

13.7

0.8

2.1

207

Yes

1

1

3

O

126

(52)

9.5

3.1

842 (450)

1.7

@

3 2 Decomposes in water. 4

3

1 1

3 3 Decomposes in water.

1

1O0 (38) 775 (412)

2.2

86 (30) >212 ( > 100)

n-Propyl Bromide C3H7Br (1-Bromoprapone)

842 (450)

0.8

6.0

99 (37)

Propyl Carbinol

0.7

120

2.0

Yes

1 5

3

3

O

No

1

2

3

O

(49) 0.9

833 (445) 914 (490)

n-Propyl Buîyraîe C3H7COOC3H7

5

(97)

-35 604 2.0 10.4 (-37) (318) Note: See Hozardous Chemicals Dato.

Propylbenzene C3H7C6H5 (Phenylpropane)

Propyl Chloride CIHICI (1-Chloropropane)

1.3

(2)

Propylamine CH~ICHZ)~"~

2-Propybiphenyi C6H5c6H.iC~b

545

(285)

4.1

319 (159)

-

6.77

536 ( - 280)

O

1

O

1.35

4.34

160 (71)

2

3

O

0.87

4.49

290 (143)

O

3

O

0.9

2.7

115 (46)

2

3

O

See Butyl Alcohol.

968 I5201

2.6

11.1

Very slight

1


Not for Resale

NFPA 325 94 325-82


FLASH POINT

71°C)

Propyl Chlorothiolfonnate C~HISCOCI . .

m 6474446 0528345 408 m

FLAMMABLE Vamar LIMITS Sp.Gr. D e & y IGNITION TEMP. Percent by Vol. (Water (Air " F N Lower Upper =i) = 1 )

145 (63) . .

1.1

BOILING POINT "F 1°C)

4.8

31 1

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth biliîy tiviîy

No

2

O

2

f,1551.

Propylcyclohexane H&CaHii

478 (248)

0.8

313-315 (156-1 57)

O

O

Propylcyclopentane C~H~C~HP (1-Cyclopentylpropone)

516 (269)

0.8

269 (1311

O

O

Propylene CH2:CHCHa (Propene)

Gas 851 2.0 11.1 (455) Note: See Hazardous Chemicals Dota.

Propylene Aldehyde

See Crotonaldehyde.

Propylene Carbonate OCHZCH~CH~OCO

275 (135)

1.5

6

1

4

1

2

1

1

O

2

3

O

4

2

3

O

5

O

1

O

O

3

O

5

O

2

O

Yes

5

3

1

2

Yes

1 5

3

4

2

3

O

3

O

-53 (-47)

No

468 (242)

Yes

246 (1 19)

Yes

205

No

370 (188)

Yes

283 1140)

Yes

3.11

248 (120)

Yes

0.966

4.6

295 (146)

Slight

1.05

4.5

410 (210)

O83

20

94

1.2

5

(04 Propylene Chlorohydrin

See 2-Chloro-1-Propanol.

sec-Propylene Chlorohydrin

See 1-Chlore-2-Propanol.

Propylenediamine CH&H(NH?)CHzNHz

92 (33)

780 (4161

0.9

2.6

1

5

(4 Propylene Dichloride CH3CHCICH2CI (1,2-Dichloropropone)

1035 (557)

3.4

Propylene Glycol CH3CHOHCH20H (Methyl Ethylene Glycol) (1,2-Proponediol)

210 (99)

700 (371)

2.6

--```,,`-`-`,,`,,`,`,,`---

60 116)

14.5

1.2

3.9

(96) 12.5

Propylene Glycol Acetate

See Methyl Glycol Acetate.

Propylene Glycol Isopropyl Ether

110 (43)

Propylene Glycol Methyl Ether CH~OCH~CHOHCHJ (1-Methoxy-2-proponol)

90 (32)

1.6

Propylene Glycol Methyl Ether Acetate (99% Pure)

1O8 (42)

1.5 7.0 @200"C

Propylene Glycol Monoacrylate CHz:CHCOO(C3Ha)OH (HydroxypropylAcrylote)

207 (97)

1.0+

2.62

0.86

13.80.92

1.4 @loPC

~

Propylene Oxide OCH2CHCH3 n-Propyl Ether (c3H7)Zo (Dipropyl Ether)

I

-35 840 23 36 (-37) (449) Note See Hozordous Chemicals Dato 70 121)

370 (188)

27

851 (455)

Propyl Formate HCOOC3H7

(-3)

Propyl Methanol

See Butyl Alcohol.

Propyl Nitrate CHJCH~CH~NO~

66 (20)

347 (175)

13

2

70

100

(35) O75

353

194 (90)

0.9

3.0

178 (81)

Slight

231 (111)

Slight

1.1

0.9

4.0

245 (1181

No

Propyltrichlararilane (C3H7)SiCIs

98 (37) Note: See Hazardous Chemicals Dda.

1.2

6.12

254 (123.5)

Yes

Propyne CH3C CH (Allylene) (Methylacetylene)

Gas

1.4

-10 1-23)

PNSSiC Acid

See HvdrocvanicAcid.

Pseudocumene

See 1,2,4-Trimethylbenzene

1.7


Not for Resale

1

5

R a p y i Propionate 175 C H J C H ~ C O O C H ~ C H ~ C H ~ (79)

(4

1

2

5

2 3 May explode on heating.

30x

1

3

O

1

3

3

1

6

2

4

2

NFPA 325 94

m 6474446 0528346

m

344

325-83

PROPERTIES OF FLAMMABLE LIQUIDS. GASES, VOLATILE SOLIDS

FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol. (water (Air =i) =i) 'FpJ OF(%) Lower Upper

.

I

68 1201

< -

900 1482)

1.8

12.4

1.0-

2.7

BOILING POINT "F("C) 239 1,1 151 .

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bilily tMty

Yes

1 5

3

3

O

Na

1

1

3

O

2

2

O

2

3

1

2

1

O

O

1

O

2

1

O

O

1

O

1

O


Pyroxylin Solution

80 (27) May be below.

Pyrrole (CHCH)?" (Azole)

102 (39)

1.0-

2.3

268 (131)

No

Pyrrolidine NHCHZCH~CH~CH~

37 (3)

0.9

2.5

186-189 (86-87)

Yes

265 (129)

1.1

473 (245)

Yes

u

5 1

(Tetrohydropyrrole) 2-Pyrrolidone NHCOCHzCHiCHz

2.9

(04

2

5

Quenching Oil

365 (185) 096 (480)

Quinoline C6H4N:CHCH:CH

u

Range Oil

See Fuel Oil No. 1.

Rape Seed Oil (Colza Oil)

325 (163)

Red Oll

See Oleic Acid.

Resorcinol CaH4(0H)z (Dihydroxybenzol)

261 (127)

836 (447)

1.4@ 392 12001 Note: Melting point 232 ( 1 11).

Rhodinol CHZ:C(CH~)(CH~)~CH(CH31ICHz)zOH

1126 (608)

>212 ( > 100)

Ricinus Oil

See Costor Oil.

Rosin Oil

266 11301

648 (3421

Rum

See Ethyl Alcohol and Woter

Salicylaldehyde HOC6H4CHO (o-Hydroxybenzaldehyde)

172 1781

Salicylic Acid HOC6H4COOH

315 (157)

Safrole C~HSC~H~OZCHZ (4-allyl-1,Z-Methylenedioxy-benzene)

212 (100)

1.1

No 4.5

460 (238)

0.9

1.28

No

No

3.80

2

2

531 (277)

0.9

237-239 (1 14-1 151 @ 12 rnrn

No

1.0-

>680 í > 3601

No

2

O

1

O

1.2

384 (196)

Slight

5

O

2

O

No

2

O

1

O

1

O

1

O

1.1 @ 1.5 392 (2001 Note: Melting point 316-322 1158-1611

Santalol ClSH240 (Arheol)

I

0.9

1004 (540)

4.8

Sublimer @ 169 (76)

1.1

>212 (>loo)

1.0-

Sesame Oil

491 12551

Signal Oil

See Mineral Seo1 Oil, Typical.

Silane

Gas

-572 ( - 300)

0.9

Pyrophoric

No

No

1.3

- 169

Slight

Sin4

2

O

1

O

Avoid halon

1

4

3

(Silicon Hydride) Soy Bean Oil

540 (282)

833 (445)

0.9

No

2

O

1

O

428

586 (308)

0.9

No

2

O

1

O

No

2

1

1

O

S p e m Oil No. 1

No. 2

(220) 460 (2381

See Lubricating Oil, Spindle.

Spindle Oil Siearic Acid C H ~ ( C Hi ~ )

6

~

385 743 1196) ~ ~ (395).~ Note: Melting point 157 (69).

0.8

726 (386)


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Note: Melting paint 77 (25)

NFPA 325 94 325-84

= b47444b 0528347

280 D


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol. (Water (Air =i) =i) “F (“C) “F(“C) Lower Upper Steayl Alcohol CHdcHdi7oH (1-Odadecanal)

0.8

842 (450)

BOILING POINT “F (“Cl

410 (2101 @15mm

Water Soluble


No

O

O

Note: Melting point 131 (55). Straw Oil

315-361 (1 57-1831

Siyrene CaH5CH:CHz (Cinnamene) (Phenylethylene) Winvl Benzene1

88 (311

914 (4901

0.9

6.8

0.9

3.6

295 (146)

No

2

O

1

O

No

1

2

3

2

2

2

O

1

O

2

1

O

2

1

O

Note: Polymerizes. See Hazardous Chemicals Dota ~

Siyrene Oxide C~H~CHOCHZ

~~

1.1

Succlnonitrile NCCHzCHzCN (Ethylene Dicyanide)


1.0-

SuHolane CHz(CHzl3SOz

350 (1771

1.3

(Tetrohydrothtophene-1,l-

2.1

509-513 (265-267)

Yes

2 5

545 (2851

Yes

2

(oc]

Dioxide) (TetramethyleneSulfone) Note: Melting point 81 (27).

I

(207)

450 (2321

a32 (4451

1.8

No

Sulfur Chloride

245 453 (118) (234) Note: See Hazardous Chemicals Data.

Sweet Oil

See Olive Oil

Sylvan

See 2-Methylfuran.

Tallow

509 (265) Note: Melting point 88-100 (31-381.

0.9

No

2

O

1

O

Tallow Oil

492 (2561 Note: MeltinQpoint 109 (43).

0.9

No

2

O

1

O

Tannic Acid (HO)&HzCOzCaHz(OH)zCOOH (Tannin) IDiaallic Acid1

390 (199)

Yes

2

O

1

O

Tartarlc Acid (d, I) (CHOHCO2H)z

410 (210)

O

1

O

1.7

280 (138)

Decomoases

980 (527)

Decomposes

3 1 Decomposes in water.

1

(4 ~

797 (425)

1.76

518

(ml

Note: Melting point 338 (1 70). Terephïhallc Acid C6H.dCOOHIz (para-Phthalick i d ) (TW (Benzene-poro-Dicarboxylic Acid) Terephthaloyl Chloride C6H4(COCIh (TerephthalylDichloride) (p-Phthalyl Dichloride) Il .4-8enzenedicorbonvl Chloride)

500

(260)

(4

925 (496)

1.5

356 (180)

Sublimes above 572 (3001

No

2

O

1

O

498 (2591

Yes

2

3

1

O

Note: Melting point 175 (79). o-Terphenyl (C6H5hC6H4

325 (163) (oc)

1.1

630 (3321

No

2

O

1

O

m-Terphenyl (CaH5hCaH.4

375 (1911

1.2

685 (3631

No

2

O

1

O

417-435 (214-224)

No

O

2

O

O

2

O

(4

Note: Melting point 188 (87). Terpineol CioHi 70H (Terpilenol)

195 1911

0.9

Terpinyl Acetate CioHi 7OOCCHj

200 193)

1 .o-

428 (2201


Not for Resale

Slight

5 2

--```,,`-`-`,,`,,`,`,,`---

405

NFPA 325 94

b 4 7 Y 4 4 b 0528348 117

--```,,`-`-`,,`,,`,`,,`---

325-85

PROPERTIES OF FLAMMABLE LIQUIDS, GASES,VOLATILE SOLIDS

FLASH POINT "F ("C) Tetraamylbenzene G H i 1)4C6Hz

FIAMMABLE Vapor IGNITION LIMITS Sp. Or. Densify TEMP. Percent by Vol. (water (Air "F ("C) Lower Upper =1) =i)

295 1146)

1.1,2,2-Tetrabromoethane CHBr2CHBrz (Acetylene Tetrabromide)

0.9 635 (335)

Tetmchlorobenzene C6HzC14

31 1 (155)

Tetradecane CHdcHz)i2CH3

212 (100)

392 (200)

1-letradecene CH?:CH(CH2),iCH3

230 (1 10)

455 (235)

2.97

0.5

BOILING POINT "F ("C) 608-662 (320-350)

11.9

Water Soluble No

475 (246)

No

0.8

487 1253)

No

493 1256)

No

6.8

O

1

O

3

O

1

2

O

1

O

2

O

1

2

275 (135)

1.7

0.8

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZñRD METHODS IDENTIFICATION Flamma- ReacHealth bilify tMty

O ~

496-532 (258-2781

0.9

Tetra (2-Ethylbufyl) Silicate 335 [ C Z H ~ C H ( C ~ H ~ ) C H ~ O ] & ~(168) (oc)

0.9

Tetraethylene Glycol HOCHZ(CH20CH2)3CHzOH

360 (182) locl

1.1

Tetraethylene Glycol, Dibutyl Ether

See DibutoxyTetraglycol

Tetraethylene Glycol, Dimethyl Ether

See DimethoxyTetraglycol.

Tetraethylene Pentamine 325 HZN(CZH~NH)~CZH~NHZ (163) (oc)

6.7

1.o-

61 O (321)

Tetra (2-Elhylhe~ryl)Sillcale 390 [ C ~ H P C H ( C ~ H ~ ] C H Z ~ ] J ~(199) (oc)

200 (93)

Tetraethyl Otihoslllcaïe

See Ethyl Silicate.

tetrafluoroeîhylene F2C:CFz ITW (Perfluoroethylene)

Gas

Tetraglycol Dichloride

See Bis[2-(2-Chloroethoxy)Ethyl] Ether.

1,2,3,á-Tetrahydrobenzaldehyde CH2CH:CHCHzCHzCHCHO

135 1571 (oc)

1.8

1.6

8.6

II

10.0

50.0

1.5

1.0-

1

O

No

2

1

1

O

Decomposes

Yes

2 5

1

1

O

631 13331

Yes

2 5

2

1

O

No

2

1

1

O

Decomposes above 230 (1 10)

No

3

2

3

3.87

- 105 1-74

No

2

4

3

3.8

328 1164)

Slight

2

2

O

Noie: See Hozordous Chemicols Doto.

392 1200)

2

2

460 12381 @ 50 mm

0.9

Tetraethyl Lead, Compounds PblCzH5)4

5

Noie: See Hazardous Chemicals Dota.

5

(3-Cyclohexene-1-Carboxaldehvde) endo-Tetrahydrodicyclopentadiene ClOHi6 (Tricyclodecone)

523 1273)

0.9

O

379 1193)

Noie: Melting point 171 (77). Tetrahydrofuran OCHzCHzCH2CHz

u

6 (-14)

(DiethyleneOxide) (Tetramethylene Oxide)

610 (321)

2

11.8

0.9

2.5

151 (66)

Yes

1

2

3

1

5

Note: See Hazardous Chemicols Dato.


Not for Resale

NFPA 325 94 325-86

6474446 0528349 053


FLAMMABLE Vanor LIMITS Sp. Gr. Density FLASH IGNITION POINT TEMP. Percent by vol. (water (Air "F ("C) "F ("C) Lower Upper =i) = i ) TetrahydrofurfurylAlcohol C4H70CH2OH

167

(75)

540 (282)

1.5

9.7

Tehahydrofurfutyl Oleate 390 C ~ H ~ O C H ~ O O C C I ~ H J ~ (1 99)

160 (71)

0.9

725 (385)

0.8

d 212 (100)

Tetrahydropyran

5.0 @

BOILING POINT 'F ("C)

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHeaCh biliiy tiviiy

Yes

5

2

2

O

392-545 (200-285) @ 16 mm

No

2

1

1

O

1

2

O

352 (1 78) 8 743

1.1

loc)

Tetrahydronaphthalene C~HZICH~IZCZH~ (Tetralin)

m

1.0-

4.6

405 (207)

No

l.O+

4.0

368 (187)

Yes

5

1

2

O

361 11831

Yes

5

O

2

O

0.9

399-401 (204-205)

No

O

2

O

0.9

387-389 (197-198)

No

O

2

O

385 (196)

No

O

2

O

230 (1 101

Yes

5

O

1

O

No

3

3

3

273 (1 34)

O

3

O

270

O

3

O

302 (1 50)

See Pentomethylene Oxide.

Tetrahydropyran-2200 Methanal (93) OCH~CHZCH~CH~CHCH~OH (OC) Tetrahydropyrrole

See Pyrrolidine.

Tetralin

See Tetrahydronaphthalene.

1,1,3,3-Tetramethoxyoronone [I&O)~~HIZCH~

170 177)

1,2,3,4-Tehamethyibenzene 95% C6b(CH3)4 (Prehnitene)

166 (74)

1.2.3.5-Tetramethyibenzene 85.5% CnHdCH& - _. _.. (Isodurene)

160 (71)

1,2,4,5-Tetmmethylbenzene 95% C6Hz(CH3)4 (Durene)

130 154)

1.0-

800 est.

(427) 800 est.

(427) 0.8 @ 178 1811

4.6

Note: Melting point 174 (79). Tetmmethylene

See Cyclobutane.

Tetramethylenegiycol CH20H(CHz)zCHzOH Tetrameihvlene Oxide Tetramethyl Lead, Compounds Pb(CHd4

734 (390)

1.0+

See Tetrahydrofuran 1O0 (38)

1.6

Decomposes above

6.5

Note: See Hazardous Chemicals Dato. 2,2,3,3-TeiramethyI <70 Pentane 1<211 . . (CH~)~CC(CH~)ZCH~CH~ 2,2,3,4-Tetramethylpentane (CH3)3CCH(CH3)CH(CH3)2

806 1 . 4301

0.8

< 70

4.9

212 (100) 0.7

4.4

0.74

4.43

(i32)

Tetramethyi Tin Sn(CH3)4

< 70 l<21)

Tetraphenyl Tin (CaHsl4Sn

450 (232)

1.9

1.3

6.2

172 (78)

No

3

2

1.5

14.7

795 (424)

No

2

3

1

O

Slighi

5

2

2

1

Yes

5 2

1

1

O

O

Note: Melting point 439 (226). TetrapropionylGlucosyl Propionate

See Glucose Pentapropionate.

Thialdine 200 SCH(CH3)SCH(CH3)NHCHCHa (93)

1.1

Decomposes

1.2

540 (282)

(oc)

Note: Melting point 112 (44). 2.2-Thfodiethanol (HOCH~CHZ)~S (ThiodiethyleneGlycol)

320 (160)

lhiodieîhylene Glycol

See 2,2-Thiodiethanol.

lac)

--```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94

m 6474446 0528350 875 m 325-87


.

-

V a-r-. mar

FLAMMABLE

FLASH IGNITION POINT TEMP. "F["C) "F ["C)

I

LIMITS Sp. Gr. Density Percent by vol. (Water (Air Lower Upper =i) =i)

2

2

I

O

2.9

184 (84)

No

1

2

3

O

1.12

3.59

300 (149)

2

2

O

0.9

3.1

231 (111)

No

2

3

O

1.2

6.0

484 (251)

No

295 (140) 4 20 rnrn

Yes

2

545 (285)

Yes

2

Thiophene SCH:CHCH:CH

30 (-1)

1.1

1,4-Thioxane OíCHzCHzIzS (1,4-Oxathiane)

108 (42)

Toluene C6H5CH3 (Methylbenzene) (Phenylmethone) (Toluol1

40 (4)

1.2

1.1

7.1

~

Yes

320 (160)

896 (480)

~

Water Soluble

541 (283)

Thiodigiycol (CHzCH20H)zS (ThiodiethyieneGlycol) (Beto-bis-Hydroxyethyl Sulfide) (DihydroxyethylSulfide)

568 (298)

BOILING POINT "F ["C)

SEE INTRODUCTION FOR SUGGESTED EmINGUISHING HAZARD METHÖDS IDENTIFICATION Flamma- ReacHealth bility ti+

1


Toluene-2,4-Diisocyanate CH~C~H~(NCO)Z

260 0.9 9.5 (127) Noie: See Hazardous Chernicols Doto.

p-Toluenesulfonlc Acid CaH4JS03H)(CH31

363 (184)

3 1 3 w Reacts exothermically with woter. 3

1

1

1

O

Note: Melting point 220 (104.5). Toluhydroquinone CaH3íOH)zCh (Methylhydroquinone)

342 (172)

875 (468)


o-Toluidine CH~C~H~NHZ (2-Methylaniline)

185 (85)

900 (482)

1.0-

3.7

392 (200)

No

3

2

O

1.0-

3.9

392 (200)

No

3

2

O

2

2

1

O

2

1

1

O

Note: See Hozordous Chemicals Doto. p-Toluidine CH3CaH4NHz (4-Methyloniline)

188 900 (87) (482! Note: Melting point 111 (44). See Hozordous Chemicals Doto

Toluol

See Toluene.

rn-Toiydiethanolamine (HOCZH~IZNC~H~CH~ (MTDEA)

400 740 0.6 (204) (393) ( 4 Note: Melting point 144 (62).

2A-ToIylene Diisocyanate

See Toluene-2.4-Diisocyanote.

o-Tolyl Phosphate

See Tri-o-Cresyl Phosphate.

o-Toiyl p-Toluene Sulfonate CidHi 1 0 1 5

363 (1 84)

Tmnril Oil

See Transformer Oil.

Triacetin

See Glyceryl Triocetote.

Triamylamine (C5Hii)aN

215 (102)

No

1.2

0.8

453 (234)

No

2

2

1

O

0.9

575 (302)

No

2

O

1

O

417 (214)

No

3

2

O

(OC)

Note: See Horordous Chemicals Doto. Trlamylbenzene (C5H1133c6H3

270 (132) (oc1

187 (86)

0.8

6.4

(4

Note: See Hozordous Chernicols Data.

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 9 4 325-88

m

b47444b 0528351 701


FLAMMABLE Vapor FLASH IGNITION LIMITS Sp. Gr. Density POINT TEMP. percent bY vol. (Water (Air OF(%) 'F("C) Lower Upper =1) =i) Tributyi Citrate 315 C ~ H ~ ( O H ) ( C O O C ~ H P ) ~ (157) Tributyl Phosphate lC&W"4

695 (368)

295 1146)

BOILING POINT OF(%)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- Reactivity Health biliv

1.0+

450 (232)

No

2

O

1

O

1.0-

560 (293)

No

2

2

1

O

473 12451

No

O

1

O

Decomposes

2

1

1

2

1

O

(oc)

Tributylphosphine 1CdHoI.P

392 12001

Tribuiyl Phosphite (C4H913PO3

248 1120)

1,2,4-Trichlorobenzene C6H3C13

222 (105)

(4 1060 (571)

-

2.5

6.6

0.9

244-250 (118-121) @7mm

1.5

415 1213)

No

4.55

165 1741

No

2

1

O

2

1

O

3

2

O

3

4

2w

3

@302(150)

1,l.l -TrichIomethane CHKCI? (Methyl Chloroform)

None

Trichloroethylene C1HC:CCIz

None

10.5 1.5 @ 25°C 1420) 7.8 52 @ 100°C Note: See NFPA 49, Hazardous Chemicals Dato.

4.5

188 (87)

No

1,2,3-Trichloropropane CHzCICHCICHzCI (Allyl Trichloride) (Glycevl Trichlorohydrin)

160 (71)

1.4

5.1

313 (156)

No

1.3

4.7

89 (32)

Trichlorosilane HSiC13

7.5

788

12.5

1.32

8

3.2 @ 120°C

12.6

(3150°C

7 (-14)

3

Decomposes

(4 Tri-o-Cresyl Phosphate (CH3CbH4I3PO4 (o-Tolyl Phosphate)

437 (225)

Tridecanol cHdcHz)izoH

250 (121)

725 (385)

1.2

0.8

6.9


No

2

2

1

O

525 (274)

No

2

O

1

O

No

2

1

1

O

5

O

2

O

(oc)

Note: Meltina point 86 (301. ~

2-Tridecanone

See Methyl Undecyl Kelone.

Tridecyl Acrylate CHz:CHCOOCi3Hz7

270 (132)

0.9

302 (150) @10mm

180 (82)

0.8

485-503 (252-262)

0.9

356 (180) @0.1 mm

No

2

O

1

O

2 5

2

1

1

1

1

O

Tridecyl Alcohol Ci+hCH20H (Tridecanol)

Triethanolamine (CHzOHCHz)3N

104

(4


354 (179)

1.1

5.1

650 13431

Yes

1.1.3-Triethoxyhexane CH(OCzHs)?CHzCHíOCzH51CaH7

210 (99)

0.9

7.5

271 1133) @ 50 mm Decomposes @ 760 mm

No

Trieîhylaluminum (C2H5)3AI

Note: Ignites spontaneouslyin oir.

Triethylamine íC2HhN

16 (-7)

1.2,CTriethylbenzene ICZHS)~C~H~

181 1831

(2,2',2"-Nitrilotriethonol)

I

Iod

480 (249)

1.2

3 4 3w Do no1 use water, foam, or hologenoted extinguishing agents.

8.0

0.7

3.5

193 1891

No

0.9

5.6

423 (217)

No

1 5

3

3

O

2

O

(oc)

56 @115"C

(4


--```,,`-`-`,,`,,`,`,,`---

Not for Resale

NFPA 325 9 4

m 6474446 0528352 648 325-89


FLASH POINT "F("C)

IGNITION TEMP. "F(4)

FLAMMABLE Vaoor LIMITS Sp. Gr. Den& Percent by Vol. (water (Air =i) =i) Lower Upper

Triethylborane lCzH5)3B

Note: Ignites spontaneously in air.

Triethyl Citrate HOC(CHzCO&H5)COzC2h

303 (151)

Triethylene Glycol HOCH?(CH2OCH2)2CH?OH (Dicoproote) (2,2-Eihylenedioxydiethonol)

350 (177) (oc)

Trlethyiene Glycol Diacetate CH3COO(CHzCH?O)3COCH3 (TDAC)

345 1174)

Methylene Glycol, Dimethyl Ether CH3(OCHz)3OCH3

232 (1111

Triethylene Glycol, Ethyl Ether

See Ethoxyiriglycol.

Triethylene Glycol, Methyl Ether

See MethoxyTriglycol.

0.9

Waïer Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth biliíy Hvily 1 3 Do not use hologenoted extinguishing agents.

1.1

700 (371)


9.2

1.1

5.2

1.1

3w

561 (294)

Very slight

2

O

1

O

546 (286)

Yes

2

1

1

O

572

Yes

O

1

O

5

5

(300)

2

42 1 (216)

2

1

1

O

5

O

1

O

3

1

O

O

1

1

4

O

1

O

1

O

4

3w

(OC)

1.0-

4.7

(oc1

1.ot

Triethylenetetramine HzNCHz(CH2NHCHz)zCHzNHz

275 (135)

640 (338)

1.0-

Triethyl Phosphate lCzH5)3P04 IElhvl Phosphate1

240 (115)

850 (454)

1.1

Trifiuorochloroethylene CF2:CFCI (R-1113)

GOS

270 (132)

Yes

532 (278)

Yes

408-424 (209-21 8)

Yes

2 2 5 5

2

(oc)

8.4

16.0

1.31 @5.7 atm

4.02

-18

6

í - 28)

(Chlorotrifluoroethylene)

Triglycol Dichloride CICHz(CH30CH2)2CHzCI

250 (121) locl

1.2

466 1241)

0.9

275-286 (135-1 41) @2mm

No

2

2

Decomposes Decomposes in water.

Note: Moy ignite spontaneouslyin air.

3

Do not use wafer, foam or halogenated extinguishing agents.

I Trlisobulyl Borate B(OC~HP)~

185 (851

0.84

7.94

413 (212)

3

2

1

2

1

O

O

1

O

3

3

1

O

1

O

(oc) Triisopropanolamine [ICH~)ZCOHJ~N (1,1',1 "-Nitroldri-ipropanol)

320 (160)

Triiropropylbenzene c6hIcH3cHCH3)3

207 (971 (oc)

0.9

82

0.82

Triisoprapyl Borate (C3H70hB Trilauryl Trithiophasphite lCH3íCHz)i iSl3P

608 (320)

1.0-

584 13071

Yes

495 (2371

No

2 5

(4

6.49

(281 398

288 (142)

0.9

2

(203)

(4

Trimethylaluminum (CHd3AI

Noie: Ignites sponianeouslyin air.

Trimathylamine

Gas

374 2.0 11.6 (190) Note: See Hazardous Chemicals Data.

3 3w Do not use water, foam or halogenated extinguishing agents. 38 (3)

2.0

Yes

6

3

4

O

1994 Edition --```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 94 325-90

m

b 4 7 4 4 4 b 0528353 584

m


FLAMMABLE Vaaar FLASH IGNITION LIMITS 5p.Gr. Dei& POINT TEMP. Percent by vol. (Water (Air +(T) OF(%) Lower Upper =i) =i) ~~

1.2.3-Trimethylbenzene C6h(CH3)3 (Hemellitol)

111 (44)

878 (470)

1.2.3-Trimethylbenzene 90.5% CóH3íCHd3 (Hemimellitine90.5%)

128 1531

895 1479)

1.2.4-Trimethylbenzene Cóh(CHd3 (Pseudocumene)

112 (44)

(500)

1.3,5-Trimethylbenzene c 6 H d c H ~.) ~ (Merilyiene)

122 (50)

1039 (559)

Trimeihyl Bomie

See Methyl Borate.

2,2,3-Trimethylbutone (CHJ)~C(CH~ICHW (Triptane-on isomer of Hepione)

(
2.3.3-Trimethyl-1 -Butene (CH~)~CC(CH~):CHZ (Heptdenel

(
Trimethyl Carbinol

See tert-Butyl Alcohol.

Trlmethylchlororilane (CH3)3SiCI

< 32

-

3.3.5-Trimethyl-1 Cyclahexanol CH2CH(CH3)CH2C(CH3)2-

2

O

No

O

2

O

329 (165)

No

O

2

O

4.1

328 (164)

No

O

2

O

0.69

3.46

178 (81)

O

3

O

0.71

3.39

172 (78)

O

3

O

0.9

3.75

135 (57)

3

3

2w

0.9

4.1

347-351 (175-1771

0.87

4.15

0.9

774 (412)

707 (375)

6.4

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flomma- ReacHealih bility tMty O

349 (176)

0.9

6.6

BOILING POINT O F ("C)

4.15

0.8

-18 ( - 28)

Yes

1

O

O

597 (314)

1,3,5-Trimethylcyclohexane (CHd3cób (Hexohydromesitylene)

Trimethylcyclohexanol CH(OH)CHzC(CH&

~~~

0.89

932

~ 3 2

~

2

2

O

5

2

2

O

Yes

5

1

255 (124)

No

1

2

3

O

381 (194)

No

2

2

O

O

2

O

2

2

O

2

2

O

O

1

O

O

3

O

165 (74)

0.9

4.9

388 (198)

No

190

0.9

4.9

388 (198)

Slight

1.1

2.6

417 (214)

0.7

4.4

(88) (oc)

I CHzCHOH

2 Trimethylene

See Cyclopropane.

Trimethylenediamine

See 1.3-Propanediamine.

Trimethylene Glycol HO(CHz)3OH (1.3-Proponediol) Trimethylethylene

752 (400)

O

See 2-Methyl-2-Buiene.

. . 3,5,5-Trlmeîhylhexanol CH~C(CHJ)~CH~CH(CH3)CH,CHzOH

200 193) (oc)

0.8

2,4,ô-Trimeîhyl-6Nonanol Cd%CH(OH)C7HI s (2,6,8-Trimeihyl-4nononol)

199 193) (oc)

0.82

6.43

491 (255)

0.8

2.6.8-Trimethrl-4195 . . Nonanoni 191) (OC) (CH~)ZCHCH~CH[CH~)CH~COCH7CHCHd7

0.8

Trlmethylolpropane 300 Tliacrylale (1491 CZH~C(CH~OCOCHCHZ)~ (OC)

1.5

2,2,3-Trimeîhylpentane CH3CH2CH(CH3)C(CH3)3

<70 (<21)

745 (346)

0.72

6.3

No

2

3.94

1994 Edition --```,,`-`-`,,`,,`,`,,`---


425 (218)

Not for Resale

230 (1 10)

NFPA 325 9 4

m 6474446

0528354 4 L O

m 325-9 1


FLASH IGNITION POINT TEMP. O F ( % ) 'F ["C) 1.2.4-Trimethylpentane

10 (CH~)~CCHZCH(CH~)Z (-12)

779 (415)

<70 (<21) 235 (1 13)

2~,3-Trimethylpentane

CH~CHZC(CH~)ZCH(CH& 2.2.4-Trimethyl- 1.3Penîanediol

FIAMMABLE Vapor LIMITS Sp.Gr. Density Percent by Vol. (water (Air Lower Upper =1) =1)

6.0

0.7

3.9

797 (425)

0.73

3.94

655 (346)

0.9

1.1

BOIUNG POINT "F ("C)

21 1 (99)

Water Soluble

No

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING W R D METHODS IDENTIFICATION Flamma- ReacHealth biiiiv tMtv

3

O

O

3

O

2

O

1

O

2

O

1

O

2

O

1

O

2

O

1

O

1

239

(i 15) 419-455 (215-235)

No

(oc)

(CH3)2CHCH(OH)C(CH3)2CHzOH

Note: Melting point 115-131 (46-55). 2.2.4-Trimethyl pentanediol Diisobutyrate

250 (121)

795 (424)

0.5@

248 (120)

740 (393)

0.6@ 300 I .1491.

(4

0.9

9.9

342 (1 72)

536 (280)

C16H3004 2.2.4-Trlmeîhyl-1.3Pentanediol Irobvhrate

(oc1

(CH~)ZCHCH(OH)C(CHJ)~CH-~OOCCHICHQI? 2,2,4-Trimeîhylpentanediol Isobuiyrate Benzoate

4.2@ 393 I .2011,

325 (1 63)

1.0-

356-360 125 mrn 1180-1821

1 .o

167 (75) @ 1Omm

(oc)

No

Ci 9H2a04

2.4.4-Trimethyi-lpentene

23

0.7

3.8

214 1101)

Na

1

2

3

O

581 (305)

0.7

3.8

221 (105)

No

1

2

3

O

617 (325)

0.74

3.87

234 (112)

O

3

O

1.0+

4.3

232-234 ( I 1 1-1 12)

No

O

2

O

212 (1 00) @ 0.01 mm

No

2

O

1

O

Slight

5

2

2

O

O

1

O

(-5)

736 (391)

35 (2)

0.8

4.8

CHZ:C(CH~)CHZC(CH~)~ (Diisobutylene) 2,4,4-Trimethyl-2pentene

( 4

CH3CH:C(CH3)C(CH3)3 3,4,4-Trimeihyl-2pentene

(CH&CCfCH?I:CHCHi

<70 (<21)

Trimethyi Phorphie

130

(CH3013P

(54) (oc)

Trioctyl Phosphite CaHi 70)3p [Tris (2-Ethylheryl) Phosohitel

340 (1711

0.9

(oc)

Trioxane

113 (45)

OCHzOCHzOCH2

I (04

777 (414)

3.6

29

239 (1 15) Sublimes

Note: Melting point 147 (64). Trlphenylmethone

(CóHJ3CH

>212 (>loo)

Triphenyl Phosphate

(CóHd3Pod

428 (220)

See Triphenylphosphorus.

Triphenyi Phosphite

425 (218)

Triphenyiphosphorus

(CaHshP (Triphenylphosphine) Tripropyl Aluminum

8.43

678 (359)

1.3

750 (399)

No

2

2

1

O

1.2

311-320 (1 55-160)

Na

2

O

1

O

No

2

O

1

O

3

3w

Note: Meltina aoint 122 1501.

Triphenylphosphine

(CaHs0)3P03

1.01


(4

@ 0.1 rnrn

356 (180)

9.0

71 1 (377)

(oc) Note: Melting point 176 (80). Note: Ignites spontaneouslyin air.

Da not use water, foam or halogenoted exiinguishing agents.

íC3H7)3AI

Tripropylamine

(CH~CH~CHZ)~N

105 (41)

0.8

4.9

313 (156)

V:ry

2

2

O

slight --```,,`-`-`,,`,,`,`,,`---

lac)


Not for Resale

NFPA 325 94 H 6474446 0528355 357 H 325-92


FLASH POINT “F(“C) Trlpropylene C9H18 (Propylene Trimer)

FLAMMABLE Vapor IGNITION LIMITS Sp. Gr. Density TEMP. PeKewbYvOl. (Water (Air “F (“Cl Lower Upper =1) =i)

75 (24)

0.7

4.35


Water Soluble

271-288 (133-142)

SEE INTRODUCTION FOR SüGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bllity tlvhy

1

O

3

O

2

O

1

O

O

1

O

(oc)

1.0+ Tripropylene Glycol Methyl Ether HO(CJH~O)&H~OCH~

250

0.97

514 (268) 7.12

(121)

Tris (2-Ethylhexyl) Phosphite

See Trioctyl Phosphite.

Tung Oil (Chino Wood Oil)

552 (289)

Turblne Oil

See Lubricoting Oil, Turbine.

Turbo Fuels

See Jet Fuels.

Turlcey Red O i l

476 (247)

833 (445)

95 (35)

488 (253)

855 1457!

Yes

470 (243)

0.9

No

2

O

1

O

1 .o-

Yes

2

O

1

O

1

3

O

1

2

O


Turpentine Ultrasem (Kerosene, Deodorized) Undecane

5 0.8

<1

300 (1 491

No

1

No

175

(79) See Hendecone.

0.8

Unsymmetrical Dimeîhylhydrazine Valeraldehyde CHa(CH2)3CHO (Pentanal)

437 (225)

No

2

1

1

O

217

No

1

1

3

O

Slight

1 5

2

3

2

2

4

3

2

See 1,l-Dimethylhydrazine.

54

432

(12)

(222)

0.8

3.0

1103)

(oc)

Valeric A d d

See Pentonoic k i d .

Vinyl Acetate CHz:CHOOCCH3 (Ethenyl Ethanoote)

18 (-8)

756 (402)

2.6

13.4

0.9

3.0

161 (72)

1.80

41

Note: Polymerizes. See Hozordous Chemicols Doto.

Vinylaceto-ß-Lactone

See Diketene.

21

Vinyl Aceíylene CH2:CHCi CH (1-Buten-3-yne)

100

0.68 @1.7 otm

15)

Spont. decomposition Vinyl Allyl W e r CHz:CHOCHzCH20(CHhCH3 (Allyl Vinyl Ether)

c 68

Very slight

1

2

3

444 (229)

No

2

2

1

No

2

O

1

2

3

2

2

3

2

0.8

153 (67)

1.1

( <20)

(4

Vinylbenzene

See Styrene.

Vinylbenzylchlorlde CICH&H4CH:CH2

(104)

220 for\

Vinyl Brornlde

None

986 (530)

Vinyl Butyl Ether CH2:CHOC,H, (8*i Vinyl Ether)

15

(-9)

437 (255)

9

15

1.5

3.7

60 (15.8)

0.8

3.5

202 (94)

Slight

242 (1 17)

Slight

1

5

(4

Vinyl Butyrate CHz:CHOCOCsH,

68

1.4

8.8

0.9

4.0

120)

1

5

(4 vinyl 2-Chloroeíhyl Ether CH2:CHOCHzCHiCI (2-Chloroethyl Vinyl Ether)

Vinyl Chloride CH2CHCI (Chloroethylene)

80 (27)

1.ot

3.7

228 (1 09)

Slight

1 5

2

3

2

.91

2.2

7 (-14)

NO

6

2

4

2

(oc)

-108.4

1-78)

882

3.6

33.0

(472)

(oc)

Note: Polymerizes. See Hozordous Chemicols Doto.

1994 Edition

--```,,`-`-`,,`,,`,`,,`---


Not for Resale

b 4 7 4 4 4 b 0528356

NFPA 325 94

325-93

PROPERTIES OF FLAMMABLE LIQUIDS, GASES,VOLATILE SOLIDS

FLAMMABLE Vapor F W H IGNITION LIMITS Sp. Gr. Density POINT TEMP. Percent by vol. (Water (Air "F("C) "F ["C) lower Upper =i) =i) Vinyl Crotonate CH?:CHOCOCH:CHCH3

78 126)

0.9

4.0

BOILING POINT "F ("C) 273 (134)

Water Soluble

SEE INTRODUCTIONFOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTIFICATION Flamma- ReacHealth bility tivity 2

3

2

O

3

2

O

2

O

2

4

2

2

2

2

5

2

2

2

Slight

6

1

4

2

NO

4

2

4

2

Slight

6

1

4

2

1 5

2

3

2

1

2

O

2

4

2

O

3

O

Slight

1

5

IOCI

Vinyl Cyanide

See Acrylonitrile.

4-Vinyl Cyclohexane CBHIZ Vinyl Ether

61 1161

Vinyl Ethyl Ether CHz:CHOC2H5 (Hhyl Vinyl Ether)

0.8

3.7

266 (1301

1

34

0.84

2.49

233 (1121

Yes

28

0.8

2.5

96 136)

No

0.9

6.0

365 (185)

No

0.8

5.4

352 (178)

Slight

See Divinyl Ether.

Vinyl Ethyl Alcohol CHz:CH(CHz)zOH (3-Buten-1-01) Vinylelhylene Oxide

51 7 (269)

1O0 1381

4.7

See ButadieneMonoxide.

< -50 (<-46)

Vinyl 2-Ethylhexoate CHz:CHOCOCH(CzH5)CdHp

395

1.7

(202)

165 (74)

1 5

IOCI

Vinyl 2-Ethylhexyl Ether CioH2oO (l-Ethylhex$ Vinyl Ether)

135 157)

2-Vinyl-5-Ethylpyridine N:C(CH:CHz)CH:CH-

200 1931

395 (202)

(oc1

0.9

248 1120) @ 50 mm

I (4

No

C(CzH5):CH

Vinyl Fluoride CHzCHF Vinylidene Chloride CHz:CCIz (1,l-Dichloroethylene)

2.6

Gas

21.7

-97.5 1-721

-19 1058 6.5 15.512 1-26) 1570) Note: Polymerizes. See Hazardous Chemicals Dota.

5.5

3.4

Vinylidene Fluoride CHz:CFz

Gas

Vinyl Isobutyl Ether CH2:CHOCH2CH(CH3)CH3 (Isobutyl Vinyl Ether)

15 (-9)

0.8

3.5

182 (83)

Slight

Vinyl Isoodyl Ether CHz:CHO(CHz)~CH(CH3lz (Isooayl Vinyl Ether)

140 (601

0.8

5.4

347 11751

No

3.0

133 (56)

3.52

228

Vinyl Isopropyl Ether CHz:CHOCH[CH3)2 (isopropylVinyl Ether)

21.3

89 (32)

- 122.3

1-86]

-26 (-32)

522 (272)

1 5

~

Vinyl 2-Methoxyethyl Ether CHz:CHOC2HdOCHj (1-Methoxy-2-Vinyloxyethane)

64 118)

0.90

11091

(oc)

Vinyl Methyl Ether CHz:CHOCH3 (Methvl Vinyl Ether)

Gas

Vinyl Octadecyl Ether CHz:CHO[CHz)i7CH3 (Octadecyl Vinyl Ether]

350 (1771 Note: Melting point 82.4 (28).

Vinyl Propionate CHz:CHOCOC2H5

34 (1)

1-Vinylpyrrolidone CHsCHNCOCHzCHzCHz

209 (98)

549 (287)

2.0

0.8

Slight

6

2

4

2

No

2

O

1

O

203 (95)

Slight

1 5

2

3

2

205

Yes

5

O

1

O

2

2

2

3

3

2w

43 (61 297-369 (147-1 87) @5mm

0.9

3.3

1.0+

3.8

(04

(96) @14mm

(oc3

(Vinyl-2-Pyrrolidane) Vinyl-2-Pyrrolidone

See 1-Vinylpyrrolidone.

Vinyl Toluene CHjC*H&H:CHz

127 153)

1000 (538)

0.8

11.0

0.9

4.08

334 11681

1.3

5.61

195 (911

No

Note: See Hozardous Chemicals Dato.

Vinyl Trlchlorosilane CHz:CHSiC13

70 (21)

1

IOCI

1994 Edition

--```,,`-`-`,,`,,`,`,,`---


Not for Resale

NFPA 325 74 W b 4 7 4 4 4 b 0528357 1 2 T 325-94


FLASH POINT

"F CC)

Water Gas Wax, Microcrystalline

FLAMMABLE Vapor IGNITION LIMITS Sp. Or. Density TEMP. P e N e m b V o l . (Wahr (Air "FCC) Lower Upper =1) =1)

BOILING POINT "FCC)

Water Soluble

SEE INTRODUCTION FOR SUGGESTED EXTINGUISHING HAZARD METHODS IDENTiFIC&TION Flamma- ReacHealth bility tivity

See Gos. >400 ( > 204)

0.9

Wax. Ozocerite (MineralWax)

236 (1 13)

0.9

Wax. Paraííin

390 473 (199) (243, Note: Melting point 120-167 (49-75).

0.9

Whale Oil

446 12301

800 14271

>700 (>371)

0.9

2

O

1

O

No

2

O

1

O

No

2

O

1

O

No

2

O

1

O

--```,,`-`-`,,`,,`,`,,`---

Whisker

See Ethvl Alcohol and Water.

White Tar

See Naphthalene

Wines Sherry and Port High

See Ethyl Alcohol and Woter

Wood Alcohol

See Methyl Alcohol

Wood Tar Oil

See Pine Tar Oil.

Wool Grease

See Lanolin.

m-Xylene CéH&Hdz ( 1,?.-Dimethylbenzene)

81 982 1.1 7.0 (27) (527) Note: See Hazardous Chemicals Data.

0.9

3.7

282 (139)

No

1

2

3

O

o-Xylene CéH4íCH3)z (1,2-Dimethylbenzene) (o-Xylol)

90 (32)

0.9

3.7

292 (144)

No

1

2

3

O


p-Xylene C6H.i(CH3)z (1,4-Dimethylbenzene)

1.1 7.0 984 15281 Note: See Hazardous Chemicals Dato.

0.9

3.7

28 1 (138)

No

1

2

3

O

o-Xylidine CéHdCH3)z"z (o-Dimethylaniline)

1.o 206 (97) Note: See Hazardous Chemicals Data.

1.o-

435 (224)

No

3

1

O

O

1

O

867 (463)

0.9

6.7

81

(27)

o-Xylol

See o-Xylene.

Zinc Diethyl

See Diethylzinc.

Zinc Stearate ZniaH.4~

530 (277)

788 (420)

1.1

(4


Not for Resale

NFPA 325 94

6474446 0528358 Ob6

=

The NFPA Codes and Standards Development Process Since 1896, one of the primary purposes of the NFPA has been to develop and update the standards covering ali areas of fire safety.

Calls for Proposals The code adoption process takes place twice each year and begins with a call for proposals from the public to amend existing codes and standards or to develop the content of new fire safety documents.

Upon receipt of public proposals, the technical committee members meet to review, consider, and act on the proposals. The public proposals - together with the committee action on each proposal and committeegenerated proposals - are published in the NFPA's Report on Proposals (ROP). The ROP is then subject to public review and comment.

Report on Comments These public comments are considered and acted upon by the appropriate technical committees. All public comments - together with the committee action on each comment - are published as the Committee's supplementary report in the NFPA's Report on Comments (ROC). The committee's report and supplementary report are then presented for adoption and open debate at either of NFPA's semi-annual meetings held throughout the United States and Canada.

Association Action The Association meeting may, subject to review and issuance by the NFPA Standards Council, (a) adopt a report as published, (b) adopt a report as amended, contingent upon subsequent approval by the committee, (c) return a report to committee for further study, and (d) return a portion of a report to committee.

Standards Council Action The Standards Council will make a judgement on whether or not to issue an NFPA document based upon the entire record before the Council, including the vote taken at the Association meeting on the technical committee's report.

Voting Procedures Voting at an NFPA Annual or Fall Meeting is restricted to members of record for 180 days prior to the opening of the first general session of the meeting, except that individuals who join the Association at an Annual or Fall Meeting are entitled to vote at the next Fall or Annual Meeting. "Members" are defined by Article 3.2 of the Bylaws as individuals, firms, corporations, trade or professional associations, institutes, fire departments, fire brigades, and other public or private agencies desiring to advance the purposes of the Association. Each member shall have one vote in the affairs of the Association. Under Article 4.5 of the Bylaws, the vote of such a member shall be cast by that member individually or by an employee designated in writing by the member of record who has registered for the meeting. Such a designated person shall not be eligible to represent more than one voting privilege on each issue, nor cast more than one vote on each issue. Any member who wishes to designate an employee to cast that member's vote at an Association meeting in place of that member must provide that employee with written authorization to represent the member at the meeting. The authorization must be on company letterhead signed by the member of record, with the membership number indicated, and the authorization must be recorded with the President of NFPA or his designee before the start of the opening general session of the Meeting. That employee, irrespective of his or her own personal membership status, shall be privileged to cast only one vote on each issue before the Association. Copyright National Fire Protection Association Provided by IHS under license with NFPA No reproduction or networking permitted without license from IHS

Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Report on Proposals

~

NFPA 325 94

= b47444b

~~

0528359 T T 2

Sequence of Events Leading to Publication of an NFPA Committee Document Call for proposals to amend existing document or for recommendations on new document.

v Committee meets to act on proposals, to develop its own proposals, and to prepare its report.

v Committee votes on proposals by letter ballot. If two-thirds approve, report goes forward. Lacking two-thirds approval, report returns to committee.

Report is published for public review and comment. (Report on Proposals - ROP)

v Committee meets to act on each public comment received.

v Committee votes on comments by letter ballot. If two-thirds approve, supplementary report goes forward. Lacking two-thirds approval, supplementary report returns to committee.

v Supplementary report is published for public review. (Report on Comments - ROC).

v NFPA membership meets (Annual or Fall Meeting) and acts on committee report (ROP and ROC).

v Committee votes on any amendments to report approved at NFPA Annual or Fall Meeting.

v Complaints to Standards Council on Association action must be filed within 20 days of the NlTA Annual or Fall Meeting.

Appeals to Board of Directors on Standards Council action must be filed within 20 days of Council action.


Not for Resale

--```,,`-`-`,,`,,`,`,,`---

Standards Council decides, based on all evidence, whether or not to issue standard or to take other action, including hearing any complaints.

NFPA 325 94

6474446 0528360 714

FORM FOR PROPOSALS ON NFPA TECHNICAL COMMITTEE DOCUMENTS Mail to: Secretary, Standards Council National Fire Protection Association, 1 Batterymarch Park, Quincy, Massachusetts 02269-9101 Fax NO. 617-770-3500 Note: All proposals must be received by 5:oO p.m. ESTEDST on the published proposal-closing date. If you need further information on the standards-making process, please contact the Standards Administration Department at 617-984-7249.

Date

Name

9118/93

Tel. No. 617-555-12 12

John B. Smith

Company Street Address

9 Seattle St., Seattle, WA 02255

Please Indicate Organization Represented (if any) Fire Marshals Asn. of North America N

1. a) NmA Document Title National Fire Alarm Code b) Section/Paragraph

~

NO. A

& Year NFPA 72,1993 4.

1-5-8.1(Exception No.1) FOR OFFICE USE ONLY

2. Proposal recommends: (Check one)

O new text O revised text E¡ deleted text

Date Rec'd

Delete exception.

4. Statement of Pro tion; give the specific

A properly installed an em should be free of ground faults. The occurrence of one or more ground faults should be required to cause a "trouble" signal because it indicates a condition that could contribute to future malfunction of the system. Ground fault protection has been widely available on these systems for years and its cost is negligible. Requiring it on all systems will promote better installations, maintenance and reliability.

This Proposal is original materiai. (Note: Original material is considered to be the submitter's own idea based on or as a result of hidher own experience, thought, or research and, to the best of hidher knowledge, is not copied from another source.)

5.

O This Proposal is not original material; its source (if known) is as follows: Note 1: Type or print legibly in black ink. Note 2: If supplementary material (photographs. diagrams, reports, etc. ) is included, you may be required to submit sufficient copies for all members and alternates of the technical committee.

I hereby grant NFPA the non-exclusive, royalty-free rights, including non-exclusive, royalty-free rights in copyright, in this proposai and I understand that I acquire no rights in any publication of NFPA in which this proposal in this or another similar or analogous form is used.

%Øu Signature (Required)

--```,,`-`-`,,`,,`,`,,`---


PLEASE USE SEPARATE FORM FOR EACH PROPOSAL Not for Resale

NFPA 325 74

= b47444b

0528363 b50

=

FORM FOR PROPOSALS ON NFPA TECHNICAL COMMITTEE DOCUMENTS Mail to: Secretary, Standards Council National Fire Protection Association, 1 Batterymarch Park, Quincy, Massachusetts 02269-9101 F ~ NO. x 617-770-3500 Note: All proposals must be received by 500 p.m. ESTEDST on the published proposal-closing date. If you need further information on the standards-making process, please contact the

Standards Administration Department at 617-984-7249.

--```,,`-`-`,,`,,`,`,,`---

Date

Name

Tel. No.

Company

I

I

I I

I I I

I

I I I I I I I I I I I I

I I I I I I I I

I I I I I I I

I

Please Indicate Organization Represented (if any)

I I

1. a) NFPA Document Title

b) Sectioflaragraph

" P A No. & Year

~

2. Proposal Recommends: (Check one)

O new text O revised text O deleted text

Log # Date Rec'd

I I I

I I I I I I I I I I I I I I

I I

I

3. Proposal (include proposed new or revised wording, or identification of wording to be deleted):

I I

:c:

;a

:3

4. Statement of Problem and Substantiation for Proposal: (Note: State the problem that will be resolved by your recommendation; give the specificreason for your proposal including copies of tests, research papers, fue experience, etc. If more than 200 words, it may be abstracted for publication.)

I I I I I I I I I I I I I

I I I I I I I I I I I I I I I I

I I

5. O This Proposal is original material. (Note: Original material is considered to be the submitter's own idea based on or as a result of hidher own experience, thought, or research and, to the best of hidher knowledge, is not copied from another source.)

O This Proposal is not original material; its source (if known) is as follows: Note 1: Type or print legibly in black ink. Note 2: If supplementary material (photographs. diagrams, reports, etc.) is included, you may be required to submit sufficientcopies for ail members and alternatesof the technical committee.

I hereby grant NFPA the non-exclusive, royalty-free rights, including non-exclusive, royalty-free rights in copyright, in this proposal and I understand that I acquire no rights in any publication of NFPA in which this proposal in this or another similar or analogous form is used.

Signature (Required) PLEASE USE SEPARATE FORM FOR EACH PROPOSAL Copyright National Fire Protection Association Provided by IHS under license with NFPA No reproduction or networking permitted without license from IHS

Not for Resale

I I I I I I I l l I I

I I I I I I I

I I

I I I I I I I I I I I I I I I I I

I I I

NFPA 325 94

œ

b 4 7 4 4 4 b 0528362 597

rn

Bibliography of NFPA Standards 1 Fire PreventionCode 10 Portable Extinguishers 10R Portable Fire Extinguishing Equipment in Dwellings 11 Low-Expansion Foam 11A Medium- and High-Expansion Foam Systems 11C Mobile Foam Apparatus 12 Carbon Dioxide Systems 12A Halon 1301 Systems 12B Halon 1211 Systems 13 Sprinkler Systems 13D Sprinkler Sys., Dwellings 13E Sprinkler Prop., F.D. Operations at 13R Sprinkler Sys.. Res. Occ. up to and Including4 Stories 14 Standpipe, Hose Systems 15 Water Spray Fixed Systems 16 Deluge Foam-Water Systems 16A Closed Head Foam-Water Sprinkler Systems 17 Dry Chem. Ext. Systems 17A Wet Chem. Ext. Systems 18 Wetting Agents 20 Centrifugal Fire Pumps 22 Water Tanks 24 Private Fire Service Mains 25 Water-Based Fire Prot. Systems 26 Supv'n. Water Supply Valves 30 flam. Liquids Code 30A Automotive and Marine Service Station Code 308 Aerosol Products 31 Oil-Burning Equipment 32 Drycleaning Plants 33 Spray Application 34 Dipping and Coating Processes 35 Mfg. Organic Coatings 36 Solvent Extraction 37 Combustion Engines 40 Motion Picture Film 40E Pyroxylin Plastic 43A Liquid, Solid Oxidizers 438 Organic Peroxide Formulations 43D Storage of Pesticides 45 Labs Using Chemicals 46 Forest Products. Stwage 49 Hazardous Chemicals Data 50 Bulk Oxygen Systems 50A Gaseous Hydrogen Systems 508 Liquefied Hydrogen Systems 51 Welding and Cutting 51A Acetylene Charging Plants 518 Welding Proceses 52 CNG Vehicular Fuel Systems 53 Oxy. Atmospheres 54 Nat'l Fuel Gas Code 55 Ccmpressed and Liquefied Gases in Portable Cylinders 57 LN Gas Vehicular Fuel Systems 58 LP-Gas Storage, Use 59 LP-Gas, Utility Plants 59A LN-Gas. Stg.. Handling 61A Starch, Mfg. Handling 61B Grain Elevators 61C Feed Mills 81O Agricultural Commodities 65 Aluminum Processing 68 Venting of Deflagrations 69 Explosion Prev. Systems 70 Nat'/ Electrical Code 70A Dwelling Electrical Code 708 Elect. Equip. Maint. 70E Employee ElectricalSafety 72 National Fire Alarm Code 73 Residential Elect. Maint. 75 Electronic Computer Systems 77 Static Eiectricity 79 Elect. Std. for Ind. Machinery 80 Fire Doors and Fire Windows SOA Exposure Fires, Rot. 81 Fur Storage B Cleaning 82 Incinerators, Systems 8 Equip. 85C Furnace Explosicasilmplosionsin Multiple Bumer Boiler-Fumaces

86 Ovens and Furnaces 86C Ind. Fum., Sp. Processing 86D Ind. Vacuum Furnaces 88A Parking Structures 888 Repair Garages 90A Air Conditioning Systems 908 Warm Air Htg., Air Cond. 91 Exhaust Syst. for Air Conveying of Materials 92A Smoke-Control Systems 928 Smoke Mgmt. Syst. in Malls, Atria, Large Areas 96 Commercial Cooking Operations 97 Heating Terms, Glossary 99 Health Care Facilities 996 Hypobaric Facilities 99C Gas and Vacuum Systems 1OT Life Safety Code 101M Alt. Approaches to Life Safety 102 Assembly Seating, Tents 105 Smoke-Control Door Assemblies 110 Emer.. Standby Power Systems 111 Stored Electrical Energy Emer. & Standby Power Systems 120 Coal Preparation Plants 121 Self-Propelled & Mobile Surface Mining Equip. 122 Flam. &Comb. Liquids in Mines 123 Underground Bit. Coal Mines 124 Diesel Fuel & Equip. in Underground Mines 130 Fixed Guideway Transit Systs. 150 Racetrack Stables 170 Fire Safety Symbols 203 Roof Coverings 204M Smoke, Heat Venting 211 Chimneys, Fireplaces. Vents 214 WaterCooling Towers 220 Types Bldg. Construction 221 Fire Walls and Fire Barrier Wails 231 General Storage 231C Rack Storage of Mat'ls. 231D Storage of RubberTires 231E Storage of Baled Cotton 231F Storage of Roll Paper 232 Protection of Records 232AM Archives Centers 241 Constr. Alteration, and Demolition Operations 251 Fire Tests Bldg. Constr. & Mat'ls. 252 Fire Tests of Door Assem. 253 Test for Floor Covering Systems 255 Burning Character. Bldg. Mat'ls. 256 Tests of Roof Coverings 257 Tests of Window Assemblies 258 Test of Smoke Generation 259 Test for Heat of Bldg. Mat'ls. 260 Tests for Cig. Ignition ResistanceComponents of Furniture 261 Tests for Cig. Ignition ResistanceUphol. Fum. Assem. 262 Test for Fire and Smoke Char. of Wires and Cables 263 Test for Heat &Smoke Release Rates 264 Test for Heat 8 Smoke Rates Using Oxygen-Consumption Calorimeter 264A Heat Release Rates Uphol. Fum. Comp. & Mattresses 265 Textile Wall Coverings, Room Fire Growth Contribution, Tests for 266 Test for Uphol. Fum. Exp. to flaming Ignition Sources 267 Test for Mattress and Bedding Exp. to Flaming Ignition Source 291 Fire Hydrants 295 Wildfire Control 297 Telecomm. Rural Forestry 298 Foam Chem. for Class A FueURural Suburban 299 Protection Life and Property from Wildfire 302 Pleasure and Cwnm. Motor Craft 303 Marinas and Boatyards 306 Gas Hazards on Vessels 307 Marine Terminals. Piers

-

312 318 321 325 326

Vessels, Constr., Repair Cleanrooms Class. Flam. Liquids Prop. of Flam. Liquids. Gases, Solids Safe Entry, Underground Storage Tanks 327 Cleaning Small Tanks Without Entry 328 Manholes, Sewers, Flam. Liquids and Gases in 329 Underground Leakage, flam. Liquid Tanks 385 Tank Vehicles 386 Portable Shipping Tanks 395 Farms, Storage Flam. Liquids 402M krcraft Rescue, Fire Fighting 403 Aircraft Rescue Services 407 Aircraft Fuel Servicing 408 Aircraft Extinguishers 409 Aircraft Hangars 410 Aircraft Maintenance 412 Eval.. Foam Equip. for Aircraft 414 Aircraft Rescue Vehicles 415 Aircraft Fueling Ramp Drainage 416 Airport Terminals 417 Aircraft Loading Walkways 416 Roof-top Heliports 419 Airport Water Systems 422 Aircraft Accident Response 423 Aircraft Engine Test Facilities 424M AirporüCommunity Emerg. Planning 471 Respondingto Haz. Mat. Incidents 472 Haz. Mat. Resp. Prof. Comp. 473 Competenciesfor EMS Personnel 480 Magnesium 481 Titanium 482 Zirconium 485 Lithium Metal 490 Ammonium Nitrate 491M Haz. Chern. Reactions 495 Explosive Materiais 496 Purged Enclosures, Elec. Equip. 497A Class I Haz. Locations for Elec. Inst. 4978 Class II Haz Locations for flec. Inst. in Chem. Process Areas 497M Gases. Vapors Dusts for Elec. Equip. in Haz. Loc. 498 Explosives, Motor Vehicle Term. 501A ManufacturedHome Instal., Sites 501C Recreational Vehicles 501D Recreational Vehicle Parks 502 Highways. Tunnels Bridges 505 Powered Industrial Trucks 512 Truck Fire Protection 513 Motor Freight Terminals 550 Firesafety Concepts Tree 600 Industrial Fire Brigades 601 GuardService 650 Pneumatic Conveying Systems 651 Aluminum Powder 654 Prevent. Fire 8 Dust Explosions 655 Sulfur Fires 664 Wood Processing. Woodworking 701 Fire Tests, Textiles, Films 703 Fire-Ret. Treat. of Bldg. Mat'ls. 704 Ident. of Fire Haz of Materials 705 Field flame Test for Textiles and Films 780 Lightning Prot. Code 801 RadioactiveMaterials Facilities 802 Nuclear Research Reactors 803 Light Water Nuclear Power Plants 820 Wastewater Facilities 850 Electric Generating Plants 851 Hydroelectric Generating Plants 901 Uniforni Coding for Fire Prot. 902M Field Incident Guide 903 Propefty Survey Guide 904 Incident Follow-up Report Guide 906 Fire Incident Field Notes 907M Inves. of Fires of Elec. origin Y10 Libraries and Library Collecticas 911 Museums and Museum Collections 912 Places of Worship 913 Historic Structures and Sites 914 Fire Prd. in Historic Struc.

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Not for Resale

921 Fire and Explosion investigations 1000 Prof. Qual. Accreditation and Cert. Sys. 1001 Fire Fighter Prof Qual. 1002 F.D. Vehicle Driver Prof. Qual. 1003 Airport Fire Fighter Prof. Qual. 1021 Fire Officer Prof. Quai. 1031 Fire Inspector Prof. Qual. 1033 Fire Investigator Prof. Qual. 1035 Public Fire Educator Prof. Qual. 1041 Fire Instructof Prof. Qual. 1122 Model Rocketry 1123 Fireworks, Public Display 1124 Fireworks, Mfg., Trans., Stge 1125 Model Rocket Motors, Mfg. 1126 Pyrotechnics Before Proximate Audience 1141 Planned Building Groups 1201 Devel. of FP Services for Public 1221 Public Fire Sew. Comrn. Systs. 1231 Suburban & Rural Water Supplies 1401 Training Reports, Records 1402 Building Training Centers 1403 Live Fice Training Evolutions 1404 FD SCBA Program 1405 Land-Based Fire Fighters Who Respond to Marine Vessel Fires 1406 Outside Live Fire Training Evolutions 1410 Initial Fire Attack 1420 Warehouse Occupancies 1452 Dwelling Fire Safety Surveys 1470 Search and Rescue 1500 Fire Dept. Occupational Safety and Health Prog. 1521 Fire Dept. Safety Officer 1561 F.D. Incident Management Syst. 1581 F.D. Infection Control Program 1582 Medical Requirementsfor Fire Fighters 1901 Pumper Fire Apparatus 1902 Initial Attack Fire Apparatus 1903 Mobile Water Supply Fire Apparatus 1904 Aeria! Ladder & Elev. Platform 1906 Wildland Fire Apparatus 1911 Tests of Pumps on F.D. Apparatus 1914 Testing F.D Aerial Devices 1921 Portable Pumping Units 1922 FS Self-Contained Pumping Units 1931 Fire Dept. Ground Ladders. Design 1932 Fire Dept. Ground Ladders, Use 1961 Fre Hose 1962 Fire Hose Care, Use 1963 Fire Hose Connections 1964 Spray Nonles (Shutoff and Tip) 1971 Prot. Clothing, Structural m e Fighting 1972 Helmets, Shuctural Fire Fighting 1973 Gloves for Structural Fire Fighting 1974 Prd. Footwear. Struc. Fire Fighting 1975 StatiwiMork Uniforms for FF 1976 Prot. Clothing - Proximity Fire Fighting 1977 Prot. Clothing -Wildland Fire Fighting 1981 Self-contained Breathing App. 1982 Personal Alert Safety Systems for Fire Fighters 1983 Life Safety Rope 1991 Vapor-Protective Suits for Haz Chem. Emergencies 1992 Liquid Splash-Protective Suits for Haz Chem. Emergencies 1993 Suwort FunctionProt. Clothing for Haz. Chem. Oper. 1999 Prot. Clothing - Medical Emerg. Oper. 2001 Clean Agent Ext. Systems 8501 Single Burner Boiler Operation 8503 Pulverlzed Fuel Systems 8504 Atmospheric Fluidized-Bed Boiler Operatica 8505 Stoker Operation

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NFPA National Fire Protection Association Batteryrnarch Park. PO Box 91 01. Quincy. MA 02269-91 O 1 To Order Products. Call Toll-Free: 1-800-344-3555

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Not for Resale

NFPA 325 M

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